William Marsh Rice University

Nitto-denko Corporation

Conyar Bv

Matteo Pasquali

Robert H Hauge

Virginia Angelica Davis

Rajesh Kumar Saini

Richard E Smalley

Ramesh Sivarajan

Haiqing Peng

Avishek Saha

Lars Martin Ericson

Angel A Marti-Arbona

Colin Young

A Nicholas Parra-Vasquez

James Mitchell Tour

Howard K Schmidt

Natnael Behabtu

Michael Wong

Dmitry Kosynkin

Takayuki Yamamoto

Satish Kumar

Wen-Fang Hwang

Micah J Green

Jay R Lomeda

Sreekumar Thaliyil Veedu

Amanda Lynn Duque

Jorrit Jong De

Marcin Jan Otto

Ryuta Kibe

A Nicholas G Parra-Vasquez

Ingrid Stepanek-Basset

Laurent Maillaud

Robert James Headrick

Francesca Mirri

Ammar S Alkhawaldeh

Manuel Joao Mendes

Pradeep K Rai

Chengmin Jiang

Anson Ma

Natneal Behabtu

Hua Fan

Ronald Edward Hoogerwerf

Ronald Folkert Waarbeek Ter

Virginia Davis

Colin C Young

The present invention relates to a composition comprising carbon nanotubes and a surfactant for forming a thin film on a substrate, and a method of manufacturing a thin film on a substrate by using an aqueous dispersion of the composition comprising carbon nanotubes and a surfactant.

Carbon nanotube coating composition

Methods for dissolving carbon materials such as, for example, graphite, graphite oxide, oxidized graphene nanoribbons and reduced graphene nanoribbons in a solvent containing at least one superacid are described herein. Both isotropic and liquid crystalline solutions can be produced, depending on the concentration of the carbon material The superacid solutions can be formed into articles such as, for example, fibers and films, mixed with other materials such as, for example, polymers, or used for functionalization of the carbon material. The superacid results in exfoliation of the carbon material to produce individual particles of the carbon material. In some embodiments, graphite or graphite oxide is dissolved in a solvent containing at least one superacid to form graphene or graphene oxide, which can be subsequently isolated. In some embodiments, liquid crystalline solutions of oxidized graphene nanoribbons in water are also described.

Dissolution of graphite, graphite and graphene nanoribbons in superacid solutions and manipulation thereof

In some embodiments, the present disclosure pertains to methods of forming a solution of single-walled carbon nanotube polyelectrolytes in a liquid crystalline phase. In some embodiments, such methods comprise: (a) providing single-walled carbon nanotube polyelectrolytes; and (b) mixing the single-walled polyelectrolytes with a polar aprotic solvent to form a mixture, where the mixing results in the formation of single-walled carbon nanotubes in the liquid crystalline phase. In some embodiments, the polar aprotic solvent comprises crown ether. In some embodiments, the present disclosure pertains to a method of making single-walled carbon nanotube fibers. Further embodiments of the present disclosure pertain to a method of making a single walled carbon nanotube composite. In some embodiments, the present disclosure pertains to an article comprising neat aligned carbon nanotubes.

Liquid crystals from single-walled carbon nanotube polyelectrolytes and their use for making various materials

In some embodiments, the present invention provides methods of immobilizing carbon nanotubes on a surface, wherein the method comprises: (1) mixing carbon nanotubes with a superacid to form a carbon nanotube solution; and (2) exposing the carbon nanotube solution to the surface. The exposing results in the immobilization of the carbon nanotubes on the surface. In some embodiments, the method occurs without the utilization of carbon nanotube wrapping molecules. Other embodiments of the present invention pertain to systems that comprise immobilized carbon nanotubes on a surface, as developed by the aforementioned methods.

Immobilized carbon nanotubes on various surfaces

We have discovered that size dependent solubility of large fullerenes in strong acids is dependent on acid strength. This provides a scalable method for separating large fullerenes by size. According to some embodiments, a method for processing a fullerene starting material comprises large fullerenes comprises mixing the starting material with a first concentrated sulfuric acid solution so as to obtain a first dispersion comprising a first portion of the large fullerenes solubilized in the first concentrated sulfuric acid solution.

