Mitsubishi Chemical Corporation

Nippon Chemi-con Corporation

Honda Motor Co., Ltd.

Mitsubishi Petrochemical Company Limited

Alps Alpine Co., Ltd.

Masayuki Takeda

Atsushi Hatakeyama

Makoto Ue

Masashi Ozawa

Hiroo Miyauchi

Hideo Nagaoka

Takeshi Fujino

Masahiro Takehara

Byoungju Lee

Takako Takahashi

Kenji Sato

Minoru Wada

Yasuhiro Matsumoto

Tomohiro Sato

Tatsunori Tsuji

Daisuke Noda

Tomohiro Satoh

Masahi Ozawa

Provided is an electrolyte containing tetrafluoroaluminate ions, which is advantageous in that the electrolyte can be prevented from leaking from both the cathode and the anode in an electrolytic capacitor. An electrolyte for electrolytic capacitor, which comprises: (A) a tetrafluoroaluminate ion, and (B) at least one compound selected from the group consisting of: (1) at least one compound selected from the group consisting of a phthalimide, a quinoline, a dioxime, a nitrophenol and an amino group-containing aromatic carboxylic acid; (2) at least one compound selected from the group consisting of an aluminum complex, a boric acid ester and a silicic acid ester; (3) at least one compound selected from the group consisting of a monocyclic quinone compound and a bicyclic quinone compound; (4) a tricyclic or higher polycyclic quinone compound; and (5) at least one compound selected from a heteropoly acid and a salt thereof,

Electrolysis solution for electrolytic capacitor, and electrolytic capacitor

An electrolytic capacitor having a low impedance characteristic, having a high withstand voltage characteristic of 100V class, wherein the electrolytic capacitor provides an excellent high temperature life characteristic and an excellent leakage characteristic. The electrolyte solution containing the aluminum tetrafluoride salt is used. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic. Moreover, the aforementioned electrolyte solution is used, and a foil showing noble potential at least in the electrolyte solution than the electrode potential of the cathode tab, or a cathode electrode foil subjected to chemical treatment is used as the cathode electrode foil, so as to obtain an excellent leakage characteristic.

Electrolytic capacitor

An electrolytic capacitor having a low impedance characteristic, having a high withstand voltage characteristic of 100V class, wherein the electrolytic capacitor provides an excellent high temperature life characteristic. The electrolyte solution containing the aluminum tetrafluoride salt is used. The moisture content of the capacitor element is adjusted to 0.7% by weight or less, wit respect to the weight of the capacitor element, preferably 0.5% by weight or less, and most preferably 0.4% by weight or less. In this way, the electrolytic capacitor having the low impedance characteristic and the high resistance voltage characteristic, and the excellent high temperature life characteristic is provided.

Electrolytic capacitor manufacturing method

An electrolyte for an electrolytic capacitor which is high in electrolytic conductivity, excellent in heat stability and high in withstand voltage. An electrolyte for an electrolytic capacitor comprising a tetrafluoroaluminate ion; and an electrolyte for an electrolytic capacitor containing a salt and a solvent, characterized in that electrolytic conductivity X (mS&#xb7;cm) at 25&#xb0; C. and withstand voltage Y (V) of a capacitor satisfy the relationships of formulae (I): Y&#x2267;&#x2212;7.5X+150, and X&#x2267;4, Y&#x3e;0.

Electrolyte for electrolytic capacitor and electrolytic capacitor using the same

The present invention provides an electric double layer capacitor which has electrodes made of an alkali-activated carbon, prepared from a graphitic material, useful in manufacturing high-capacitance capacitors and which has an electrolytic solution containing chain carbonate and/or cyclic carbonate. Even if the electric double layer capacitor is used under high-temperature and high-voltage conditions, chain carbonate and/or cyclic carbonate is prevented from being degraded and the amount of generated gas is slight. The electric double layer capacitor has high initial performance and energy density and the performance of the electric double layer capacitor is maintained high. The electrolytic solution contains a quaternary ammonium salt except for a quaternary ammonium salt containing a carbon atom being bonded to the quaternary nitrogen atom and being bonded to other nitrogen atom than the quaternary nitrogen atom, chain carbonate and/or cyclic carbonate, and a solvent containing a carboxylic ester which contains five or more carbon atoms and which has two or more carboxylic ester bonds.

