Rohm and Haas Company

Miao-Hsun L Sheng

Shang J Chiou

Scott Lind Egolf

Shang-Jaw Chiou

William Christopher Finch

Travis E Stevens

John William Hook, Iii

Stephen Lee Walker

Aaron Thomas Mailloux

A pigment dispersant including 80-97% by weight, based on the weight of thepigment dispersant, of a first polymer comprising as copolymerized units 15-75% by weight, based on the first polymer weight, ethylenically unsaturated carboxylic acid-functional monomer, the polymer having a Mw from 4,000 to 16,000, and the polymer having a Tg greater than 70&deg; C.; and 3-20% by weight, based on the weight of the pigment dispersant, of a poly(ethylene oxide/propylene oxide) block second polymer having an Mw from 3,000 to 20,000 and an HLB value of 16 to 32 is provided. And the invention relates to a method for dispersing a pigment in an aqueous medium using the pigment dispersant, an aqueous pigment dispersion including the pigment dispersant, and an aqueous ink including the pigment dispersion.

Pigment dispersant composition

An aqueous ink binder including 30-60%, by weight based on the dry weight of the binder composition, of a first polymer including, as polymerized units, 15-75%, by weight based on the weight of the first polymer, ethylenically unsaturated carboxylic acid monomer having a pKa from 2.0 to 4.6, the first polymer having a calculated Hansch parameter from 1.3 to 2.1, and 70-40%, by weight based on the dry weight of the binder composition, of a second polymer, the second polymer being an aqueous emulsion polymer is provided. Also provides are a clear or pigmented ink composition and a method for providing an ink which has press resolublility and, as a dry film, water resistance.

Aqueous ink binder composition

Aqueous emulsions of grafted polymer compositions are provided. The grafted component of these compositions has two or more polymeric substituents. The aqueous emulsions of grafted polymer compositions are particularly useful as cement modifiers.

Grafted polymer composition

A method for improved polymer powder stability is provided, particularly spray-dried emulsion polymers, by spray-drying emulsion polymers with selected low HLB surfactants. Stable spray-dried emulsion polymers are particularly useful as cement modifiers.

Polymer powder stability

A process for preparing large dimension emulsion polymer particles and the polymer products of the process are disclosed. In one embodiment, the invention provides particles having a high aspect ratio, having a shape described by a long axis and an intersecting short axis. These particles range in shape from egg-like, through rod-like, up to extended filaments. In another embodiment, the invention relates to large, nearly spherical emulsion polymer particles.

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Lower Gwynedd, PA, United States of America

Miao-Hsun L Sheng