Kuraray Co., Ltd.

Idemitsu Petrochemical Co., Ltd.

Masao Ishii

Takayuki Okamura

Shunro Taniguchi

Keishiro Igi

Yoshifumi Murata

Shinichi Yokota

Makoto Nishikawa

Hideo Takamatsu

Shobu Minatono

Shiroh Kishii

Noriaki Yoshimura

Koji Hirai

Michihiro Ishiguro

Kazuto Hashimoto

Yoshio Hirayama

Hideki Endo

Takeshi Matsumoto

Kazushige Ishiura

Hiromichi Nakata

Kenji Tanaka

Osamu Kusudo

Manabu Kusano

Yoshito Hamamoto

Katsuya Hashimoto

Atsushi Ohishi

Isamu Akiba

Nobuo Sukenobe

Miduho Maeda

There is disclosed a resin composition which comprises:

Resin composition

Microporous crumbs of a hydrogenated block copolymer, produced by the process comprising feeding a solution of a hydrogenated block copolymer in a hydrocarbon solvent at a concentration of said hydrogenated block copolymer within a range from 5% to 60% by weight into hot water while maintaining the temperature of said solution at 40.degree. C.-150.degree. C., and then steam stripping at a temperature higher than the boiling point of the hydrocarbon solvent or higher than the azeotropic point of the hydrocarbon solvent and water when they form an azeotropic mixture and lower than 150.degree. C., wherein said hydrogenated block copolymer is obtained by hydrogenating more than 50% of unsaturated bonds derived from conjugated diene of a block copolymer having at least one polymer block consisting essentially of a vinyl aromatic compound and at least one polymer block consisting essentially of a conjugated diene in which the weight ratio of the vinyl aromatic compound to the conjugated diene is within a range from 5/95 to 95/5, and wherein said crumbs have (1) a bulk density of more than 0.18 g/cc, (2) a total volume of micropores of is more than 0.4 cc/g and (3) a ratio of the sum of the volume of micropores having a pore diameter within a range from 0.14 to 3.9 .mu.m based on the total volume of the micropores of more than 8% are provided. The microporous crumbs can absorb a softening agent, a plasticizer and the like uniformly and rapidly, have an excellent handling property and provide molding compounds free of non-melted matters.

Microporous crumbs of hydrogenated block copolymers and process for

A thermoplastic polymer composition comprises:

Thermoplastic polymer composition

A thermoplastic polymer composition comprises: a thermoplastic polymer (a) having polarity on the main chain of the molecule thereof, and a modified block copolymer (b) of a block copolymer comprising: at least one polybutadiene block (B) having a degree of vinylization of not more than 30%, and at least one polymer block (D) comprising units from isoprene and butadiene in a ratio by weight of isoprene/butadiene of 30/70 to 100/0 and having a degree of vinylization of not more than 30%, said polybutadiene block (B) and said polymer block (D) each has a degree of unsaturation of not more than 30%, to said block copolymer a molecular unit containing a carboxyl acid group or derivatives thereof having added, the ratio by weight between said component (a) and said component (b), (a)/(b), being in a range of 2/98 to 98/2.

A thermoplastic elastomer composition comprises the following two components: (a) a thermoplastic polyurethane having soft segments from a poly (3-methyl-1,5-pentane adipate) diol having a molecular weight of at least 2,000 and having a JIS A hardness at 25.degree. C. of not more than 80, and (b) a block copolymer comprising at least 2 polymer blocks A principally comprising an aromatic vinyl compound and at least 1 block B comprising an olefinic elastomer, said aromatic vinyl compound being contained in an amount of 5 to 50% by weight based on the weight of the block copolymer and the olefinic elastomer block having a glass transition point of not higher than -20.degree. C. and a heat of fusion of crystal of not more than 8 cal/g; the ratio by weight between the component (a) and the component (b) being (a)/(b)=95/5 to 5/95.

Thermoplastic elastomer composition

Process for producing polyurethane

A process for the hydrogenation of conjugated diene polymers having alcoholic hydroxyl groups, is provided. In the process, reduced nickel is used as a catalyst and an ether or a mixture of an ether and a hydrocarbon is used as a solvent for the hydrogenation reaction whereby elimination of the group rarely occurs with a very high hydrogenation rate being attained.

