Permelec Electrode Ltd.

De Nora Permelec Ltd

Aquaecos Ltd.

Masashi Hosonuma

Takayuki Shimamune

Toshiki Goto

Tsuneto Furuta

Hiroshi Asano

Yoshinori Nishiki

Masaharu Uno

Yukiei Matsumoto

Hideo Nitta

Tomoyasu Shibata

Yi Cao

Tetsuro Tojo

Miwako Nara

Hideo Sato

Tateki Kurosu

Osamu Fukunaga

Hisoshi Asano

Hajime Wada

There is provided an electrolysis device configured to use unpurified water containing a small amount of ions of alkaline earth metal such as Ca and Mg as raw water, and to have a structure of supplying the raw water to a cathode chamber in which deposition of scale of the alkaline earth metal on the surface of a cathode provided in the cathode chamber can be prevented. The electrolysis device and the apparatus for producing electrolyzed ozone water are configured by an electrolysis cell formed in a manner that a membrane-electrode assembly is configured by a solid polymer electrolyte separation membrane formed by a cation exchange membrane, and an anode and a cathode which are respectively adhered to both surfaces of the solid polymer electrolyte separation membrane, and the membrane-electrode assembly is compressed from both surfaces thereof, and thus the solid polymer electrolyte separation membrane, the anode, and the cathode are adhered to each other. A porous conductive metallic material having flexibility and having multiple fine voids therein is used as the cathode, and scale which is mainly formed of hydroxide of alkaline earth metal is stored in fine voids in the cathode, and thus localized deposition of hydroxide of the alkaline earth metal at a contact interface between the cathode and the solid polymer electrolyte separation membrane is prevented.

Electrolysis device and apparatus for producing electrolyzed ozonated water

A process for manufacturing electrodes for electrolysis, including the steps of forming an arc ion plating undercoating layer comprising valve metal or valve metal alloy including a crystalline tantalum component and a crystalline titanium component on the surface of the electrode substrate comprising valve metal or valve metal alloy, by an arc ion plating method; heat sintering the electrode substrate to transform only the tantalum component of the arc ion plating undercoating layer into an amorphous substance; and forming an electrode catalyst layer on the surface of the arc ion plating undercoating layer including the valve metal or valve metal alloy including the tantalum component transformed to the amorphous substance and the crystalline titanium component.

Manufacturing process of electrodes for electrolysis

A process for manufacturing electrodes for electrolysis, including steps of forming an arc ion plating (AIP) undercoating layer including valve metal or valve metal alloy containing a crystalline tantalum component and a crystalline titanium component on a surface of the electrode substrate comprising valve metal or valve metal alloy, by an arc ion plating method; heat sintering, including the steps of coating a metal compound solution, which includes valve metal as a chief element, onto the surface of the AIP undercoating layer, followed by heat sintering to transform only the tantalum component of the AIP undercoating layer into an amorphous substance, and to form an oxide interlayer, which includes a valve metal oxides component as a chief element, on the surface of the AIP undercoating layer containing the transformed amorphous tantalum component and the crystalline titanium component; and forming an electrode catalyst layer on the surface of the oxide interlayer.

The present invention provides a conductive diamond electrode having: a conductive substrate; a coating layer formed on a surface of the conductive substrate, the coating layer containing one of a metal and an alloy each including at least one of niobium and tantalum; and a conductive diamond layer formed on a surface of the coating layer, and a process for producing the conductive diamond electrode.

Conductive diamond electrode and process for producing the same

The present invention provides an electrode for electrolysis including: a conductive substrate; and a conductive diamond formed on a surface of the conductive substrate, the conductive substrate having at least one surface shape selected from the group consisting of: (a) a surface shape of a combination of an Ra of 100-1,000-&#x3bc;m and an RSm of 50-10,000 &#x3bc;m; (b) a surface shape of a combination of an Ra of 2.5-100 &#x3bc;m and an RSm of 1.5-800 &#x3bc;m, and (c) a surface shape of a combination of an Ra of 0.01-2 &#x3bc;m and an RSm of 0.005-250 &#x3bc;m, and a process for producing the electrode.

Electrode for electrolysis and process for producing the same

A conductive diamond electrode including an electrode substrate comprising a material selected from the group consisting of a valve metal and an alloy based on the valve metal, at least a surface of the metal or alloy having been subjected to plasticization processing, or heat treatment in vacuum or inert atmosphere; and a conductive diamond film formed on the plasticization processed surface of the electrode substrate. When the electrode substrate is subjected to plasticization processing and heat treatment, peeling resistance of the conductive diamond film is improved, thereby an electrode life is prolonged.

