Bergwerksverband Gmbh

Menachem El-Roy

Ingo Romey

Synthetic plastic materials for the manufacture of extrusion, injection and press forms are described, which are prepared from elastomers as well as mixed- and copolymers thereof with thermoplastic properties and liquification products from extractive coal hydrogenation which are residues with a softening point between 50.degree. and 150.degree. C. Polar, aromatic or cyclic groups in the elastomer component increase the compatibility of the coal liquification residue with the elastomer and improve the mechanical properties of the products.

Modified synthetic plastic from thermoplastic synthetics and coal

Synthetic form masses are described which are derived from thermoplastic polyolefins as well as mixed and copolymerisates thereof and a coal liquification product. The coat liquification product is a residue which precipitates out during extractive hydrogenation and has a softening point between 70.degree. and 200.degree. C. The thermoplastic polyolefin contains a component of polar, aromatic or cyclic monomers, which improve the compatibility of the components in the mixture. The form masses from this mixture, which may include filler material, have excellent tear resistance properties.

Form masses from thermoplastic synthetic materials and residues of coal

Self-curing or curable materials are obtained from the distillation residues of coal hydrogenation by condensing a residue of this type having a softening point of 30.degree. to 54.degree. C. in a first stage with a mono- or dihydroxybenzene and/or a methylhydroxybenzene and/or an ethylene substituted benzene. These reactants are used at a ratio of residue to benzene derivative between 1:1 and 2:1 and the reaction is carried out in the presence of acid at a pH of 1 to 2 and at a temperature of 90.degree. to 100.degree. C. In a second stage the thus obtained reaction product is then further reacted at about the same temperature with an aldehyde. As a result a novolak-type resin is obtained. The invention permits the making of inexpensive self-curing or curable materials with properties similar to those of phenolic acids. Besides, the invention also provides an outlet for the high boiling residue of the extractive coal hydrogenation which otherwise had little use.

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Haifa, Israel

Menachem El-Roy