Texaco Inc.

Matthew A McMahon

Ronald J McKeon

Motasimur R Khan

Kung-You Lee

Kenneth W McKenzie

Robert M Suggitt

Albert Brent

Edward L Cole

Justin C Powell

King D Eng

Robert F Heyl

Mitri S Najjar

Roger J Corbeels

Stephen J DeCanio

John M Crone, Jr

John T Brandenburg

Christine C Albert

John T Nolan, Jr

Robert B Burns

Richard V Kessler

Michael C Martin

Raymond F Wilson

Erven J Kuhlmann

Peter D Robison

Enrique F dePaz

George C Meldrum

Jackson K Chiou

Kung Y Lee

A chemically disinfected sewage sludge-containing material comprising (1) an aqueous slurry of sewage sludge-containing material having a solids content in the range of about 10 to 30 wt. %; and (2) a chemical disinfectant comprising a water soluble silicate of sodium in the amount of 5 to 20 wt. % (basis dry wt. of said sewage sludge). In one embodiment, a pumpable chemically disinfected sewage sludge-containing material was produced by the steps of (1) dewatering sewage sludge to produce an aqueous slurry having a solids content of about 10 to 30 wt. %; (2) shearing the dewatered sewage sludge from (1) at a temperature in the range of about ambient to 230.degree. F. and at a shear rate of at least 30 per second for a period in the range of about 0.5 to 180 minutes; and (3) mixing the following materials together at a temperature in the range of about ambient to 230.degree. F. to produce a pumpable aqueous slurry having a solids content in the range of about 30 to 65 wt. % and a pH of at least about 11: (a) about 0.5 to 7 parts by wt. of sheared dewatered sewage sludge from (2); (b) about 5 to 20 wt. % of a silicate of sodium (basis total dry weight of sewage sludge); and (c) about 5 to 7 parts by wt. of at least one material from the group consisting of sewage sludge-containing material, liquid hydrocarbonaceous fuel, solid carbonaceous fuel-containing material, and mixtures thereof.

Chemically disinfected sewage sludge-containing materials

A process for disposing of sewage sludge by heating and shearing an aqueous mixture of sewage sludge in a tubular-shaped processing means containing a plurality of rotating agitators to produce a pumpable aqueous slurry of sewage sludge. The aqueous slurry of sewage sludge is mixed with solid carbonaceous fuel or an aqueous slurry of solid carbonaceous fuel to produce a pumpable aqueous slurry of sewage sludge and solid carbonaceous fuel. The aqueous slurry of sewage sludge and solid carbonaceous fuel is heated in a first steam jacketed rotary disc mixing-heating means. Alternately, first and second hoppers are filled with said heated aqueous slurry of sewage sludge and solid carbonaceous fuel and cycled between a second steam jacketed rotary disc mixing-heating means; wherein while one hopper is being filled the contents in the other hopper are being dewatered. The thickened pumpable slurry is burned in a partial oxidation gasifier, furnace, boiler, or incinerator to produce a hot effluent gas steam. By this process, noxious sewage sludge may be disposed of without contaminating the environment. By-product synthesis gas, reducing gas, or fuel gas may be produced.

Process for disposing of sewage sludge

A process for disposing of sewage sludge comprising the steps of, (1) dewatering the sewage sludge to produce an aqueous slurry of sewage sludge having a solids content of about 10 to 30 wt. %; (2) simultaneously heating and shearing said dewatered sewage sludge at about 150.degree. F. to 210.degree. F. in the absence of air for 0.5 seconds to 60 minutes while being continuously passed through a tubular-shaped processing means containing a plurality of rotating agitators, thereby producing a pumpable slurry having a viscosity of less than about 2000 centipoise; (3) dewatering the sewage sludge if necessary; (4) mixing at a temperature in the range of about ambient to 180.degree. F. in a ribbon or in-line static mixer the slurry of sewage sludge from (2) and/or (3) with a supplemental solid carbonaceous fuel e.g. coal and/or petroleum-coke to produce a pumpable aqueous slurry of sewage sludge and supplemental fuel having a solids content in the range of about 50 to 60 wt. %; (5) mixing the slurry of sewage sludge and supplemental fuel from (4) in a steam jacketed continuous rotary disc mixer at about 180.degree. F. to 250.degree. F. while removing steam to produce a pumpable slurry of dewatered sewage sludge and solid fuel having a solids content of 50 to 65 wt. % and a HHV of 6,000 to 18,000 BTU/LB; and (6) burning said pumpable slurry from (5) in a partial oxidation gasifier, furnace, boiler, or incinerator to produce an effluent gas stream. In a preferred embodiment, the effluent gas stream is cleaned and purified and non-contaminating ash and slag are separated. By this process, noxious sewage sludge may be disposed of without contaminating the environment. By-product synthesis gas, reducing gas, or fuel gas may be produced.

