Advanced Refining Technologies LLC

Matthew P Woods

Darryl Patrick Klein

Viorel Duma

Bruno C Nesci

Nan Chen

Stanislaw Plecha

Koichi Matsushita

Yosuke Koakutsu

Yasuhito Goto

A catalyst comprising a carrier and a metals component impregnated in the carrier, the carrier comprising alumina; and the metals component comprising a first metals fraction and a second metals fraction, the first metals fraction comprising at least one metal selected from chromium, molybdenum, or tungsten, and the second metals fraction comprising at least two metals selected from cobalt, rhodium, iridium, nickel, palladium, or platinum, wherein the catalyst has a first pore volume of 0.28 to 0.45 mL/g for pores having a pore diameter of 12 nm to less than 16 nm, and a second pore volume of 0.15 to 0.28 mL/g for pores of 2.0 nm to less than 12.0 nm.

Hydroprocessing catalyst for the reduction of metals and sulfur in heavy feeds

Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise alumina and 5 wt % or less titania. Catalyst prepared from the supports have at least 30 to 80 volume percent of its pore volume in pores having a diameter of between 200 and 500 angstroms. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion.

Extruded resid demetallation catalyst

A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks is prepared, the catalyst comprising a metal from Group 6 of the Periodic Table, a metal from Groups 8, 9 or 10 and optionally phosphorous, wherein the metals, and phosphorous when present, are carried on a foraminous carrier or support, the carrier or support, preferably comprises porous alumina having a total pore volume (TPV) of about 0.6 cc/g to about 1.1 cc/g and comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (&#x212b;); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 (&#x212b;) to less than about 1000 &#x212b;; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 &#x212b;; and (d) a pore mode equal to or greater than about 90 &#x212b; and less than about 160 &#x212b;. Preferably the support exhibits a d50 greater than about 100 &#x212b; and less than about 150 &#x212b;.

Catalyst support and catalysts prepared therefrom

Improved supported hydroprocessing catalysts, and their method of preparation useful for the hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) of a petroleum feedstock, including a residuum hydrocarbon feedstock are disclosed. The Catalysts contain at least one Groups VIB metal component, at least one Group VIII metal component, and a phosphorus component, supported on a foraminous support such as alumina. The supported catalysts are characterized by a specific combination of properties, namely, the Group VIII metal to Phosphorous molar ratio, the Group VIII metal to Group VIB metal molar ratio, the phosphorous component to Group VIB component molar ratio and the median pore diameter. The resulting catalysts exhibit enhanced HDN without sacrificing to any significant degree the HDS activity.

High HDN selectivity hydrotreating catalyst

Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise precipitated alumina prepared by a low temperature pH swing process. A large portion of the pore volume of the catalyst supports has pores with a diameter in the range of about 200 &#x212b; to about 500 &#x212b;. Catalysts prepared from the supports of the invention exhibit improved catalytic activity and stability to remove metals from heavy hydrocarbon feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion during the hydroconversion process.

Resid hydrotreating catalyst

A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A.

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Pasadena, MD, United States of America

Matthew P Woods