Electric double layer capacitor and electrolytic solution therefor

Electrolyte solution and an electrolytic capacitor using it having a low impedance characteristic, having a high withstand voltage characteristic of 100V class, and a high temperature life characteristic is provided. The electrolyte solution containing an aluminum tetrafluoride salt, and a solvent with high boiling point, such as sulfolane, 3-methyl sulfolane, and 2,4-dimethyl sulfolane, and the like are used. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic.

Electrolyte for electrolytic capacitor and electrolytic capacitor containing the same

There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125&#xb0; C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously used in an aluminum electrolytic capacitor.

Electrolyte for electrolytic capacitor, electrolytic capacitor and process for producing tetrafluoroaluminate salt of organic onium

In an electric double layer capacitor and electrolytic solution, decomposition of at least one of an open-chain carbonate and a cyclic carbonate can be controlled under high temperature conditions, initial performance and maintained ratio of capacitance are superior, and energy density is high, when graphitized alkali-activated carbon is used as an electrode material and at least one of an open-chain carbonate and a cyclic carbonate is used in an organic electrolytic solution. The electric double layer capacitor includes electrodes containing alkali-activated carbon including graphitized carbon material, and an organic electrolytic solution in which a supporting salt is dissolved in solvent including aromatic carboxylate and at least one of an open-chain carbonate and a cyclic carbonate, in which the content of the aromatic carboxylate is not more than 50 weight % relative to the total weight of the solvent.

An electrolytic capacitor having a low impedance characteristic, and a high withstand voltage characteristic in the 100V class, provides excellent high temperature life and leakage characteristics. An electrolyte solution containing an aluminum tetrafluoride salt is used. Moreover, a ceramics coating layer or an insulating synthetic resin layer is formed at a contact portion with a sealing component of a rivet or a cathode leading means. Alternatively, a partial cross-linking peroxide butyl rubber with added peroxide as a cross-linking agent to a butyl rubber polymer containing isobutylene, isoprene, and divinylbenzene copolymer is used as the sealing member. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic.

An object of the present invention is to provide an electrolyte for an electrolytic capacitor, which is advantageous not only in that both electric conductivity and withstand voltage property are high, but also in that thermal stability is excellent, and an electrolytic capacitor using the electrolyte. Specifically, the present invention provides an electrolyte for an electrolytic capacitor, comprising a solvent, at least one quaternary amidinium salt selected from the group consisting of a quaternary amidinium salt of a hydroxy-substituted aromatic monocarboxylic acid and a quaternary amidinium salt of phthalic acid, and metal oxide particles, and an electrolytic capacitor using the electrolyte.

Electrolytic solution for electrolytic capacitor and electrolytic capacitor using the same

An electrical double-layer capacitor showing a sleight increase of resistance when used under continuous application of high voltage and maintaining high energy residual ratio after standing for a long time includes an electrode element including a pair of electrodes disposed opposite to each other with a separator interposed therebetween, and is impregnated with a nonaqueous electrolyte solution prepared by dissolving quaternary ammonium salts into cyclic carbonates and containing impurities of 30 ppm or less of glycols, 30 ppm or less of primary alcohols and less than 20 ppm of tertiary amines. The water content may be 50 ppm or less. The quaternary ammonium salt may be triethylmethylammonium tetrafluoroborate. The cyclic carbonate may be propylene carbonate. The nonaqueous electrolyte solution may have a concentration of 0.1 to 2.5 mol/liter. The electrode may be a polarizable electrode composed of activated carbon.

Electrical double-layer capacitor

An N-alkyl-N'-methylimidazolinium salt of an organic acid is prepared in high purity and in high yield by (a) preparing an N-alkyl-N'-methylimidazolinium methyl carbonate in a quaternization reaction by methylating an N-alkylimidazoline with dimethyl carbonate and (b) reacting the resulting N-alkyl-N'-methylimidazolinium methyl carbonate with an organic acid, in an anion exchange reaction, wherein the reaction of each step is conducted in methanol solvent.

Growing community of inventors

Mie, Japan

Masayuki Takeda