Carbon, Inc.

Matthew S Menyo

Jason P Rolland

Ikpreet Singh Grover

Lloyd Mahlon Robeson

Joseph M DeSimone

Marie K Herring

Justin Poelma

R Griffin Price

R Nicholas Carmean

Raymond C Pederkoff

Provided according to some embodiments is a polymerizable liquid useful for the production of a three-dimensional object comprised of polyurethane, polyurea, or a copolymer thereof by additive manufacturing, the polymerizable liquid comprising a mixture of: (a) a first blocked or reactive blocked prepolymer comprising a compound of the formula X(A), where X is a hydrocarbyl group, n is at least 3, and each A is an independently selected substituent of Formula I: (I) where R is a hydrocarbyl group, R' is O or NH, and Z is a blocking group; (b) a polyol and/or polyamine chain extender; (c) optionally a reactive diluent; and (d) a photoinitiator. A method of use of the polymerizable liquid to make a three-dimensional object by additive manufacturing and prepolymer compounds useful for the same are also provided.

Branched reactive blocked prepolymers for additive manufacturing

The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by sterolithography, such as by continuous liquid interface production (CLIP), wherein the three-dimensional object is flame retardant.

Dual cure additive manufacturing resins for production of flame retardant objects

Provided is a method of making a cured object having a surface coating bonded thereto, which may include: providing an intermediate object produced in an additive manufacturing process such as stereolithography by light polymerization of a dual cure resin, the resin comprising a mixture of (i) a light polymerizable first component, and (ii) a second component that is different from the first component; applying a first reactive coating composition to a surface portion of the object to form a first coating thereon; optionally, but in some embodiments preferably, applying a second reactive coating composition to the first coating to form a second coating thereon; and heating the object at (and for) a time and to a temperature sufficient to bond the first coating to the surface portion, and bond the second coating when present to the first coating, and form the cured object having a surface coating bonded thereto.

Bonded surface coating methods for additively manufactured products

Provided is a method of forming a three-dimensional object, which may include the steps of: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid that comprises a reactive blocked monomer and/or prepolymer comprising a self-polymerizing monomer and/or prepolymer blocked with a light-polymerizable blocking group; (c) irradiating the build region with light through said optically transparent member to form a solid polymer scaffold from the reactive blocked monomer and/or prepolymer and also advancing the carrier away from the build surface to form a three-dimensional intermediate; and then (d) heating and/or microwave irradiating, the three-dimensional intermediate sufficiently to degrade the scaffold and regenerate the monomer and/or prepolymer in de-blocked form, which monomer and/or prepolymer in turn self-polymerize, to form said three-dimensional object.

Serially curable resins useful in additive manufacturing

Provided herein according to some embodiments is a dual cure stereolithography resin that includes thermoplastic particles, which thermoplastic particles are insoluble in the resin and insoluble during a first, light, cure in which an intermediate object is produced, but then dissolve or swell in the intermediate object during the second, heat, cure.

Dual cure stereolithography resins containing thermoplastic particles

Provided herein is a dual cure resin useful for the production of objects by stereolithography, said resin comprising a mixture of: (a) a light-polymerizable component; and (b) a heat-polymerizable component, said heat-polymerizable component comprising: (i) a dicyclopentadiene-containing polyepoxide resin; (ii) a cyanate ester resin; (iii) an epoxy-reactive toughening agent; and (iv) a core shell rubber toughener.

Dual cure resin for the production of moisture-resistant articles by additive manufacturing

The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by sterolithography, such as by continuous liquid interface production (CLIP).

Tough, high temperature polymers produced by stereolithography

The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by stereolithography, such as by continuous liquid interface production (CLIP), wherein the three-dimensional object is flame retardant.

Provided herein according to some embodiments is a dual cure stereolithography resin that includes a Diels-Alder adduct, which adduct is light polymerizable in the first, light, cure to produce an intermediate object, and on heating the intermediate object yields a bis-maleimide that can further react and/or polymerize during the second, heat, cure.

Dual cure stereolithography resins containing diels-alder adducts

A method of forming a three-dimensional object is carried out by: (a) providing a cyanate ester dual cure resin; (b) forming a three-dimensional intermediate from said resin, where said intermediate has the shape of, or a shape to be imparted to, said three-dimensional object, and where said resin is solidified by exposure to light; (c) optionally washing the three-dimensional intermediate, and then (d) heating and/or microwave irradiating said three-dimensional intermediate sufficiently to further cure said resin and form said three-dimensional object. Compositions useful for carrying out the method, and products made from the method, are also described.

Cyanate ester epoxy dual cure resins for additive manufacturing

Cyanate ester dual cure resins for additive manufacturing

Provided is a method of making a coated object, which may include stereolithographically producing a green intermediate object from a dual cure polymerizable resin, the intermediate object containing uncured polymerizable material therein; then, optionally cleaning the green object; then, in any order: coating at least one surface portion of the object with a particulate material; and heating the object sufficiently to further cure the object; the coating and/or heating steps carried out under conditions in which uncured polymerizable material sweats (or exudes) to the surface of said object, and wherein the uncured polymerizable material contacts the particulate material, polymerizes, and bonds the particulate material to the surface of the object during the coating and/or heating steps. Also provided is a coated object produced by the method.

Growing community of inventors

San Francisco, CA, United States of America

Matthew S Menyo