Sumitomo Chemical Company, Limited

Osaka University

Eisai R&d Management Co., Ltd.

Eisai Company, Limited

Masato Ueda

Takanobu Noguchi

Yutaka Ie

Yoshio Aso

Hitoshi Harada

Shuhei Miyazawa

Masahiro Miura

Tetsuya Satoh

Hiroyuki Watanabe

Junichi Nagakawa

Makoto Kitano

Isao Yahagi

Daisuke Iida

Masahiro Yasuda

Chizu Sekine

Tetsuya Kawahara

Yoshihiko Kotake

Osamu Asano

Nobuhisa Watanabe

Atsuhiko Kubota

Masanobu Shinoda

Hideaki Fujisaki

Nobuyuki Yasuda

Fumi Yamaguchi

Yoshikazu Umemoto

Hiroki Terauchi

Masashi Nitani

Masashi Ueta

Kenichi Nakayama

Hideyuki Higashimura

Toshihiro Ohnishi

Shigeru Sasaki

Yoshiaki Tsubata

Jun Kumagai

Yasuhiro Kabasawa

Atsushi Kamada

Kazuei Ohuchi

Hiroshi Ishihara

Takenori Osada

Kenta Tanaka

Akio Tanaka

Masaaki Yokoyama

Masamitsu Ishitobi

Yasuaki Abe

Makoto Nakagawa

Yoshiko Nakamura

Yusuke Matsuura

Fumitoshi Kakiuchi

Hayato Tsurugi

Makoto Okabe

Manabu Sasaki

Yukio Fujii

Sachiko Kikuchi

Kazuo Hirota

Masahiro c/o Osaka University Miura

Provided is a fused ring compound which can exhibit sufficient charge transport properties and excellent solubility in a solvent. The fused ring compound is represented by general formula (1), wherein Rand Reach independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group, an optionally substituted aryl group having 6 to 60 carbon atoms, an optionally substituted heterocyclic group having 4 to 60 carbon atoms, or a cyano group, provided that at least one of Rand Ris not a hydrogen atom; Rand Reach independently represent a monovalent group, and n and m each independently denote an integer of 0 to 2; and Yand Yare each independently a divalent group comprising a sulfur atom, an oxygen atom, a nitrogen atom, a selenium atom or a tellurium atom.

Fused ring compound and method for producing same, polymer, organic thin film containing those, and organic thin film device and organic thin film transistor comprising such organic thin film

The present invention provides a heterocyclic compound of the following general formula (I): 

Heterocyclic compound and heterocyclic polymers

It is an object of the present invention to provide a fused ring compound which can exhibit sufficient charge transport properties and which has excellent solubility in a solvent. The fused ring compound according to the present invention is represented by the following general formula (1), wherein Rand Reach independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group, an optionally substituted aryl group having 6 to 60 carbon atoms, an optionally substituted heterocyclic group having 4 to 60 carbon atoms, or a cyano group, provided that at least one of Rand Ris not a hydrogen atom; Rand Reach independently represent a monovalent group, and n and m each independently denote an integer of 0 to 2; and Yand Yare each independently a divalent group comprising a sulfur atom, an oxygen atom, a nitrogen atom, a selenium atom or a tellurium atom.

Nitrogen-containing fused ring compound having at least one structural unit selected from the group consisting of a structural unit represented by the formula (1-1) and a structural unit represented by the formula (1-2).

Nitrogen-containing fused ring compound, nitrogen-containing fused ring polymer, organic thin film, and organic thin film element

It is an object of the present invention to provide a nitrogen-containing condensed ring compound, which can be used as an organic n-type semiconductor having an excellent electron transport property and which is also excellent in terms of solubility in an organic solvent. The nitrogen-containing condensed ring compound of the present invention has a structural unit represented by the following formula (1-1) or formula (1-2):  wherein Arrepresents an aromatic ring; one of Yand Yrepresents a single bond, and the other represents &#x2014;C(R)(R)&#x2014; or &#x2014;C(&#x2550;X)&#x2014;; one of Yand Yrepresents a single bond, and) the other represents &#x2014;C(R)(R)&#x2014; or &#x2014;C(&#x2550;X)&#x2014;, and one of Yto Yrepresents &#x2014;C(R)(R)&#x2014; or &#x2014;C(R)(R)&#x2014;; at least one of Wand Wrepresents &#x2014;N&#x2550;; and Zand Zeach represent any one of the groups represented by the formula (i) to the formula (ix).

Nitrogen-containing condensed ring compound, nitrogen-containing condensed ring polymer, organic thin film, and organic thin film element

According to the first invention group there are provided conjugated compounds having two or more groups represented by the following formula (I) or the following formula (II): wherein one of Ar and Ar' represents a C6 or greater divalent aromatic hydrocarbon group and the other represents a C4 or greater divalent heterocyclic group, wherein the groups each may have a substituent, with the proviso that the groups as a whole contain no fluorine atoms, Rand Reach independently represent a hydrogen atom, a halogen atom or a monovalent group, and Ar&#x2033; represents a trivalent aromatic hydrocarbon or trivalent heterocyclic group; when the conjugated compound has two or more groups represented by formula (I), the portion excluding these groups contain no fluorine atoms. According to the second group of the present invention there are provided nitrogen-containing fused-ring compounds represented by the following formula (&#x3b1;-I): in formula (&#x3b1;-I), Rand Reach independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Zand Zeach independently represent any one of the groups represented by the following formulas (&#x3b1;-i)-(&#x3b1;-ix); wherein R, R, Rand Reach independently represent a hydrogen atom, a halogen atom or a monovalent group, and Rand Rmay bond together to form a ring, the left side and the right side of the group represented by formula (&#x3b1;-viii) may be interchanged.