Process for the hydrogenation of conjugated diene polymers having

A block copolymer having a numerical average molecular weight of 30,000 to 300,000 composed of two or more blocks consisting of aromatic vinyl units having a numerical average molecular weight of 2500 to 40,000, and one or more blocks containing a vinyl bonding content of not less than 40%, having a peak temperature of primary dispersion of tan .delta. at least 0.degree. C., and consisting of isoprene or isoprene-butadiene units in which at least a part of carbon-carbon double bonds may be hydrogenated, and a composition consisting of the block copolymer. The composition can provide a vibration-damping material.

Block copolymers and composition containing the same

A pressure sensitive adhesive composition is provided which comprises a tri-block copolymer (a) consisting of aromatic vinyl block-conjugated diene block-aromatic vinyl block in which the conjugated diene moiety is hydrogenated and a block copolymer (b) consisting of an aromatic vinyl block and a conjugated diene block in which the conjugated diene moiety is hydrogenated. The adhesive composition is significantly improved in low temperatures characteristics, adhesion and processability with good adhesion.

Pressure sensitive adhesive composition

A polycarbonate resin composition which comprises

Polycarbonate resin composition

A copolyester film is disclosed which comprises a copolyester in which the dicarboxylic acid component comprises 100 to 85 mole percent of terephthalic acid and the diol component comprises 65 to 97 mole percent of 1,4-butanediol and 3 to 35 mole percent of a polyethylene glycol with a molecular weight of 106 to 550. The copolyester has a reduced viscosity in the range of 0.8 to 1.4 dl/g as measured at a concentration of 0.5 g/dl in a 1:1 (by weight) solvent mixture of phenol and tetrachloroethane at 30.degree. C. The copolyester has a main endothermic peak with a peak maximum temperature of 160.degree. C. to 200.degree. C. and at least one subsidiary endothermic peak with a peak maximum temperature of 30.degree. C. to 80.degree. C. in differential scanning calorimetry with the ratio (R) of the area occupying not less than 40.degree. C. in the subsidiary endothermic peak, the main endothermic peak area being within the range of 3 percent to 20 percent. A hot melt adhesive comprising the copolyester film and a method for producing the copolyester film are also disclosed. The hot melt adhesive has a high initial modulus of elasticity at high temperature (30.degree.-50.degree. C.) and features improved processability or workability while retaining the required properties of a hot melt adhesive.

Copolyester film and a method for production thereof

A copolyester film comprising: (a) a copolyester which comprises, as a dicarboxylic acid component, 80 to 97 mole percent of terephthalic acid and 3 to 20 mole percent of isophthalic acid and, as a diol component, 60 to 85 mole percent of 1,4-butanediol and 15 to 40 mole percent of diethylene glycol, and said copolyester having a reduced viscosity in the range of 0.8 to 1.4 dl/g and a melting point in the range of 160.degree. to 200.degree. C.; and said film having (b) a heat of crystal fusion in the range of 5 to 10 cal/g, (c) a haze value in the range of 5 to 35 percent, and (d) an initial Young's modulus in the range of 3.times.10.sup.3 kg/cm.sup.2 to 30.times.10.sup.3 kg/cm.sup.2. A hot melt adhesive comprising said film is also provided. This hot melt adhesive has excellent high speed bonding characteristics, durability and high bond strength with respect to substrates.

Copolyester film and a hot melt adhesive comprising said film

Polycarbonate resin compositions are disclosed, comprising: (1) (A) a polycarbonate resin and (B) polyesterether elastomer, said elastomer composing of a bifunctional carboxylic acid component and a glycol component comprising polyalkylene glycol and ethylene glycol, or (2) the components (A) and (B), and (C) a rubber-like elastomer, or (3) the components (A) and (B), and (D) a polyester resin, or (4) the components (A), (B), (C) and (D). These compositions are excellent in solvent resistance and so forth, and further possess excellent physical and thermal properties characteristic of a polycarbonate resin. Thus the compositions are useful for use in production of industrial and electrical articles, such as a car bumper in the field of car industry.

A process for producing a novel polyester polyurethane having excellent hydrolysis resistance and excellent flexibility at low temperature, which is obtained from a polyisocyanate and a polyester polyol which is obtained by reaction a dicarboxylic acid with a mixture of 1,9-nonanediol and a polyol represented by the formula ##STR1## wherein R.sup.1 denotes methyl group or ethyl group, R.sup.2 denotes hydrogen atom, methyl group, ethyl group, hydroxymethyl group or hydroxyethyl group, and n is an integer of 1 to 5, said polyester polyol having an average molecular weight of 500 to 30,000.

Growing community of inventors

Kashima, Japan

Masao Ishii