Kerr-mcgee Chemical, LLC

Merlin D Coe

Alan J Morris

James L Fairchild

Donald S Arnold

Donald A Nichols

A system for increasing the capacity of a process for producing titanium dioxide by reacting titanium tetrachloride vapors with oxygen wherein the process includes an oxygen preheat assembly for preheating oxygen to a predetermined temperature level and a first titanium tetrachloride preheat assembly for preheating titanium tetrachloride to a first, relatively high, temperature level, a portion of the oxygen and the titanium tetrachloride vapors at the first temperature level being reacted in a first reaction zone to produce a mixture of titanium dioxide reaction product, oxygen and unreacted titanium tetrachloride vapors at the first temperature level. The system comprises adding a second titanium tetrachloride preheat assembly for preheating titanium tetrachloride to a second temperature level, substantially below the first temperature level, and adding a second reaction zone adapted for receiving the mixture from the first reaction zone, the titanium tetrachloride vapors at the first temperature level in said mixture and the titanium tetrachloride vapors at the second temperature level being reacted with the oxygen in the mixture from the first reaction zone to produce titanium dioxide. The present invention also contemplates an improved reactor for use in the system for increasing the capacity of the titanium dioxide producing process.

System for increasing the capacity of a titanium dioxide producing

A process for the production of sodium carbonate wherein sodium bicarbonate is recovered from a brine containing sodium carbonate by carbonation of the brine under controlled conditions. The sodium bicarbonate is crystallized from the carbonated brine in a multi-stage carbonating, cooling and crystallization process after which it is filtered to produce wet cake. The wet cake is subjected to predrying to provide a predried wet cake of a specified free moisture content and mixed with recycle light ash to provide a dryer feed of specified moisture content to alleviate problems of product fouling or plugging of the dryer. The light ash from the dryer then is bleached and subjected to recrystallization, screening, centrifuging and drying to provide a dried sodium carbonate possessing, after evaporation of the water of hydration and free moisture, less than 0.10 percent moisture and chemical and physical properties meeting commercial dense ash specifications.

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Oklahoma City, OK, United States of America

Merlin D Coe