Panasonic Corporation

Panasonic Intellectual Property Management Co., Ltd.

Matsushita Electric Industrial Co., Ltd.

Sanyo Electric Co., Ltd.

Panasonic Holdings Corporation

Mitsubishi Chemical Corporation

Panasonic Energy Co., Ltd.

Masaki Deguchi

Hiroshi Yoshizawa

Tooru Matsui

Satoshi Nishitani

Masaya Ugaji

Atsushi Ueda

Satoshi Yamamoto

Taisuke Yamamoto

Kazuya Iwamoto

Kentaro Takahashi

Masanobu Takeuchi

Takaharu Morikawa

Natsuhiko Mukai

Atsushi Fukui

Shinichi Kinoshita

Hizuru Koshina

Masatoshi Nagayama

Hiroshi Minami

Yasushi Nakagiri

Masamichi Onuki

Kazuhiro Iida

Takafumi Oura

Takuya Iwamoto

Naoya Morisawa

Masahiro Kinoshita

Taiki Satow

Yasuko Nozaki

Hiroshi Nishiyama

Yasunori Watanabe

Chisaki Fujitomo

Shunsuke Mitani

Kumiko Mie

Yuta Ichikawa

A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes a positive electrode material including particles of a composite oxide containing lithium and a metal Me other than lithium, and a tungsten compound attached to a surface of the particles. The metal Me contains at least nickel. The nonaqueous electrolyte includes an unsaturated sultone compound.

Nonaqueous electrolyte secondary battery

This non-aqueous electrolyte secondary battery that is an example of an embodiment comprises a winding type electrode body for which a positive electrode and a negative electrode are wound with a separator interposed. The electrode body has a positive electrode lead. The positive electrode lead has: a lead base made of metal that includes a first surface joined to the positive electrode, and a second surface on the side opposite to the first surface; and an insulating ceramic layer principally comprising an inorganic compound and formed over a range within the second surface of the lead base so as to face the negative electrode with at least the separator interposed therebetween.

Non-aqueous electrolyte secondary battery

Disclosed is a non-aqueous electrolyte secondary battery including: a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and an electrolyte solution, wherein the electrolyte solution includes a solvent, a solute, and a carboxylic anhydride, the solvent includes a carboxylic acid ester compound, and the solute includes a sulfonyl imide compound.

Non-aqueous electrolyte secondary battery, electrolyte solution, and method for producing non-aqueous electrolyte secondary battery

Disclosed is a non-aqueous electrolyte secondary battery including: a positive electrode; a negative electrode; and an electrolyte solution. The negative electrode contains a negative electrode active material that is capable of electrochemically absorbing and desorbing lithium. The negative electrode active material contains a lithium silicate phase and silicon particles that are dispersed in the lithium silicate phase. The lithium silicate phase is an oxide phase that contains lithium, silicon, and oxygen. The atomic ratio O/Si of oxygen relative to silicon in the lithium silicate phase is greater than 2 and less than 4. The electrolyte solution contains a halogenated benzene. The amount of halogenated benzene contained in the electrolyte solution is 1 ppm or more and 500 ppm or less.

A positive electrode, a negative electrode, and a non-aqueous electrolyte. The negative electrode includes a negative electrode material, a binder, and a thickener, and the negative electrode material includes a lithium silicate phase, and Si particles dispersed in the lithium silicate phase. The ratio of the Si particles in the negative electrode material is 30 mass % or more. The binder includes a poly(meth)acrylic acid, the thickener includes a carboxyalkyl cellulose, and the amount of the poly(meth)acrylic acid relative to 100 parts by mass of the negative electrode material is 0.1 parts by mass or more and 5 parts by mass or less. The non-aqueous electrolyte includes a lithium salt, a non-aqueous solvent, and an acid that exhibits a pKa of 1 to 30 in water at 25° C. The non-aqueous electrolyte secondary battery can suppress the generation of gas during high-temperature storage, and secure excellent cycle characteristics.

