Kennametal Inc.

Deloro Stellite Holdings Corporation

Matthew Yao

James B C Wu

Abdelhakim Belhadjhamida

Danie DeWet

Rachel Collier

Paul D Prichard

Kevin Michael Gamble

Qingjun Zheng

Michael J Meyer

Martin G Perez

David A Lee

Louw DeJong

Brad McLane

Volker Hellinger

Don Williams

John Skwara

Alloy compositions and associated articles are described herein which, in some embodiments, exhibit enhancements to ductility and processing capabilities without significant sacrifices to hardness, wear resistance, and/or corrosion resistance. An alloy, in some embodiments, comprises 0-40 wt. % nickel, 14-20 wt. % chromium, 24-35 wt. % molybdenum, 0-15 wt. % iron, 0-1.5 wt. % manganese, 0.01-0.1 wt. % carbon, 0-15 wt. % tungsten, and the balance cobalt, wherein the alloy has a configurational entropy greater than 1.5R, where R is the universal gas constant.

Wear and corrosion resistant alloy compositions

Powder alloy compositions and associated additive manufacturing techniques are described herein for production of sintered articles with microstructure and/or enhanced wear and corrosion resistance. In some embodiments, an article comprises sintered cobalt-based alloy having chromium carbide precipitates dispersed therein, the chromium carbide precipitates having an average size less than 4 μm.

Sintered alloy articles and methods of making the same

In one aspect, cobalt-based alloys are described herein comprising composition and microstructure permitting a balance of hardness, toughness and wear resistance desirable for wood cutting applications. A cobalt-based alloy comprises a chromium rich carbide phase in an amount of 15-30 volume percent, a tungsten-rich phase in an amount of 9-15 volume percent and a balance of cobalt-rich solid solution matrix comprising nickel, chromium, vanadium and tungsten.

Cobalt-based alloys for wood cutting applications

Cobalt-based alloy compositions are described herein having properties compatible with thermal spray and sintering techniques. Such alloy compositions can provide claddings to a variety of metallic substrates having complex geometries, wherein the claddings exhibit desirable density, hardness, wear resistance and corrosion resistance. Briefly, an alloy composition described herein comprises 15-25 wt. % chromium, 15-20 wt. % molybdenum, 0-15 wt. % tungsten, 10-20 wt. % nickel, 2.5-3.5 wt. % boron, 2.5-4.5 wt. % silicon, 1-2 wt. % carbon and the balance cobalt, wherein a ratio of boron to silicon (B/Si) in the alloy composition ranges from 0.5 to 1.0.

Wear resistant and corrosion resistant cobalt-based alloy powders and applications thereof

A surgical implant component comprising an implant component body manufactured from a Co-based substrate alloy comprising Co, Cr, Mo, Si, and C, and a coating on a bone-ingrowth surface of the component body manufactured from a Co-based coating alloy comprising Co, Cr, Mo, Si, C and B. The coating is a network of fused particles of the Co-based coating alloy with spherical particles, irregular aspherical particles, and between about 35 and about 70 volume % porosity. A method of manufacturing the foregoing surgical implant component.

Porous coating for surgical orthopedic implants

A surgical implant component comprising an implant component body manufactured from an alloy comprising from about 23 to about 33 wt % Cr, from about 8 to about 20 wt % Mo, from about 0.05 to about 1.5 wt % Si, from about 0.35 to about 3.5 wt % C, from about 40 to about 60 wt % Co, and incidental impurities. The implant component alloy has an atomic % ratio of (Cr+Mo+Nb)/Co of at least 0.59, a matrix metallurgical microstructure comprising between about 45% and about 85% by volume face-centered cubic structure, and between about 15% and about 55% by volume hexagonal close-packed structure; and a Rockwell C hardness of greater than 35. A method for manufacturing a surgical implant component body for a surgical implant by a manufacturing method selected from the group consisting of casting, forging, and powder metallurgy pressing-plus-sintering from an alloy.

Surgical orthopedic implants made from wear-resistant cobalt&#x2014;chromium&#x2014;molybdenum alloys

A wear- and corrosion-resistant alloy, and related application method, where the alloy has by approximate weight %, C 0.12-0.7, Cr 20-30, Mo 7-15, Ni 1-4, and Co balance, wherein the alloy further contains one or more carbide-former elements from the group consisting of Ti, Zr, Hf, V, Nb, and Ta in a cumulative concentration to stoichiometrically offset between about 30% and about 90% of the C in the alloy.

Weldable, crack-resistant co-based alloy, overlay method, and components

A pipe or pipe fitting for use in harsh environment such as in petroleum refinery processes for cracking petroleum feedstocks, the pipe or pipe fitting comprising a 0.25 to 2.5 mm thick Co-based metallic coating on an internal surface of the pipe body, the coating having a hypereutectic microstructure characterized by carbides in a cobalt matrix and an average carbide grain size of less than 50 microns, and the Co-based metallic composition overlays the pipe internal surface at an interface which is free of heat-affected zone and which has a diffusion zone which is less than 0.002 inches thick.

Wear resistant inner coating for pipes and pipe fittings

Forming a wear- and corrosion-resistant coating on an industrial component such as a chemical processing or nuclear power valve component by applying a cobalt-based dilution buffer layer to an iron-based substrate by slurry coating, and then applying by welding a cobalt-based build-up layer over the cobalt-based dilution buffer layer. An industrial component having a dilution buffer layer and a welding build-up layer thereover.

Dilution control in hardfacing severe service components

A method for imparting wear- and corrosion-resistance to a metal component comprising overlaying the component with a ductile Co-based alloy comprising between about 0.12 wt % and about 0.7 wt % C, between about 20 wt % and about 30 wt % Cr, between about 10 wt % and about 15 wt % Mo, between about 1 wt % and about 4 wt % Ni, and balance of Co, without forming cracks during the alloy's solidification.

Weldable, crack-resistant Co-based alloy and overlay

A Co&#x2014;Mo&#x2014;Cr Co-based alloy and overlay for wear and corrosion applications. The Mo:Si ratio is between about 15:1 and about 22:1 for enhanced ductility with a Laves phase.

Ductile cobalt-based Laves phase alloys

Enhancing wear and corrosion resistance of an industrial component by depositing a Ni-based alloy coating having a thickness of at least about 50 microns onto a surface of the industrial component by high velocity oxyfuel propulsion of a Ni-based alloy powder containing a) Cr, b) from about 15 to about 25 wt % Mo, c) no more than about 1 wt % Fe, and d) no more than about 1 wt % elements having an atomic number greater than 42. A Ni-based alloy powder for HVOF deposition containing a) Cr, b) from about 15 to about 25 wt % Mo, c) no more than about 1 wt % Fe, and d) no more than about 1 wt % elements having an atomic number greater than 42. A Ni-based coating on an industrial component having enhanced corrosion and wear resistance.

Wear-resistant, corrosion-resistant Ni-Cr-Mo thermal spray powder and method

A Co-based alloy comprising 13-16 wt % Cr, 20-30 wt % Mo, 2.2-3.2 wt % Si, and balance Co, with a Cr:Si ratio of between about 4.5 and about 7.5, a Mo:Si ratio of between about 9 and about 15, wear resistance, and corrosion resistance in both oxidizing and reducing acids.

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Belleville, Canada

Matthew Yao