Toray Industries, Inc.

Masatoshi Iwamoto

Tadao Fukumoto

Akihiko Kishimoto

Koji Onishi

Shiro Kataoka

Kazuhisa Yano

Hideyuki Umetsu

Kazumasa Chiba

Osamu Togashi

Takuya Ogawa

Thermoplastic resin compositions consisting of 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, further containing (C) 0.1-10% of a modified vinyl polymer containing carboxyl groups, are permanently antistatic, excellent in mechanical properties represented by impact resistance, heat resistance moldability and also in the appearance and gloss of the moldings, and suitable for housings of optical or magnetic recording media.

Housing and resin composition including polyether ester amide,

A process for producing a molded product having excellent heat resistance, which including forming a composition including a crystalline polyamide by mixing together (a) 50-90% by weight of a hexamethylene adipamide component, (b) 5-40% by weight of a hexamethylene terephthalamide component, (c) 5-30% by weight of a hexamethylene isophthalamide component, components (a), (b) and (c) being based on the weight of the crystalline polyamide, and (d) 1-150 parts by weight of an elastomer, based upon 100 parts by weight of the crystalline polyamide; forming a melt polymer from the composition and applying shear to the melt polymer, the melting point (Tm) and crystallization temperature (Tc) of the crystalline polyamide being Tm.gtoreq.225.degree. C. and Tc.ltoreq.230.degree. C., respectively, and the melt viscosity of the crystalline polyamide varying greatly depending on the shear rate applied to the melt polymer and satisfying formulae (I) and (II):

Process for producing polyamide blow molded product

Thermoplastic resin compositions consisting of 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, further containing (C) 0.1-10% of a modified vinyl polymer containing carboxyl groups, area permanently antistatic, excellent in mechanical properties represented by impact resistance, heat resistance moldability and also in the appearance and gloss of the moldings, and suitable for housings of optical or magnetic recording media.

Instrinsically antistatic thermoplastic resin compositions housing and

The resin composition of the present invention allows the molding of a hollow molded product, able to stably form a long parison and having a three-dimensionally curved shape, by the formation of a copolyamide having a melting point of 225.degree. C. or more and a crystallization temperature of 230.degree. C. or less obtained by a polymerization of 66, 6T and 6I components at a specific compounding ratio.

Blow molding process

Housing and thermoplastic resin compositions including polyether ester

A flame retardant nylon polymer moulding composition comprises a 6T/66 copolyamide or 6T/6 copolyamide and a specific flame-retardant and auxiliary flame-retardant. The composition can be made into molded items for electric and electronic parts, automotive parts, and housing owing to their high degree of flame retardancy, good external appearance, and good heat resistance.

Flame-retardant nylon resin composition

A transparent polyester-ester amide having a permanently antistatic property is obtained by copolymerizing (a) an aminocarboxylic acid, a lactam, or a salt derived from a diamine and a dicarboxylic acid; (b) a diol of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are an ethylene oxide or propylene oxide group, Y is covalent bond, alkylene, alkylidene, cycloalkylidene, arylalkylidene, O, SO, SO.sub.2, CO, S, CF.sub.2, C(CF.sub.3).sub.2 or NH, X is H, alkyl, halogen, sulfonic acid or salt thereof, l is 0 or an integer of 1-4, and m and n an integer of 1-15; (c) a poly(alkylene oxide)glycol or a diol of the formula:

Polyether-ester amide and permanently antistatic resin composition

Disclosed is a resin composition comprising (A) from 1-98 wt. parts of a graft copolymer obtained by graft-polymerizing (a) 5-80 wt. % of a rubbery polymer and (b) 95-20 wt. % of a monomer mixture consisting of 40-90 wt. % of an aromatic vinyl compound, 60-10 wt. % of a vinyl cyanide compound and 0-50 wt. % of another ethylenically unsaturated compound copolymerizable therewith, (B) 1-40 wt. % parts of a modified copolymer selected from (B.sub.1) a modified vinyl copolymer obtained by polymerizing (a) 40-90 wt. % of an aromatic vinyl compound, (b) 60-10 wt. % of a vinyl cyanide compound, (c) 0.01-10 wt. % of a monomer having an epoxy, carboxyl or amino group, and (d) 0-40 wt. % of another ethylenically unsaturated compound, and (B.sub.2) a modified olefinic copolymer obtaind by copolymerizing (e) 50-95 wt. % of ethylene or propylene, (f) 0.1-20 wt. % of a monomer having an epoxy, carboxyl or amino group, and (g) 0-40 wt. % of another ethylenically unsaturated compound, (C) 1-60 wt. parts of an imidized acrylic resin, and (D) from 0-90 wt. parts of a vinyl copolymer obtained by polymerizing (a) 40-90 wt. % of an aromatic vinyl compound, (b) 60-10 wt. % of a vinyl cyanide compound and (c) 0-40 wt. % of another ethylenically unsaturated compound, wherein the content of the rubbery polymer (a) in the graft copolymer (A) is 5 to 40 wt. % based on the resin composition. This resin composition gives a shaped article having a delustered and pleasing appearance and a good impact resistance.

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Aichi, Japan

Masatoshi Iwamoto