Nippon Electric Glass Co., Ltd.

Other

Masayuki Ninomiya

Akihiko Sakamoto

Takehiro Shibuya

Yoshio Hashibe

Tadashi Takahashi

Ryo Nagase

Akira Matsui

Takahiro Matano

Seiko Mitachi

Yoshinori Morita

Yoshiaki Takeuchi

Takashi Tanabe

Kiyoshi Katagi

Kiyoyuki Okunaga

Hirokazu Takeuchi

Katsumi Inada

Toyohide Kurahashi

In order to provide a ferrule for an optical-fiber connector used for good organization of an optical communication network, the ferrule for an optical-fiber connector is made of a crystallized glass having a composition which consists essentially of, by weight percent, 60-70% of SiO,, 16-25% of Al,O,, 1.5-3% of Li,O, 0.5-2.5% of MgO, 1.3-4.5% of TiO,, 0.5-3% of ZrO,, 2-6.5% of TiO,&plus;ZrO,, 1-5.5% of K,O, 0-7% of ZnO, and 0-3% of BaO. The crystallized glass includes 30-70 volume % precipitation of &bgr;-spodumene solid solution or &bgr;-quartz solid solution having an average grain size not greater than 2 &mgr;m. In addition, the crystallized glass has a bend strength of 200 MPa or more and a thermal expansion coefficient of &minus;10&tilde;50&times;10,/&deg; C. at a temperature between &minus;50 and 150&deg; C.

Ferrule for optical-fiber connector

In order to provide an enamel frit composition for a low-expansion crystallized glass, capable of producing an enamel coating excellent in abrasion resistance and acid resistance without occurrence of cracks by using glass powder which does not contain any harmful component such as PbO, and to provide an enamel-coated low-expansion crystallized glass plate using the enamel frit composition, the enamel frit composition for a low-expansion crystallized glass essentially consists 40-98 wt % glass powder, 1-55 wt % coloring pigment, and 0-54 wt % filler. The glass powder consists, by weight, of 55-72% SiO.sub.2, 4-8% Al.sub.2 O.sub.3, 14-22% B.sub.2 O.sub.3, 2-4% BaO, 5.1-15% Na.sub.2 O, 0-2% Li.sub.2 O, 0-2.8% K.sub.2 O, and 0-2% F.sub.2.

Enamel frit composition for a low-expansion crystallized glass and

A fire-protection and safety composite glass panel includes a fireproof glass plate and a film of fluorocarbon resin of a chain molecular structure type. The film is bonded onto one of opposite side surfaces of the fireproof glass plate by the thermo-compression bonding. The fluorocarbon resin is a copolymer of at least three kinds of monomers. It may be arranged that another film of the fluorocarbon resin is further bonded onto the other side surface of the fireproof glass plate by the thermo-compression bonding. Another glass panel may be arranged that a plurality of fireproof glass plates are attached with a film of the foregoing fluorocarbon resin interposed between adjacent glass plates through the thermo-compression bonding. Those glass panels can be used as glass plates in fire-protective windows and doors.

Fire-protection and safety composite glass panel

In a fire-protection and safety glass panel having a transparent appearance and dual functions as a fire protection glass for shutting out flame and smoke for a long period of time upon occurrence of fire and as a safety glass which is neither shattered into pieces and nor forms any through hole if it is broken in an ordinary life, a PET (polyethylene terephthalate) film (12) is arranged between a first glass plate (10) and a second glass plate (11). The first and the second glass plates (10 and 11) and the PET film (12) are adhered through transparent acrylic adhesive agent layers (13 and 14), respectively. An intermediate resin layer comprises the PET film (12) and the adhesive agent layers (13 and 14) and has a thickness between 75 and 200 .mu.m.

Fire-protection and safety glass panel

Marble-like glass ceramic which consists essentially of, by weight percent, 50-75% SiO.sub.2, 1-15% Al.sub.2 O.sub.3, 6-16.5% CaO, 0.1-5% Li.sub.2 O, 0-1.5% B.sub.2 O.sub.3, 10-17.5% CaO+Li.sub.2 O+B.sub.2 O.sub.3, 2.5-12% ZnO, 0-12% BaO, 0.1-15% Na.sub.2 O+K.sub.2 O, and 0-10% coloring agents, said ceramic comprising .beta.-wollastonite precipitated as a major crystal. The coloring agents comprises at least one selected from a group of Fe.sub.2 O.sub.3, NiO, CoO, MnO.sub.2, Cr.sub.2 O.sub.3, and CuO. The marble-like glass ceramic may further comprises at least one of As.sub.2 O.sub.3 and Sb.sub.2 O.sub.3 of up to 1% as refining agents, at least one of up to 1.5% MgO and up to 1.5% SrO so as to improve meltability of the glass, and at least one of up to 1% TiO.sub.2, up to 1% ZrO.sub.2, and up to 1% P.sub.2 O.sub.5 so as to make the glass stable and less devitrifiable.

Marble-like glass ceramic

A crystallized glass having natural-marble-like surface patterns comprising 45 to 75 wt. % of SiO.sub.2, 1 to 25 wt. % of Al.sub.2 O.sub.3, 1 to 20 wt. % of CaO, 0.5 to 17 wt. % of MgO, 0.1 to 18 wt. % of BaO, 0 to 18 wt. % of ZnO, 1 to 15 wt. % of Na.sub.2 O, 0 to 7 wt. % of K.sub.2 O, 0 to 5 wt. % of Li.sub.2 O, 0 to 10 wt. % of B.sub.2 O.sub.3, 0 to 10 wt. % of P.sub.2 O.sub.5, 0 to 1 wt. % of As.sub.2 O.sub.3, and 0 to 1 wt. % of Sb.sub.2 O.sub.3, substantially free from nucleating agent, in which diopside type crystals are precipitated, and a method of producing the crystallized glass are disclosed.

Crystallized glass having natural-marble-like surface patterns and

A high-mechanical strength biocompatible crystallized glass essentially comprises both crystallines consisting of tetrasilicic fluorine mica series and calcium phosphate series. The crystallized glass has substantially non-sodium oxide and useful in a dental medical care, as repairing material of tooth.

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Shiga, Japan

Masayuki Ninomiya