Nippon Chemi-con Corporation

Masao Sakakura

Masashi Ozawa

Kazuya Koseki

Kenta Sato

Junichi Kawakami

Kenji Tamamitsu

Kazuma Okura

Shingo Takeuchi

Kouichi Kuroda

Tomohiro Matsuzaki

Hidehiko Itoh

Ippei Nakamura

Takayuki Nakaji

Takayuki Sugiyama

A hybrid-type solid electrolytic capacitor which suppresses corrosive reaction even if chlorine ions are contaminated while suppressing deterioration of product characteristics. The solid electrolytic capacitor includes a capacitor element including an anode foil and a cathode foil facing each other and an electrolyte layer formed in the capacitor element. The electrolyte layer includes a solid electrolyte layer including a dopant and a conjugated polymer, and an electrolyte solution filled in air gaps in the capacitor element on which the solid electrolyte layer is formed. The electrolyte layer includes a cation component at a molecular ratio of 6 or less relative to 1 mol of a functional group which can contribute to a doping reaction of the dopant, and the electrolytic solution includes a sulfolane-based solvent.

Solid electrolytic capacitor

In a solid electrolytic capacitor having an electrolyte layer consisting of a solid electrolyte layer and a liquid, the solid electrolytic capacitor, which suppresses a dedoping reaction and which ESR thereof does not keenly increase, in particular, after a loading of heat stress, is provided. In the solid electrolytic capacitor, the electrolyte layer is formed in the capacitor element which is formed by opposing an anode foil and a cathode foil. This electrolyte layer includes the solid electrolyte layer and the liquid. The solid electrolyte layer includes a conductive polymer consisting of a dopant and a conjugated polymer. The liquid is filled in air gaps in the capacitor element on which the solid electrolyte layer is formed. The electrolyte layer includes ammonia as a cation component, and a molecular ratio of the cation component relative to 1 mol of a functional group which can contribute to a doping reaction of the dopant, in the electrolyte layer is 23 or less.

In a solid electrolytic capacitor having an electrolyte layer consisting of a solid electrolyte layer and a liquid, the solid electrolytic capacitor, which suppresses a dedoping reaction and which ESR thereof does not keenly increase, in particular, after a loading of heat stress, is provided. In the solid electrolytic capacitor, the electrolyte layer is formed in the capacitor element which is formed by opposing an anode foil and a cathode foil. This electrolyte layer includes the solid electrolyte layer and the liquid. The solid electrolyte layer includes a conductive polymer consisting of a dopant and a conjugated polymer. The liquid is filled in air gaps in the capacitor element on which the solid electrolyte layer is formed. A molecular ratio of a cation component relative to 1 mol of a functional group which can contribute to a doping reaction of the dopant, in the electrolyte layer is 6 or less.

A solid electrolytic capacitor which exhibits excellent characteristics for high voltage applications of 80 WV or more and a method for manufacturing this solid electrolytic capacitor are provided. This solid electrolytic capacitor includes a capacitor elementwhich is obtained by winding an anode foiland a cathode foil, with a separatorinterposed therebetween, the capacitor elementincludes a solid electrolyte layer, and a void part in the capacitor elementis filled with an electrolyte solution, the electrolyte solution contains an ammonium salt of an aliphatic carboxylic acid as a solute and a polyhydric alcohol as a solvent, and the addition amount of the acid serving as the solute relative to the solvent is 0.6 mol/kg or less.

Solid electrolytic capacitor and method for manufacturing solid electrolytic capacitor

The present invention provides solid electrolytic capacitor with excellent properties in high-voltage application of 80V or more and a manufacturing method thereof. The solid electrolytic capacitor is manufactured by: forming, in a capacitor element with an anode electrode foil and a cathode electrode foil wound with an interposed separator, a solid electrolyte layer by using a conductive polymer dispersion in which particles of a conductive polymer dispersed in a solvent; and filling voids inside the capacitor element in which the solid electrolyte layer has been formed with an electrolytic solution containing less than 9 wt % of a salt of a composite compound of inorganic acid and organic acid as a solute for filling.

