Johnson Matthey Public Limited Company

Other

Johnson Matthey Inc.

Johnson Matthey (shanghai) Chemicals Co. Ltd.

Michael Anthony Howard

Jing Lu

Qinghe Zheng

Lucy Clowes

John Benjamin Goodwin

Paul James Millington

Dongxia Liu

Chris Robson

Fezile Lakadamyali

Oliver Destecroix

Sarah Frances Lockett

Neil Robert Collins

Christopher Gough Morgan

Dongsheng Qiao

Andrea Eva Pascui

Andrew Armitage

Xuan Xu

Zhou Shang

Maria C Vlachou

Kerry Simmance

Amy Kolpin

Jonathan Ashley Cooper

Wolfgang Strehlau

Janet Fisher

Paul Millington

A method of manufacturing a catalyst article, the method comprising: providing a complex of a polyamine and a PGM; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.

Preparation of supported metal nanoparticles using polyamine for three-way catalysis application

The present invention provides a catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; a first catalytic region comprising support material particles; at least some of the support material particles are rhodium-supporting support material particles having rhodium supported thereon at a concentration of from 0.001 to 3.5 wt. %, based on the weight of the rhodium-supporting support material particle; and the rhodium is present at a loading of up to 20 g/ftrelative to the first catalytic region.

Catalyst article having high local rhodium concentration

A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; a first catalytic region comprising a first platinum group metal (PGM) component, wherein the first PGM component comprises Rh and Pt; a second catalytic region comprising a second PGM component, wherein the second PGM component comprises Pd; and wherein the first PGM component has a Pt to Rh ratio of at least 1:20.

Tri-metal PGM catalysts for gasoline engine exhaust gas treatments

Provided is a composition comprising alumina, the alumina being surface-modified with a perovskite type compound of formula (I); wherein formula (I) is defined by AA'BB′O; where: A is an ion of a metal selected from the group consisting of Li, Na, K, Cs, Mg, Sr, Ba, Ca, Y, La, Ce, Pr, Nd, and Gd; A′ is an ion of a metal selected from the group consisting of Li, Na, K, Cs, Mg, Sr, Ba, Ca, Y, La, Ce, Pr, Nd, and Gd; B is an ion of a metal selected from the group consisting of Cu, Mn, Mo, Co, Fe, Ni, Cr, Ti, Zr, Al, Ga, Sc, Nb, V, W, Bi, Zn, Sn, Pt, Rh, Pd, Ru, Au, Ag, and Ir; B′ is an ion of a metal selected from the group consisting of Cu, Mn, Mo, Co, Fe, Ni, Cr, Ti, Zr, Al, Ga, Sc, Nb, V, W, Bi, Zn, Sn, Pt, Rh, Pd, Ru, Au, Ag, and Ir; x is from 0.7 to 1; y is from 0 to 0.5; and z is from 0 to 0.5.

Surface-modified alumina compound for gasoline exhaust gas applications

Provided is a composition comprising a ceria-zirconia mixed oxide, the ceria-zirconia mixed oxide being surface-modified with a perovskite type compound of formula (I); wherein formula (I) is defined by AA'BB′O; where: A is an ion of a metal selected from the group consisting of Li, Na, K, Cs, Mg, Sr, Ba, Ca, Y, La, Ce, Pr, Nd, and Gd; A′ is an ion of a metal selected from the group consisting of Li, Na, K, Cs, Mg, Sr, Ba, Ca, Y, La, Ce, Pr, Nd, and Gd; B is an ion of a metal selected from the group consisting of Cu, Mn, Mo, Co, Fe, Ni, Cr, Ti, Zr, Al, Ga, Sc, Nb, V, W, Bi, Zn, Sn, Pt, Rh, Pd, Ru, Au, Ag, and Ir; B′ is an ion of a metal selected from the group consisting of Cu, Mn, Mo, Co, Fe, Ni, Cr, Ti, Zr, Al, Ga, Sc, Nb, V, W, Bi, Zn, Sn, Pt, Rh, Pd, Ru, Au, Ag, and Ir; x is from 0.7 to 1; y is from 0 to 0.5; and z is from 0 to 0.5.

