Cmb Foodcan Plc

Carnaudmetalbox Plc

Constar International, Inc.

Cmb Packaging (uk) Limited

Crown Packaging Technology, Inc.

Michael Alexander Cochran

Rickworth Folland

James William Nicholas

Melvin Edward Robinson

John F Adams

Melvin Edward Riddell Robinson

The present invention provides a wall for a package, which wall comprises, or includes a layer comprising, a composition comprising a polymer and capable of scavenging oxygen through the metal-catalysed oxidation of an oxidizable organic component thereof. The oxidizable organic component is preferably itself a polymer, and may be the only polymer in the composition. Preferred compositions include a blend of 96% polyethylene terephthalate and 4% poly (m-xylyleneadipamide) containing 200 ppm cobalt as catalyst, with good permeance-versus-time performance (3) when formed into a bottle.

Packaging

The present invention provides a wall for a package, which wall comprises, or includes a layer comprising, a composition comprising a polymer and capable of scavenging oxygen through the metal-catalyzed oxidation of an oxidizable organic component thereof. The oxidizable organic component is preferably itself a polymer, and may be the only polymer in the composition. Preferred compositions include a blend of 96% polyethylene terephthalate and 4% poly (m-xylyleneadipamide) containing 200 ppm cobalt as catalyst, with good permeance-versus-time performance (3) when formed into a bottle.

The present invention provides a wall for a package, which wall comprises, or includes a layer comprising, a composition comprising a polymer and capable of scavenging oxygen through the metal-catalysed oxidation of an oxidisable organic component thereof. The oxidisable organic component is preferably itself a polymer, and may be the only polymer in the composition. Preferred compositions include a blend of 96% polyethylene terephthalate and 4% poly (m-xylyleneadipamide) containing 200 ppm cobalt as catalyst, with good permeance-versus-time performance (3) when formed into a bottle.

A process for the production of a wall for a package including producing a preform of the wall and stretching the preform of the wall where the preform includes a layer containing a polymer and having oxygen-scavenging properties. The preform and the stretching ratios applied are chosen (i) so that the time (t.sub.I) which the permeance of the wall for oxygen would take to rise to 1/5 of the value it would have in the absence of oxygen scavenging would be at least 10 days and (ii) if the preform were stretched at that time (t.sub.I) after the preform were produced, the time (t.sub.D) which the permeance of the wall for oxygen would take to rise 1/5 of the value it would have in the absence of scavenging would be at least 1/4 of the time (t.sub.I). The time between completion of step (A) and the commencement of step (B) is at least 10 days.

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Wantage, United Kingdom

Michael Alexander Cochran