An electrolytic electrode having an interlayer having more excellent peeling resistance and corrosion resistance and longer electrolytic life than conventional electrolytic electrodes and capable of flowing a large amount of current at the industrial level and a process of producing the same are provided. The electrolytic electrode includes a valve metal or valve metal alloy electrode substrate on the surface of which is formed a high-temperature oxidation film by oxidation, and which is coated with an electrode catalyst. The high-temperature oxidation film is integrated with the electrode substrate, whereby peeling resistance is enhanced. Further, by heating the high-temperature oxidation film together with the electrode catalyst, non-electron conductivity of the interlayer is modified, thereby making it possible to flow a large amount of current.

Electrolytic electrode and process of producing the same

A diamond electrode having a prolonged life by combining a conventional diamond electrode having a relatively short life with other components is provided. A diamond electrode for electrolysis includes an electrode substrate, at least the surface of which comprises Magneli phase titanium oxide, and conductive diamond supported as an electrode catalyst on a surface of the electrode. The electrode catalyst may contain a titanium oxide powder. Magneli phase titanium oxide improves conductivity without forming a stable oxide layer on the substrate surface.

Diamond electrode for electrolysis

A titanium composite material is disclosed which comprises a titanium or titanium alloy substrate, a base layer formed thereon of a calcium phosphate compound resulting from calcination of a hydrochloric or nitric acid aqueous solution of the calcium phosphate compound, and a covering layer thereon of a calcium phosphate compound formed by sintering a suspension of the calcium phosphate compound applied to the base layer. The composite material is useful as a biological implant. It is produced by activating the surface of the substrate, forming the base layer by calcining the solution coated on the substrate and then forming the covering layer by sintering the suspension coated on the base layer. The covering layer may be hydrothermally treated to increase its crystallinity.

Titanium composite materials coated with calcium phosphate compound and

A titanium or titanium alloy composite having a porous surface layer, which comprises a titanium or titanium alloy substrate and a porous titanium or titanium alloy layer that adheres strongly to said substrate, said porous layer being formed by first providing said substrate with a firmly adhering sinter of a mixture of a titanium or titanium alloy powder and a magnesium powder, and then removing magnesium from the sinter. A process for producing a titanium or titanium alloy composite having a porous surface layer, comprising: providing a coating composition comprising a binder added to a mixture of a titanium or titanium alloy powder and a magnesium powder; applying said composition to the surface of a titanium or titanium alloy substrate; heating the substrate at a temperature of from 650.degree. to 800.degree. C. in vacuo or an inert atmosphere so as to form a sinter of the powders of titanium or titanium alloy and magnesium which firmly adheres to said substrate; and removing magnesium from said sinter.

Process for providing titanium composite having a porous surface

A calcium phosphate-coated composite material is disclosed, comprising a metallic substrate, an oxide layer on the metallic substrate, said oxide layer consisting essentially of the oxide of one or more metals selected from the group consisting of titanium, zirconium, hafnium, niobium, tantalum, tin, cobalt, aluminum, chromium, molybdenum and tungsten, and a coating layer of calcium phosphate provided on the oxide layer. A process for production of the calcium phosphate-coated composite material is also disclosed.

Calcium phosphate-coated composite material and process for production

Titanium composite materials coated with calcium phosphate compound

A process for producing a composite material having a coating of a calcium phosphate compound on the surface of a metal substrate, said process comprising the steps of

Process for producing composite materials having a coating of calcium

A titanium composite having a coil-shaped skeletal structure on the surface, comprising a titanium or titanium alloy substrate and one or more layers of a coil-shaped skeletal titanium or titanium alloy structure that is firmly attached to the surface of said substrate and a process for producing a titanium composite having a coil-shaped skeletal structure on a surface of a titanium or titanium alloy substrate, which comprises: providing a coating composition which is a mixture of a titanium or titanium alloy powder with a binder; applying said composition in such a manner that titanium or titanium alloy coils which are to form the coil-shaped skeletal structure are firmly attached to both themselves and to the titanium or titanium alloy substrate; the heating the assembly either in vacuo or in an inert atmosphere so that the titanium or titanium alloy powder in the applied coating composition is sintered to have the coil-shaped skeletal titanium or titanium alloy structure attached firmly onto the titanium or titanium alloy substrate.

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Fujisawa, Japan

Masashi Hosonuma