Conjugated compound, nitrogenated condensed-ring compound, nitrogenated condensed-ring polymer, organic thin film, and organic thin film element

An object of the present invention is to provide a fused ring compound which can show sufficient charge transport properties and also has excellent solubility in a solvent. The fused ring compound of the present invention is represented by the following formula (1): wherein Rand Reach independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group having 3 or more carbon atoms in the alkyl moiety thereof, an aryl group which may have a substituent, a monovalent heterocyclic group which may have a substituent, or a cyano group, wherein at least one of Rand Ris not a hydrogen atom; Rand Reach independently represent a monovalent group and m and n are an integer of 0 to 2; Y, Y, Yand Yare a predetermined divalent group containing S, O, N, Se, Te or a double bond; Yand Yare selected so that a ring containing the groups forms a five-membered ring; and Yand Yare selected so that a ring containing the groups forms a five or six-membered ring.

Fused ring compound, method for producing the same, polymer, organic thin film containing the compound and/or polymer, and organic thin film device and organic thin film transistor each comprising the organic thin film

It is an object of the present invention to provide a method for manufacturing a fused ring compound, with which a fused ring compound that has excellent charge transport property and that has excellent solubility in solvents can be obtained efficiently. The method of the present invention for manufacturing a fused ring compound involves reacting a compound expressed by the following General Formula (1a) and a compound expressed by the following General Formula (1b) in the presence of an amine and a metal complex catalyst: 

Process for production of fused ring compound

A method of producing an aromatic compound of the following formula (3) comprising reacting a compound of the following formula (1) with an olefin compound of the following formula (2) in the presence of a transition metal complex: (wherein, an Arring represents an aromatic hydrocarbon ring or aromatic heterocyclic ring, an Arring represents a heterocyclic ring containing Xand N*, and the Xrepresents a nitrogen atom or carbon atom and the N represents a nitrogen atom connecting via a double bond to either one of two adjacent atoms in the Arring.) (wherein, R, R, Rand Rrepresent each independently a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 18 carbon atoms.) (wherein, Ar, Ar, X, N*, R, Rand Rrepresent the same meanings as described above.).

Method of producing aromatic compound

Fluorinated compounds of the invention are represented by the following general formula (I): 

Fluorine-containing compound and method for producing same, fluorine-containing polymer, organic thin film, and organic thin film device

A novel chemical compound useful as a therapeutic or prophylactic agent for acid-related diseases is provided, which has an excellent inhibitory effect against gastric acid secretion, an excellent effect of maintaining the inhibitory effect against gastric acid secretion, thereby maintaining intragastric pH high for a long time, and having more safety and appropriate physicochemical stability. Provided is a compound represented by where Rand Rmay be the same or different and each represent a hydrogen atom or a C1-C6 alkyl group; Rrepresents (5,5-dimethyl-1,3-dioxan-2-yl)methoxy group, 5,7-dioxaspiro[2.5]oct-6-ylmethoxy group, 1,5,9-trioxaspiro[5.5]undec-3-ylmethoxy group, or (2,2-dimethyl-1,3-dioxan-5-yl)methoxy group; R, R, Rand Rrepresent a hydrogen atom, halogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C1-C6 alkoxy group or C1-C6 haloalkoxy group; and Wrepresents a single bond, methylene or ethylene group, a salt thereof or a solvate of these.

Benzimidazole compound

A polymer having a repeating unit represented by the following general formula (I) and a ferrocene-based reduction potential of &#x2212;1.5 to &#x2212;0.5 V as measured by a cyclic voltammetry method 

Polymer having unit obtained by condensation of difluorocyclopentanedione ring and aromatic ring, organic thin film using the same, and organic thin film device

The present invention relates to a polymer film comprising a polymer having liquid crystallinity, having a number-average molecular weight in terms of polystyrene of 10to 10and having an electron mobility or hole mobility of 10cm/Vs or more, and having a film thickness in the range from 1 nm to 100 &#x3bc;m. This polymer film can be used for various polymer film devices such as an organic transistor, organic solar battery, optical sensor, electrophotographic photoreceptor, spatial light modulator, photorefractive device and the like.

Polymer film and polymer film device using the same

An organic field effect transistor comprising a gate electrode, a gate insulating layer, a semiconductor layer, a source electrode, and a drain electrode, wherein the source electrodeand the drain electrodeare composed of conductive layersand', and compound layersand&#x2032; comprising an acceptor compound, respectively, wherein the compound layersand&#x2032; are each located in contact with the semiconductor layer, and wherein the semiconductor layercontains a polymer compound having an ionization potential of 5.0 eV or more.

Organic field effect transistor

An organic light-light conversion device excellent in device characteristics, comprising a light sensing unit having a layer including a photo-conductive organic semiconductor developing a photo-current multiplication phenomenon by light irradiation, and a light emitting unit having a layer including an electroluminescent organic semiconductor emitting light by current injection, characterized in that at least one of the photo-conductive organic semiconductor and an electroluminescent organic semiconductor is polymer semiconductor. An imaging intensifier consisting of a plurality of arranged above organic light-light conversion devices. An optical sensor provided with a means of measuring and outputting voltages applied to the above organic light-light conversion device and to the opposite ends of a layer including the electroluminescent organic semiconductor.

Organic light-light conversion device

Growing community of inventors

Tsukuba, Japan

Masato Ueda