A process for disposing of sewage sludge comprising the steps of, (1) dewatering the sewage sludge to produce an aqueous slurry of sewage sludge having a solids content of about 10 to 50 wt. %; (2) heating and mildly shearing said dewatered sewage sludge at about 150.degree. F. to 210.degree. F. in the absence of air for 3 seconds to 60 minutes by a rotor/mixer at a speed of about 15 to 1000 r.p.m., thereby producing a pumpable slurry having a viscosity of less than about 2500 centipoise; (3) mixing at a temperature in the range of about ambient to 200.degree. F. the slurry of sewage sludge from (2) with a supplemental fuel to produce a pumpable slurry of sewage sludge and supplemental fuel having a solids content in the range of about 50 to 65 wt. % and a higher heating value in the range of about 6,000 to 18,000 BTU/LB; and (4) burning said pumpable slurry from (3) in a partial oxidation gasifier, furnace, boiler, or incinerator to produce an effluent gas stream. In a preferred embodiment, the effluent gas stream is cleaned and purified and non-contaminating ash and slag are separated. By this process, noxious sewage sludge may be disposed of without contaminating the environment.

An improved process for the low-cost disposal of noxious municipal sewage sludge in a safe way without polluting the environment. In the process, a portion of a stream of dewatered sewage sludge having a solids content in the range of about 17 to 40 wt.% is dried to produce dried sewage sludge having a solids content in the range of about 75 to 99 wt.%. The dried sewage sludge is ground to a small particle size. A pumpable aqueous feed slurry having a solids content in the range of about 45 to 70 wt.% is produced comprising (a) solid carbonaceous fuel, (b) ground dried sewage sludge, and (c) sheared and/or unsheared dewatered sewage sludge. The parts by weight of (a):(b):(c) are respectively in the range of about 3 to 8:0.5 to 2:0.5 to 2, and preferably 6:1:1. The aqueous feed slurry is gasified in a free-flow partial oxidation gas generator. Synthesis gas, reducing gas or fuel gas is produced, Ash and slag are separated from the gas stream and safely disposed. Waste heat produced in the process may be used to dry the sewage sludge.

Partial oxidation of sewage sludge

A process for disposing of sanitary sewage sludge by producing a pumpable slurry of sewage sludge with or without solid carbonaceous fuel and burning said slurry as fuel in a partial oxidation gas generator, furnace, or boiler. First, an aqueous slurry of sewage sludge is concentrated to produce sewage sludge cake. The sewage sludge cake is preheated and sheared while in contact with sulfuric or sulfurous acid to produce a pumpable acidified aqueous slurry of sewage sludge having a pH of about 1 to 5. After two-stage hydrothermal treatment with neutralization of the sewage sludge after the second hydrothermal stage, the solids content of the pumpable aqueous slurry of sewage sludge is increased. By means of the subject process, the viscosity of the slurry of sewage sludge with or without solid carbonaceous fuel is reduced and coagulation is suppressed. A pumpable aqueous slurry of sewage sludge with or without solid carbonaceous fuel is produced and burned with a free-oxygen containing gas in a partial oxidation gasifier, furnace, boiler, or incinerator to produce a hot raw effluent gas stream. In a preferred embodiment, the effluent gas stream is cleaned and purified and non-contaminating ash and slag are separated. By this process, noxious sewage sludge may be disposed of without contaminating the environment. By-product synthesis gas, reducing gas, or fuel gas may be produced.

Municipal sanitary sewage sludge is disposed of by an improved partial oxidation process without polluting the environment. Aqueous slurries of sewage sludge are upgraded by hydrothermal treatment, preferably while being sheared, concentrated, and then mixed with a supplemental fuel, preferably coal. A pumpable aqueous slurry of sewage sludge-coal and/or petroleum coke is thereby produced having a greater total solids and heat content (HHV) as well as containing an increased amount of sewage sludge for reacting with free-oxygen containing gas in a free-flow partial oxidation gas generator. Hot quench water or steam produced by cooling the hot raw effluent stream of synthesis gas, reducing gas or fuel gas from the gasifier may provide heat for the hydrothermal step.

