Uhde Gmbh

Thyssenkrupp Industrial Solutions Ag

Thyssenkrupp Uhde Gmbh

Gidara Energy B.v.

Max Heinritz-Adrian

Johannes Kowoll

Eberhard Kuske

Ralf Abraham

Sascha Wenzel

Johannes Menzel

Lothar Semrau

Stefan Hamel

Domenico Pavone

Helmut Gehrke

Oliver Noll

Muhammad Iqbal Mian

Natarajan Thiagarajan

Rolf Schwass

A process and device for the gasification of liquid or fine-grain solid fuel materials in a reactor is described. Synthesis gas is generated in a first reaction chamber arranged in the upper part of the reactor; feedstock is fed to the upper part. Liquid slag precipitates on its lateral walls. The lower side has a hole with a slag drop-off edge; generated synthesis gas can be withdrawn in downward direction and the liquid slag can drop off the edge. A second chamber delimited by a water film is located under the opening. A third chamber adjacent to the bottom of the second is fed with water. A water bath is adjacent the bottom of the third chamber. The synthesis gas is withdrawn from the pressure vessel in an area at the side or below the third chamber, but located above the water bath.

Gasification reactor and process for entrained-flow gasification

A process and device for the gasification of liquid or fine-grain solid fuel materials with the aid of oxygenous, gaseous gasification agents in a reactor is described. Liquid slag is separated on the walls of the reactor. The synthesis gas is generated in a first reaction chamber arranged in the upper part of the reactor and the feedstock is fed to the upper part. Liquid slag precipitates on its lateral walls, with free downflow and no solidification of the slag surface. The lower side has a hole with a slag drop-off edge, from which the generated synthesis gas can be withdrawn in downward direction and the liquid slag can drop off the edge. A second chamber which is delimited by a water film is located under the opening and used to keep the synthesis gas dry and cool. A third chamber is adjacent to the bottom of the second and fed with water to cool the synthesis gas. A water bath is adjacent the bottom of the third chamber and collects the slag particles already solidified and dropped off or those particles still in the liquid phase. The synthesis gas is withdrawn from the pressure vessel in an area below or on the side of the third chamber but in any case located above the water bath.

The invention relates to a method for dehydrating alkanes, wherein the alkane is guided in a reactor for the dehydrogenation of alkanes via a catalyst, and the process may be carried out adiabatically or non-adiabatically, and the catalyst for dehydration can be regenerated after the reaction phase by means of transferring a gas, wherein said gas is guided via the catalyst after a short rinsing phase using water vapor, and said regeneration gas consists of a gas containing oxygen and of steam, and after regeneration the catalyst is freed of the gas containing oxygen by transferring steam, wherein the duration of the transfer of a gas containing oxygen is significantly reduced as compared to common methods and represents 70% or less of the total regeneration time, and the catalyst has an increased selectivity for forming alkene by means of carrying out the regeneration at a constant activity, and the catalyst is comprised of a metal of the group of platinum metals or group VIB of the periodic table of the elements, which is applied to a carrier in form of a compound or in elementary form, which substantially consists of oxides of the elements of tin, zinc, or aluminum.

Regeneration of catalysts for dehydrating alkanes

With a method for supplying an entrained-flow gasification reactor with carbonaceous fuel for the production of a gas that contains CO and Hand flue ash under pressure and at a temperature above the melting point of the ash, wherein the resulting gas is passed to further treatment stages, particularly at least one synthesis stage, the waste gas that is derived from the subsequent treatment stage and still contains hydrocarbons and/or hydrogen is used for pneumatic conveying of the fuel into the entrained-flow gasification reactor.

Method for supplying an entrained-flow gasification reactor with carbonaceous fuels

With the help of a method and device for nozzle-jetting oxygen into a synthesis reactor, e.g. for oxy-dehydration, with largely axial flow of the gas mixture through a catalyst bed, it is intended to vastly improve the mixing-in and mixing-through of oxygen above the catalyst especially for oxy-dehydration process. This is achieved by feeding the oxygen to a ring distributor system arranged above the catalyst bed in pure form, as air or mixed with inert gas or water vapor and jetting the oxygen onto the catalyst surface through several exit openings in the ring distributor at an inclined angle deviating from the vertical.

Method and device for nozzle-jetting oxygen into a synthesis reactor

The invention relates to a method for producing unsaturated hydrocarbons. According to said method, in a first step, a hydrocarbon, especially a mixture which contains alkanes, essentially no water, and can contain water vapour, is continuously guided through a first catalyst bed provided with standard dehydration conditions. Liquid water, water vapour and a gas containing oxygen are then added to the reaction mixture obtained in the first step and, in a second step, the reaction mixture obtained is then continuously guided through another catalyst bed for oxidising hydrogen and for further dehydrating hydrocarbons. The first catalyst bed can be heated and the heating in the first step is then preferably regulated in such a way that an essentially isothermic operating mode is created.

Method for catalytically dehydrating hydrocarbons

The invention relates to a method for producing propylene during which a first gas mixture, which is technically free of oxygen but contains propane, water vapor and hydrogen, and which has a temperature of at least 400&#xb0; C., is led into a reaction device having at least one catalyst bed as well as usual dehydration conditions. Another gas mixture, which contains propane and oxygen and which can also contain ammonia, the propane content exceeding the oxygen content, is led into the same reaction device in which it reacts with the first gas mixture while forming propylene, water vapor and hydrogen, and the formed gas mixture containing propylene, water vapor and hydrogen is drawn out of the reaction device.

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Muenster, Germany

Max Heinritz-Adrian