Gaf Corporation

Michael C Mourning

Burton H Waxman

Felix Viro

Theodore Panasik

A derivative of paraphenylenediamine, for use as a color developer, having a primary amino group available for oxidative coupling, and a carboxy group bound to the benzene ring to provide the compound with the required stability to enable the compound to be incorporated into a photographic film, the compound being non-diffusible during development of the photographic film in an alkaline processing solution.

Incorporated carboxy substituted p-phenylenediamine color developer

Compounds of the formula: ##STR1## wherein R is halogen or trifluoromethyl, n is 0 to 5, and CD is the residue of a paraphenylenediamine color developer having a primary amino group available for oxidative coupling, the phenoxycarbonyl group being attached to the primary nitrogen atom of the paraphenylenediamine color developer, are used in a receiving sheet of a diffusion transfer photographic element for coupling with a color former to form a stable dye.

Phenoxy carbonyl derivatives of a paraphenylenediamine color developer

Lipophilic non-diffusing color formers yielding diffusing dyes are employed in color transfer systems to provide improved diffusion and better quality of color. The color formers are two-equivalent couplers having in the coupling position acyloxy, or sulfonyloxy groups which complete a lactone or sultone ring, respectively, and are stable to hydrolysis under alkaline development conditions. Color-providing material is created by a reaction which opens the lactone or sultone intramolecular ring after the non-diffusing color former reacts with the oxidized color developer molecule. Examples are given of intramolecular 2-equivalent couplers which react with the developer to give yellow, magenta and cyan dyes. The 2-equivalent color formers are unique since they have an intramolecular lactone or sultone ring which opens under oxidative coupling conditions to yield the diffusible yellow, magenta and cyan dyes.

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Vestal, NY, United States of America

Michael C Mourning