Hitachi Metals, Ltd.

Kurosaki Refractories Co., Ltd.

Masatoshi Kawata

Katsumi Morikawa

Norio Takahashi

Mitsuru Yano

Tomoyuki Kido

Masatoshi Nakamizo

A ceramic coating bonded to an iron tubular member comprising a bonding layer formed on a surface of the iron tubular member by a reaction of an iron tubular oxide layer of the iron tubular member and a silicate; and an iron oxide diffusion-preventing layer produced from fine metal oxide particles or an organometallic binder by firing on a surface of the bonding layer. The ceramic coating may further comprises an oxidation-preventing layer, a heat-insulating layer, a refractory layer or a thin dense protective layer. It may be produced by coating the surface of the iron tubular member with a silicate binder to form a layer which is then converted to a bonding layer by a heat treatment in a steam atmosphere; coating the surface of the bonding layer with fine metal oxide particles or an organometallic binder to form an iron oxide diffusion-preventing layer; and after curing and drying firing the resulting ceramic coating in an atmosphere having an oxygen partial pressure of 10 mmHg or less.

Ceramic coating bonded to iron member

A ceramic coating bonded to a metal member comprising a bonding layer formed by the reaction of an oxide layer formed on a surface of said metal member in advance and a silicated; and an anti-oxidizing first ceramic layer formed on said bonding layer and comprising inorganic flaky particles burned to have a cross-linked laminate structure.

Ceramic coating bonded to metal member

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Kitakyushu, Japan

Masatoshi Kawata