Tdk Corporation

Masato Kurihara

Satoshi Maruyama

Tadashi Suzuki

Hisashi Suzuki

Atsushi Sano

Yoshinori Fujikawa

Yoshitomo Tanaka

Toshinobu Miyakoshi

Hiroshi Chihara

Akira Kakinuma

An active material with a sufficient cycle characteristic and a process for its production are provided. According to the process for production of an active material of this invention, an aqueous solution containing a metal fluorocomplex is contacted with a metal oxide to form a surface-modified layer on the surface of the metal oxide. The active material of the invention comprises a core section made of a metal oxide and a surface-modified layer covering the core section, wherein the surface-modified layer is an oxide containing a metal present in the core section and a metal not present in the core section.

Active material with a surface-modified layer covering a metal oxide core and an electrode and battery comprising the same

A composite particle for electrode as an active material capable of forming an electrochemical device with excellent discharge capacities and rate characteristics is provided. A composite particle for electrode according to the present invention comprises a particulate core including at least one mother particle containing an electrode active material, and an electron-conducting layer which covers at least part of the surface of the particulate core, the electron-conducting layer including carbon and microparticles containing an electrode active material, and the microparticles having a particle size of 300 nm or less.

Composite particle for electrode and electrochemical device

The composite particle for an electrode in accordance with the present invention contains an electrode active material, a conductive auxiliary agent having an electronic conductivity, and an oxidizing/reducing agent. Therefore, this composite particle can construct an effective conductive network, and effectively provide so-called oxidizing/reducing capacity due to the oxidizing/reducing agent. Hence, when the composite particle for an electrode in accordance with the present invention is used as a constituent material of an electrode in an electrochemical device, the electrochemical device can realize a higher capacity.

Electrochemical capacitor having at least one electrode including composite particles

The method of making a composite particle for an electrode in accordance with the present invention comprises a granulating step of integrating a conductive auxiliary agent and a binder adapted to bind the conductive auxiliary agent and an electrode active material together with a particle made of the electrode active material while in close contact with each other in an inert gas atmosphere so as to form a composite particle for an electrode containing the electrode active material, conductive auxiliary agent, and binder. When the composite particle obtained by this method is used as a constituent of an electrode, an electrode having an excellent electrode characteristic and an electrochemical device having excellent electrochemical characteristics can be formed easily and reliably.

Method of making composite particle for electrode, method of making electrode, method of making electrochemical device, apparatus for making composite particle for electrode, apparatus for making electrode, and apparatus for making electrochemical device

In a method of making an electrochemical device including an electrochemical element comprising a pair of opposing electrode layers, a separator layer disposed between the pair of electrode layers, and an electrolyte existing between the pair of electrode layers; an ionic liquid is applied to at least one of the electrode and separator layers, and then the electrode and separator layers are laminated together.

Method of making electrochemical device

An electrochemical device comprises, at least, a first electrode, a second electrode, and an electrolyte layer having an ionic conductivity. The first and second electrodes oppose each other by way of the electrolyte layer. The first and second electrodes comprise a composite particle containing an electrode active material, a conductive auxiliary agent having an electronic conductivity, and a binder adapted to bind the electrode active material and conductive auxiliary agent to each other. In the composite particle, the electrode active material and conductive auxiliary agent are electrically coupled to each other without being isolated.

Electrochemical device having opposing electrodes

The present invention provides a method of making an electrochemical capacitor electrode comprising a collector and an electronically conductive porous layer formed on the collector while keeping an electric contact therewith. The porous layer contains at least a porous particle made of a carbon material having an electronic conductivity and a binder capable of binding the porous particle. The method comprises a plasma processing step of subjecting a material to high-frequency thermal plasma processing in a plasma gas atmosphere so as to yield the porous particle. All the manufacturing steps subsequent to the plasma processing step are carried out in an inert gas atmosphere.

Method of making an electrode for an electrochemical capacitor and the method of making an electrochemical capacitor

An electrode comprising a porous metal member in sheet form having a three-dimensional skeleton structure and a solid polymer electrolyte is used to construct a lithium secondary battery and an electric double-layer capacitor. Owing to the increased retaining force of the gel electrolyte component to a current collector, the gel electrolyte component can be directly applied to the current collector, contributing to mass scale productivity and cost reduction.

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Tokyo, Japan

Masato Kurihara