Chisso Corporation

Nitto Boseki Co., Ltd.

Masuhito Ohgushi

Isao Koga

Yohji Terui

Tohru Kitahara

Kenichi Watanabe

Toshiya Sawai

Hideharu Waketa

Yoshiharu Suzuki

Hideaki Kakiuchi

Motoharu Murakoshi

Masashi Ohno

Yukio Okada

Hiroshi Ohtsuka

Tsutomu Asaba

Kenichi Goshokubo

Kiminori Ishii

Takeo Wakui

Hironobu Hoshi

Silane coupling agents and a method of preparing the coupling agents are provided in which a silane coupling agent is prepared by reacting 2.3 to 4.0 mols of a haloalkylalkoxysilane with 1 mol of a diamine having N atoms to which 4 active hydrogen atoms are bound, by reacting 1.3 to 3.0 mols of a haloalkylalkoxysilane with 1 mol of a diamine having N atoms to which 3 active hydrogen atoms are bound and to which one alkylsilyl group is bound, or by reacting 0.3 to 2.0 mols of a haloalkylalkoxysilane with 1 mol of a diamine having N atoms to which 2 active hydrogen atoms are bound and to which 2 alkylsilyl groups are bound. In addition, a silane coupling agent may be prepared by reacting the diamine with a haloalkylalkoxysilane and a halomethylstyrene.

Silane coupling agent and glass fiber product for laminates

A glass fiber product for laminates is provided having excellent epoxy resin impregnation properties and solvent resistance, high soldering heat resistance, good heat shock resistance and low water adsorption properties, and to a silane coupling agent for providing such a glass fiber product. The silane coupling agent is prepared by reacting 2.3 to 4.0 mols of a haloalkylalkoxysilane with 1 mol of a diamine having N atoms to which 4 active hydrogen atoms are bound, a silane coupling agent prepared by reacting 1.3 to 3.0 mols of a haloalkylalkoxysilane with 1 mol of a diamine having N atoms to which 3 active hydrogen atoms are bound and to which one alkylsilyl group is bound, or a silane coupling agent prepared by reacting 0.3 to 2.0 mols of a haloalkylalkoxysilane with 1 mol of a diamine having N atoms to which 2 active hydrogen atoms are bound and to which 2 alkylsilyl groups are bound. A silane coupling agent prepared by reacting the diamine with a haloalkylalkoxysilane and a halomethylstyrene is also provided as is a glass fiber product for laminates treated with the above-mentioned silane coupling agent.

A thermoset acrylic resin composition for coating metallic materials, particularly stainless steel, having a superior adhesion thereonto and hence a superior resistance to forming after coated, and a stainless steel piece coated with a coating material comprising the above composition, followed by baking, and having a superior colorability and endurability, are provided, which composition is obtained by radical-copolymerizing (a) an acrylic or methacrylic acid ester having 1-12 C in the ester moiety, in 40-80% by weight, (b) a hydroxyl group- or epoxy group-containing acrylic or methacrylic acid ester, in 20-5% by weight, (c) a vinyl group-containing polysiloxane in 20-0.01% by weight and (d) a vinyl group-containing silane compound in 20-2% by weight, these % by weight being based on the total weight of monomers (a)-(d).

Thermoset acrylic resin composition for coating metallic materials and

A method for producing mono-substituted dichlorosilanes selectively with a high yield from dichlorosilane is provided. According to this method, dichlorosilane and a specified compound having a double bond at .alpha.-position are reacted in the presence of a catalyst which is a homogeneous complex of ruthenium, rhodium, nickel or platinum, and a phosphine compound, or is a ruthenium chloride.

Method for producing substituted dichlorosilane

Novel disubstituted dichlorosilane compounds which have two different specified substituents and are necessary as monomers for preparing special silicone resin are provided and a method for producing same without accompaniment of by-product production is also provided.

Novel disubstituted dichlorosilane and method for producing same

In the method of producing 3-chloropropyltrichlorosilane by the addition reaction of trichlorosilane to allyl chloride, [Pt(PPh.sub.3).sub.2 Cl.sub.2 ] is used as the catalyst for the reaction. Side reactions are suppressed to give a high yield of the product.

Method for producing 3-chloropropyltrichlorosilane

Substituted phenethyldichlorosilanes having a longer chain alkyl group and diphenethyldichlorosilane which are useful as compounds for improving heat-resisting property and other properties of silicone-oils, -rubbers and -varnishes which are used as electric insulating materials, lubricating oils, water-repelling agents, paintings, releasing agents, etc. are provided. A method for producing these compounds with a high yield without producing by-products is also provided.

Growing community of inventors

Minamatashi, Japan

Masuhito Ohgushi