Seiko Epson Corporation

Masaru Terada

Naoyuki Toyoda

Tomohiro Ogawa

Hiroshi Takiguchi

Masaya Shibatani

Koki Hirata

Hiroaki Kida

Homare Kuribayashi

Atsushi Denda

Taketoshi Kagose

Hidekazu Moriyama

Minoru Yamada

Toshiyuki Kobayashi

Shintaro Asai

Kei Hiruma

Tomoyuki Ushiyama

Mitsunobu Nakatani

An ink jet printing method includes a metallic ink application step of ejecting a metallic ink composition containing a metallic pigment from an ink jet head to apply the metallic ink composition onto a printing medium, a heating step of heating the metallic ink composition applied on the printing medium with an infrared heater, and a coloring ink application step of ejecting a coloring ink composition containing a coloring material from an ink jet head to apply the coloring ink composition onto the metallic ink composition on the printing medium. Each of the metallic ink composition and the coloring ink composition is a water-based ink or a solvent-based ink.

Ink jet printing method and ink jet printing apparatus

A recording method of the present disclosure, which is a recording method of performing recording on a recording medium by using a recording device including an ink jet head, includes ejecting a composition for ink jet from the ink jet head, in which the composition for ink jet contains a metal pigment, the metal pigment is formed of a plurality of scaly metal particles, the ink jet head includes a circulation flow path for circulating the composition for ink jet, and an average thickness of the metal particles determined by atomic force microscopy is 19 nm or less.

Recording method and recording device

A solvent-based ink composition is provided that includes: an organic solvent; a surface-treated metal powder; and a polyoxyethylene alkyl ether phosphoric acid compound, the content of the polyoxyethylene alkyl ether phosphoric acid compound with respect to the total mass of an ink is 0.1 to 10.0 percent by mass, and the surface-treated metal powder contains aluminum or an aluminum alloy and is surface-treated by a surface treating agent of a fluorine-based compound.

Solvent-based ink composition

An ink jet composition of the invention is discharged by an ink jet method and includes: metal powder; an organic solvent; and a resin having a styrene-maleic acid structure as a binder resin, in which the ink jet composition contains metal powder surface-treated with a fluorine-based compound as the metal powder.

Ink jet composition and recorded matter

A non-aqueous ink jet composition includes a surface-treated metal powder, wherein a dissolved oxygen reduction rate is 2.0 kPa/h or more and 20.0 kPa/h or less in an environment of 25&#xb0; C. and 1.0 atm.

Ink jet composition, housing, and ink jet method

Provided is an ink jet recording apparatus including: a base metal pigment ink composition; and a first nozzle that ejects the base metal pigment ink composition, in which the base metal pigment ink composition contains a flat base metal pigment of which a 50% average particle diameter D50 is in a range of 100 nm to 1 &#x3bc;m, and an organic compound of which a surface tension at 20&#xb0; C. is 35 mN/m or greater, and an ejection interval T1 after the base metal pigment ink composition is ejected from the first nozzle and before the base metal pigment ink composition is ejected again from the first nozzle is within 100 &#x3bc;s.

Ink jet recording apparatus

The invention provides metal powder constituted from metal particles. Each of the metal particles comprises a base particle having a surface and a metal material constituting at least the surface of the base particle. The base particle is subjected to a surface treatment with a fluorine type phosphoric acid ester. Further, the invention also provides an ultraviolet ray curable ink jet composition to be ejected by using an ink jet method. The ultraviolet ray curable ink jet composition comprises a polymerizable compound and metal powder constituted from metal particles. The metal particles of the metal powder are subjected to a surface treatment with a fluorine type phosphoric acid ester.

Metal powder, ultraviolet ray curable ink jet composition and recorded object

An ultraviolet ray curable ink composition adapted to be ejected by using an ink jet method is provided. The ultraviolet ray curable ink composition includes a polymerizable compound and metal powder. The metal powder is constituted from metal particles subjected to a surface treatment with a fluorine type silane compound and/or a fluorine type phosphoric acid ester as a surface treatment agent. A polymerizable compound includes a monomer having an alicyclic structure. This makes it possible to provide the ultraviolet ray curable ink composition which has excellent storage stability, can provide excellent dispersion stability of the metal particles of the metal powder. A printed object is also provided. Such a printed object is produced by using the ultraviolet ray curable ink composition.

Ultraviolet ray curable ink composition for use in ink jet method and printed object

An ultraviolet ray curable ink composition adapted to be ejected by using an ink jet method is provided. The ultraviolet ray curable ink composition includes a polymerizable compound, metal powder, and a polyether based solvent. The metal powder is constituted from metal particles subjected to a surface treatment with a fluorine type silane compound and/or a fluorine type phosphoric acid ester as a surface treatment agent. An amount of the polyether based solvent contained in the ultraviolet ray curable ink composition is in the range of 0.05 mass % or more but 7.0 mass % or less. A printed object is also provided. Such a printed object is produced by using the ultraviolet ray curable ink composition.

An ultraviolet ray curable ink composition adapted to be ejected by using an ink jet method is provided. The ultraviolet ray curable ink composition includes a polymerizable compound, metal powder, and a liquid component having an alicyclic structure including a hetero atom. The metal powder is constituted from metal particles subjected to a surface treatment with a fluorine type silane compound and/or a fluorine type phosphoric acid ester as a surface treatment agent. An amount of the liquid component contained in the ultraviolet ray curable ink composition is in the range of 0.05 mass % or more but 7.0 mass % or less. A printed object is also provided. Such a printed object is produced by using the ultraviolet ray curable ink composition.

A pigment dispersion liquid is a pigment dispersion liquid for a solvent-based ink including a base metal pigment and an organic solvent, in which the base metal pigment is subjected to a surface treatment by a fluorine-based compound, and in which the concentration of a fluorine element is from 8 atm % to 35 atm % when an X-ray photoelectron spectroscopy (XPS) analysis of the surface of the base metal pigment is performed.

Pigment dispersion liquid and solvent-based ink composition containing the same

Provided is an ink jet recording apparatus including: a base metal pigment ink composition; and a first nozzle that ejects the base metal pigment ink composition, in which the base metal pigment ink composition contains a flat base metal pigment of which a 50% average particle diameter D50 is in a range of 100 nm to 1 &#x3bc;m, and an organic compound of which a surface tension at 20&#xb0; C. is 35 mN/m or greater, and an ejection interval Tafter the base metal pigment ink composition is ejected from the first nozzle and before the base metal pigment ink composition is ejected again from the first nozzle is within 100 &#x3bc;s.

Disclosed herein is a base metal pigment, which is used for an aqueous ink composition containing water as a part of a solvent, in which the base metal pigment is surface-treated with a fluorine-based compound, and has a zeta potential of greater than or equal to &#x2212;50 mV and less than or equal to &#x2212;15 mV, as measured by an ultrasonic zeta potential measurement device, in a pH range of greater than or equal to 5 and less than or equal to 10.

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Suwa, Japan

Masaru Terada