Municipal sanitary sewage sludge is disposed of by an improved partial oxidation process without polluting the environment. Aqueous slurries of sewage sludge are upgraded by being sheared without heating, concentrated if necessary, and then mixed with a supplemental fuel, preferably coal. In one embodiment, the aqueous slurry of sewage sludge and the supplemental coal and/or petroleum coke are introduced into a shearing mixer for simultaneous shearing and mixing together. A pumpable aqueous slurry of sewage sludge-coal and/or petroleum coke is thereby produced having an increased amount of total solids and an increased heat content (HHV) as well as containing an increased amount of sewage sludge for reacting with free-oxygen containing gas in a free-flow partial oxidation gas generator. Hot quench water or steam produced by cooling the hot raw effluent stream of synthesis gas, reducing gas or fuel gas from the gasifier may provide heat for indirect heat exchange with other streams in the process.

A method for coating a substrate with alumina which comprises contacting a substrate with a supersaturated aqueous alkali aluminate solution having an alkali metal hydroxide concentration ranging from 0.75 to 1.5 molar and an aluminum to alkali mole ratio ranging from 0.65 to 0.70 is provided.

Method of forming an alumina coated substrate

Method and apparatus for forming a coating material, and for depositing the material onto the surface of an article or a substrate. The apparatus includes a tank within which the coating composition is formed together with a residual amount of gas. The tank and the internal support members are electrically segregated from a perforated container with reactant material held on the internal support to avoid the formation of gas bubbles on the surfaces of the tank and support which are immersed into the coating composition.

Method and apparatus for the production of exhaust gas filters

An apparatus for coating a substrate with an alumina hydrate film includes a coating vessel having at least one support therein; the substrate to be coated is mounted on the support; and at least one porous or perforated container for holding aluminum metal to react with a caustic solution to form an aluminate coating solution is also mounted on the support. The apparatus can also contain means for mechanical agitation, such as a rotational stirring device. In the coating of the substrate a caustic solution is contacted with a substrate and with at least one porous container having aluminum metal therein. The aluminum metal reacts with the caustic solution to form an aluminate coating solution and then an alumina hydrate film is deposited on the substrate. The caustic solution is preferably subjected to mechanical agitation during the coating process.

Apparatus and method for the production of gas filters

An apparatus and method for coating at least one substrate with an alumina hydrate film includes a coating vessel for containing a caustic coating solution, and at least one support within the coating vessel upon which are mounted substrates and porous containers. The porous containers hold aluminum metal for reacting with the caustic coating solution. A partition is situated between the porous containers and the substrates, which partition separates the gas bubbles produced by the reaction of the aluminum metal and the caustic coating solution from the substrates and which partition prevents the gas bubbles from contacting the substrates.

Apparatus and method for the manufacture of gas filters

Filter for treating a gas such as the exhaust gas stream from a diesel engine, which exhaust gas often conveys carbon particles into the atmosphere. The treating filter comprises a casing holding a plurality of serially arranged filter beds. The latter are comprised of monolith ceramic discs, and are maintained in spaced apart relationship by spacer rings to define a turbulation chamber between adjacent beds. Said beds are provided with an oxidation catalyst to promote incineration of the retained particles. The beds further serve to reinforce and support a non-rigid filtering media contained within the respective chambers.

Filter for treating a particle-carrying gaseous stream

The BTU value of a solid fuel is increased by subjecting the fuel to hydrothermal treatment in the presence of an added decarboxylation catalyst.

Coal beneficiation

Method for the in-situ deposition of a coating onto internal surfaces and matrix substrates of a body which defines one or more cavities. The single cavity, or the respective cavities packed with suitable substrates are provided with a predetermined amount of a solid reacting component to produce a suitable coating. The cavity is furnished with a liquid component which contacts the solid component, thereby forming a desired liquid coating reaction mixture. The latter is brought into contact with the cavity walls as well as with materials contained within the cavity, to achieve the desired coating of walls and matrix material.

Growing community of inventors

Wappingers Falls, NY, United States of America

Matthew A McMahon