Electrolytic capacitor having a solid electrolyte layer and manufacturing method thereof

Provided are an electrolytic capacitor with high withstand voltage capable of preventing deterioration of withstand voltage characteristics caused by lead-free reflow or the like and improving ESR characteristics, and a manufacturing method thereof. The electrolytic capacitor is obtained by impregnating a capacitor element in which an anode electrode foil and a cathode electrode foil are wound with a separator interposed, with a dispersion containing: particles of a conductive polymer; sorbitol or sorbitol and polyalcohol; and a solvent so as to form a solid electrolyte layer containing 60 to 92 wt % of the sorbitol or the sorbitol and polyalcohol, and by filling an electrolytic solution containing ethylene glycol in a gap portion in the capacitor element on which the solid electrolyte layer is formed.

Electrolytic capacitor and method of manufacturing the same

A high voltage proof solid electrolytic capacitor that can prevent deterioration of voltage proof property due to lead-free reflow etc. and a manufacturing method thereof are provided. A capacitor element having an anode and cathode electrode foils wound via a separator is impregnated with a dispersion comprising conductive polymer particles or powder and a solvent to form a solid electrolyte layer consisting of a conductive polymer, and the voids inside the capacitor element having the solid electrolyte layer formed are filled with an ion-conducting substance comprising a mixed solvent comprising ethylene glycol and &#x3b3;-butyrolactone together with a solute selected from at least one type of an ammonium salt, a quaternary ammonium salt, a quaternized amidinium salt, and an amine salt of an organic acid, an inorganic acid, and a composite compound between organic acid and inorganic acids to obtain a solid electrolytic capacitor.

Solid electrolytic capacitor and manufacturing method thereof

A hydrophobic film is formed on the electrode foil surface by adding a straight-chain saturated dicarboxylic acid represented by the general formula: HOOC(CH)COOH (wherein n indicates an integer from 9 to 11) to the electrolytic solution for medium/high-voltage electrolytic capacitor. Addition of a large amount of water to the electrolytic solution is allowed since this hydrophobic film suppresses the hydration reaction between the electrode foil and water. Further, it is possible to retain good lifespan property of the electrolytic capacitor in a medium/high-voltage electrolytic solution by having low specific resistance property and by suppressing the hydration decomposition of the electrode foil, wherein the electrolytic solution is azelaic acid, sebacic acid, 1-methyl-azelaic acid, 1,6-decanedicarboxylic acid, or a salt thereof dissolved in a solvent having ethylene glycol as the main component.

Electrolytic solution for electrolytic capacitor

Disclosed are an aluminum electrolytic capacitor having low impedance properties and a long service life, and an electrolytic solution which enables to give such capacitor. The electrolytic solution contains a solvent containing water, a phosphorus oxoacid ion-generating compound which can generate a phosphorus oxoacid ion in an aqueous solution, and a chelating agent which can coordinate with aluminum to form an aqueous aluminum chelate complex. The electrolytic solution further contains a compound selected from the group consisting of azelaic acid and an azelaic acid salt, and a compound selected from the group consisting of formic acid, a formic acid salt, adipic acid, an adipic acid salt, glutaric acid and a glutaric acid salt. The content of azelaic acid and/or the azelaic acid salt is at least 0.03 moles per kg of the solvent. When the electrolytic solution is used in an electrolytic capacitor which utilizes an anode having an aluminum oxide film containing phosphorus in an amount of 30 to 150 mg per unit CV product in terms of phosphoric acid, the service life of the capacitor is remarkably prolonged.

Electrolytic solution for aluminum electrolytic capacitor, and aluminum electrolytic capacitor

An electrolyte having a high conductivity, an excellent high-temperature life characteristic and leading to improvement of the shelf characteristic of an aluminum electrolytic capacitor. At least one phosphate ion producing compound and a chelating agent are added using a solvent largely composed of water. Therefor, an aluminum electrolytic capacitor comprising such an electrolyte has a low impedance, an excellent high-temperature life characteristic, and an improved shelf characteristic.

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Tokyo, Japan

Masao Sakakura