Surface-modified ceria-zirconia mixed oxide compound for gasoline exhaust

A method of manufacturing a catalyst article, the method comprising: providing a complex of a polyphenol and a PGM, the polyphenol comprising an ester functional group, the PGM comprising palladium; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.

Palladium fixing and low fresh oxygen storage capacity using tannic acid as a complexing and reducing agent

A method of manufacturing a catalyst article, the method comprising: providing a complex of a polyphenol and a PGM, the PGM comprising rhodium and/or platinum, the polyphenol comprising an ester functional group; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.

TWC activity using rhodium/platinum and tannic acid as a complexing and reducing agent

A catalytic wall-flow monolith filter having three-way catalytic activity for use in an emission treatment system of a positive ignition internal combustion engine comprising a porous filter substrate having a first face and a second face defining a longitudinal direction there between and first and second pluralities of channels extending in the longitudinal direction, wherein the first plurality of channels is open at the first face and closed at the second face and the channels of the first plurality of channels are defined in part by channel wall surfaces, wherein the second plurality of channels is open at the second face and closed at the first face and the channels of the second plurality of channels are defined in part by channel wall surfaces and wherein channel walls between the channel wall surfaces of the first plurality of channels and the channel wall surfaces of the second plurality of channels are porous, wherein a first on-wall coating comprising catalytic material having a layer thickness is present on at least the channel wall surfaces of the first plurality of channels, wherein the catalytic material on channel wall surfaces of the first plurality of channels comprises one or more platinum group metal selected from the group consisting of (i) rhodium (Rh) only; (ii) palladium (Pd) only; (iii) platinum (Pt) and rhodium (Rh); (iv) palladium (Pd) and rhodium (Rh); and (v) platinum (Pt), palladium (Pd) and rhodium (Rh) and a refractory metal oxide support, wherein: (i) an amount by weight of the one or more platinum group metal, per unit volume of the on-wall coating present on channel wall surfaces of the first plurality of channels varies continually along the longitudinal direction; and/or (ii) the layer thickness of the on-wall coating present on channel wall surfaces of the first plurality of channels varies continually along the longitudinal direction.

Gasoline particulate filter

The present invention provides a particulate filter for use in an emission treatment system of a gasoline engine, the filter having an inlet side and an outlet side, wherein at least the inlet side is loaded with a synthetic ash.

A catalytic wall-flow monolith for use in an emission treatment system comprises a porous substrate and a three-way catalyst (TWC), wherein the TWC is distributed substantially throughout the porous substrate and wherein the TWC comprises:

A NOstorage component comprises caesium silicate (CsSiO) and at least one platinum group metal. The invention also includes a NOabsorber catalyst comprising a NOstorage component according to the invention disposed on a substrate monolith; a method of treating exhaust gas containing NOfrom a lean burn internal combustion engine comprising the steps of contacting a NOstorage component comprising caesium silicate (Cs2SiO3) and at least one platinum group metal with lean exhaust gas containing NOto adsorb NOthereon; and periodically desorbing adsorbed NOby contacting the NOstorage component with stoichiometric or rich exhaust gas; and a method of making a NOstorage component according to the invention comprising the steps of combining and reacting an aqueous salt of at least one platinum group metal, an aqueous caesium salt and a source of silica.

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Hydrocarbon traps used to trap then release unburned hydrocarbons upon startup of a spark ignition internal combustion engine are sensitive to degradation if exposed to normal temperature exhaust gases. On board diagnostics of HC traps are provided by the invention, by incorporating a heat sensitive oxygen storage material in the HC trap material, and using conventional determination of OSC efficiency to determine if the HC trap material has been exposed to excessive temperature.

Growing community of inventors

Wayne, PA, United States of America

Michael Anthony Howard