Neste Oyj

Meri Hovi

Pekka Aalto

Marina Lindblad

Sami Toppinen

Mats Käldström

Kaisa Lamminpää

Antti Pasanen

Jouni Touronen

Salla Likander

Kari Jansson

Jukka-Pekka Pasanen

Ville Paasikallio

Blanka Toukoniitty

Mats Kaldstrom

Andrea Perez Nebreda

Jukka Myllyoja

Petri Lindqvist

Rami Piilola

Väinö Sippola

Mika Kettunen

Jaana Makkonen

Ville Suntio

Jarno Kohonen

Sonja Kouva

José Luis González Escobedo

Salla Jaatinen

The present invention relates to a method for reducing deactivation of a hydrotreatment catalyst. The hydrotreatment catalyst is used as a main active catalyst for producing renewable hydrocarbons by hydrotreatment from a renewable feedstock which comprises at least an oxygen containing compound, at least one metal containing compound and at least one phosphorus containing compound as impurities. The method comprising adjusting the metal to phosphorus (M:P) weight ratio of the renewable feedstock to a value within the range from 0.70 to 1.26, measured as elemental metal and elemental phosphorus, subjecting the obtained feedstock to a temperature of from 190 to 400° C. under reducing conditions, thereby forming a solid precipitate comprising at least one metal and phosphorus containing compound, and contacting the obtained liquid renewable feedstock with the main active catalyst, in the presence of hydrogen.

Method for reducing deactivation of a hydrotreatment catalyst

A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material contains one or more impurities selected from a group consisting of silicon compounds, phosphorous, Cl and sterols. Exemplary embodiments include (a) providing the recycled or renewable organic material; (c) heat treating the recycled or renewable organic material at 100 to 450° C.; and (f) hydrotreating the heat treated recycled or renewable organic material in a presence of a hydrotreating catalyst; to obtain purified hydrotreated recycled or renewable organic material.

Purification of recycled and renewable organic material

A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material includes more than 1 ppm silicon as silicon compounds. Exemplary steps include (a) providing the recycled or renewable organic material; (b) heat treating the recycled or renewable organic material to form a heat treated recycled or renewable organic material, wherein the at least part of silicon compounds present in the recycled or renewable organic material are converted to volatile silicon compounds, and (c) evaporating volatile silicon compounds from the heat treated recycled or renewable organic material to obtain recycled or renewable organic material fraction containing less silicon than the recycled or renewable organic material provided in step (a).

A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material includes more than 1 ppm silicon as silicon compounds and/or more than 10 ppm phosphorous as phosphorous compounds. The method can include providing a feed of the lipid material; heat treating the organic material in presence of an adsorbent and the filtering organic material and hydrotreating the lipid material in a presence of a hydrotreating catalyst to obtain purified hydrotreated organic material having less than 20% organic material and/or less than 30% of the original phosphorous content of the organic material.

A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material contains more than 20 ppm Cl. Exemplary methods include (a) providing the recycled or renewable organic material; (b) purifying the organic recycled or renewable organic material to obtain a purified recycled or renewable organic material, and (c) hydrotreating the purified recycled or renewable organic material in a presence of a hydrotreating catalyst at a temperature from 270 to 380&#xb0; C. under pressure from 4 to 20 MPa and under continuous hydrogen flow; to obtain purified hydrotreated recycled or renewable organic material.

A method for producing a renewable base oil from a feedstock of biological origin includes providing a feedstock, the feedstock including: 2-95 wt % of a mixture of free fatty acids; 5-98 wt % fatty acid glycerols selected from mono-glycerides, di-glycerides and tri-glycerides of fatty acids; 0-50 wt % of one or more compounds selected from the list consisting of: fatty acid esters of the non-glycerol type, fatty amides and fatty alcohols; a major part of the feedstock being a mixture of free fatty acids and fatty acid glycerols; subjecting all or part of the feedstock to ketonisation reaction conditions where two free fatty acids react to yield a ketone stream, and subjecting the ketone stream to both hydrodeoxygenation and to hydroisomerisation reaction conditions, to yield a deoxygenated and isomerised base oil product stream containing the renewable base oil.

TiOcatalyst in ketonisation reactions to produce RBO

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Porvoo, Finland

Meri Hovi