Showa Denko K.k.

Masaki Horikita

Takashi Sato

Kunchan Lee

Ryuji Monden

Yasuaki Wakizaka

Chunfu Yu

Yoshinori Abe

Yuji Ito

Akira Takahashi

Takuya Imai

Toshikazu Shishikura

Kenichiro Ota

Masayuki Yoshimura

Kazunori Ichioka

Ryoko Konta

Noriyasu Tezuka

A method for producing a fuel cell electrode catalyst, including a step (I) of bringing an aqueous solution of a transition metal compound (1) into contact with ammonia and/or ammonia water to generate a precipitate (A) containing an atom of the transition metal, a step (II) of mixing at least the precipitate (A), an organic compound (B), and a liquid medium (C) to obtain a catalyst precursor liquid, and a step (IV) of subjecting the solid in the catalyst precursor liquid to heat treatment at a temperature of 500 to 1200&#xb0; C. to obtain an electrode catalyst; a portion or the entirety of the transition metal compound (1) being a compound containing a transition metal element of group 4 or group 5 of the periodic table; and the organic compound (B) being at least one selected from sugars and the like.

Method for producing fuel cell electrode catalyst

The present invention concerns an oxygen reduction catalyst comprising composite particles in which primary particles of a titanium compound is dispersed into a carbon structure, wherein the composite particles have titanium, carbon, nitrogen and oxygen as constituent elements, and with regard to a ratio of number of atoms of each of the elements when titanium is taken as 1, a ratio of carbon is larger than 2 and 5 or less, a ratio of nitrogen is larger than 0 and 1 or less, and a ratio of oxygen is 1 or more and 3 or less, and an intensity ratio (D/G ratio) of D band peak intensity to G band peak intensity in a Raman spectrum is in the range of 0.4 to 1.0. The oxygen reduction catalyst according to the present invention has satisfactory initial performance and excellent start-stop durability.

Oxygen reduction catalyst and method for producing same

A catalyst carrier production process includes a step (a) of mixing a transition metal compound (1), a nitrogen-containing organic compound (2), and a solvent to provide a catalyst carrier precursor solution; a step (b) of removing the solvent from the catalyst carrier precursor solution; and a step (c) of thermally treating a solid residue obtained in the step (b) at a temperature of 500 to 1100&#xb0; C. to provide a catalyst carrier; wherein the transition metal compound (1) is partly or wholly a compound including a transition metal element (M1) selected from the group 4 and 5 elements of the periodic table as a transition metal element; and at least one of the transition metal compound (1) and the nitrogen-containing organic compound (2) includes an oxygen atom.

Process for producing catalyst carrier, process for producing composite catalyst, composite catalyst, and fuel cell using same

In a direct-liquid fuel cell supplied directly with a liquid fuel, a process for producing an electrode catalyst for a direct-liquid fuel cell is provided which is capable of suppressing decrease in cathode potential caused by liquid fuel crossover and providing an inexpensive and high-performance electrode catalyst for a direct-liquid fuel cell. The process for producing an electrode catalyst for a direct-liquid fuel cell includes Step A of mixing at least a transition metal-containing compound with a nitrogen-containing organic compound to obtain a catalyst precursor composition, and Step C of heat-treating the catalyst precursor composition at a temperature of from 500 to 1100&#xb0; C. to obtain an electrode catalyst, wherein part or entirety of the transition metal-containing compound includes, as a transition metal element, at least one transition metal element M1 selected from Group IV and Group V elements of the periodic table.

Process for producing catalyst for direct-liquid fuel cell, catalyst produced by the process and uses thereof

A catalyst carrier production process includes a step (a) of mixing a transition metal compound (), a nitrogen-containing organic compound (), and a solvent to provide a catalyst carrier precursor solution; a step (b) of removing the solvent from the catalyst carrier precursor solution; and a step (c) of the thermally treating a solid residue obtained in the step (b) at a temperature of 500 to 1100&#xb0; C. to provide a catalyst carrier; wherein the transition metal compound () is partly or wholly a compound including a transition metal element (M) selected from the group 4 and 5 elements of the periodic table as a transition metal element; and at least one of the transition metal compound () and the nitrogen-containing organic compound () includes an oxygen atom.

Provided is a process for producing a fuel cell electrode catalyst having high catalytic activity which uses a transition metal, e.g., titanium, which process comprises thermal treatment at relatively low temperature, i.e., not including thermal treatment at high temperature (calcining) step. The process for producing a fuel cell electrode catalyst comprises a step (1) of mixing at least a transition metal-containing compound, a nitrogen-containing organic compound and a solvent to provide a catalyst precursor solution; a step (2) of removing the solvent from the catalyst precursor solution; and a step (3) of thermally treating a solid residue obtained in the step (2) at a temperature of 500 to 1100&#xb0; C. to provide an electrode catalyst; wherein the transition metal-containing compound is partly or wholly a compound comprising at least one transition metal element (M1) selected from the group 4 and 5 elements of the periodic table as a transition metal element.

Process for producing fuel cell electrode catalyst, process for producing transition metal oxycarbonitride, fuel cell electrode catalyst and uses thereof

Growing community of inventors

Tokyo, Japan

Masaki Horikita