Methods for solubilizing and separating large fullerenes

According to some embodiments, a method for separating a first fraction of a single wall carbon nanotubes and a second fraction of single wall carbon nanotubes includes, but is not limited to: flowing a solution comprising the nanotubes into a dielectrophoresis chamber; applying a DC voltage, in combination with an AC voltage, to the dielectrophoresis chamber; and collecting a first eluent from the dielectrophoresis chamber, wherein the first eluent comprises the first fraction and is depleted of the second fraction, wherein the first and second fractions differ by at least one of conductivity, diameter, length, and combinations thereof.

Flow dielectrophoretic separation of single wall carbon nanotubes

New methods for the synthesis of nanocrystals/quantum dots are disclosed. The methods comprise use of reasonably-priced and commercially available heat transfer fluids (such as Dowtherm&#xae; A) as solvents to synthesize CdSe nanocrystals. Separation of nucleation and growth is achieved by quenching the reaction solution with relatively cold (room temperature) solvent to lower the solution temperature. Quenching may be followed by raising the solution temperature, to allow controlled growth to take place.

Solvents and new method for the synthesis of CdSe semiconductor nanocrystals

The present invention involves alewives of highly aligned single-wall carbon nanotubes (SWNT), process for making the same and compositions thereof. The present invention provides a method for effectively making carbon alewives, which are discrete, acicular-shaped aggregates of aligned single-wall carbon nanotubes and resemble the Atlantic fish of the same name. Single-wall carbon nanotube alewives can be conveniently dispersed in materials such as polymers, ceramics, metals, metal oxides and liquids. The process for preparing the alewives comprises mixing single-wall carbon nanotubes with 100% sulfuric acid or a superacid, heating and stirring, and slowly introducing water into the single-wall carbon nanotube/acid mixture to form the alewives. The alewives can be recovered, washed and dried. The properties of the single-wall carbon nanotubes are retained in the alewives.

Single-wall carbon nanotube alewives, process for making, and compositions thereof

The present invention involves fibers of highly aligned single-wall carbon nanotubes and a process for making the same. The present invention provides a method for effectively dispersing single-wall carbon nanotubes. The process for dispersing the single-wall carbon nanotubes comprises mixing single-wall carbon nanotubes with 100% sulfuric acid or a superacid, heating and stirring under an inert, oxygen-free environment. The single-wall carbon nanotube/acid mixture is wet spun into a coagulant to form the single-wall carbon nanotube fibers. The fibers are recovered, washed and dried. The single-wall carbon nanotubes were highly aligned in the fibers, as determined by Raman spectroscopy analysis.

Fibers of aligned single-wall carbon nanotubes and process for making the same

The present invention is directed to at least one method and at least one apparatus for determining the length of single-wall carbon nanotubes (SWNTs). The method generally comprises the steps of: dispersing a sample of SWNTs into a suitable dispersing medium to form a solvent-suspension of solvent-suspended SWNTs; determining the mean SWNT diameter of the solvent-suspended SWNTs; introducing the solvent-suspended SWNTs into a viscosity-measuring device; obtaining a specific viscosity for the SWNT solvent-suspension; and determining the length of the SWNTs based upon the specific viscosity by solving, for example, the Kirkwood-Auer equation corrected by Batchelor's formula for the drag on a slender cylinder for 'L,' to determine the length of the SWNTs. The apparatus generally comprises: a SWNT sample introduction mechanism; a dispersal chamber; a SWNT radius-determination chamber; and a viscosity determining chamber, wherein the SWNT sample introduction mechanism, the dispersal chamber, the SWNT radius-determination chamber, and the viscosity determination chamber are each operatively connected to at least one of the others.

Method and apparatus for determining the length of single-walled carbon nanotubes

Growing community of inventors

Houston, TX, United States of America

Matteo Pasquali