A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, and an electrolyte. The negative electrode includes a negative electrode active material capable of electrochemically absorbing and releasing lithium, and a binder. The negative electrode active material includes a Si-containing material, and the binder includes at least one cellulose compound selected from the group consisting of a carboxyalkyl cellulose and a salt thereof. The electrolyte includes a non-aqueous solvent, and a lithium salt dissolved in the non-aqueous solvent. The lithium salt includes lithium bis(fluorosulfonyl)imide: LFSI.

A battery comprises a first polarity terminal that is attached via a first insulating member to an opening of an outer case. A first polarity plate includes: a first core formed of a conductive material; and a first active material layer. A first drawn-out portion is formed from a side of the first core on the first polarity terminal side thereof being drawn further out than a side of the first active material layer on the first polarity terminal side thereof. The first drawn-out portion includes a first bent portion that is bent towards the radially inner or outer side of the electrode body. A first surface of a first polarity collector plate contacts the surface of the first bent portion on the first polarity terminal side, and the first polarity terminal connects directly or via a conductive member to a second surface of the first polarity collector plate.

Cylindrical battery

A nonaqueous electrolyte solution according to one embodiment of the present disclosure contains a lithium salt and a nonaqueous solvent; the nonaqueous solvent contains fluoroethylene carbonate and a chain carboxylic acid ester having a dielectric constant of 6.0 or more; the lithium salt contains LiPOFand LiSOF; and the respective concentrations of LiPOFand LiSOF in the non-aqueous solvent are 0.15 mol/L or more.

Nonaqueous electrolyte solution and nonaqueous electrolyte secondary battery

It is an object of the present invention to provide a nonaqueous electrolyte secondary battery in which swelling due to charge-discharge cycling is inhibited. The nonaqueous electrolyte secondary battery including a flat electrode assembly in which a first electrode plate and a second electrode plate having a different polarity from the first electrode plate are wound with a separator provided therebetween.

Disclosed is an electronic device including: a component that generates heat while operating; a first battery capable of being charged and discharged; a second battery that is capable of being charged and discharged, and has a higher heat resistance than the first battery; and a housing accommodating the component, and providing a first space for accommodating the first battery and a second space for accommodating the second battery. The first space and the second space are arranged such that the temperature of the second battery becomes higher than that of the first battery on average, while the component is operating.

Electronic device

A negative electrode for nonaqueous electrolyte secondary batteries includes a negative electrode core member and a negative electrode mixture layer attached to the negative electrode core member, wherein the negative electrode mixture layer contains negative electrode active material particles with a graphite structure and a binder, the mixture density of the negative electrode mixture layer is 1.5 g/cmto 1.8 g/cm, the ratio I/Iof the diffraction intensity Iof the (002) plane to the diffraction intensity Iof the (110) plane satisfies 60&#x2266;I/I&#x2266;120 as determined by measuring the negative electrode mixture layer by an X-ray diffraction method, the amount of particles with a size of 1 &#x3bc;m to 10 &#x3bc;m in the particle size distribution of a crushed product of the negative electrode mixture layer is 12% to 25% by volume.

Negative electrode for nonaqueous electrolyte secondary batteries and nonaqueous electrolyte secondary battery including the same

Disclosed is a non-aqueous electrolyte secondary battery including a positive electrode including a lithium-containing transition metal composite oxide as a positive electrode active material, a negative electrode including a negative electrode active material, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The positive electrode contains lithium carbonate and lithium hydrogencarbonate in a total amount of 500 ppm or more and 3000 ppm or less, and exhibits a weight loss by temperature increase from 25&#xb0; C. to 300&#xb0; C. at 5&#xb0; C./min of 70% or less of the total amount and of 1500 ppm or less. The non-aqueous electrolyte includes a non-aqueous solvent and a lithium salt. The non-aqueous solvent may contain a cyclic carbonate and a chain carbonate.

Non-aqueous electrolyte secondary battery and method for producing the same

A non-aqueous electrolyte in which the proportion of diethyl carbonate is reduced, and a nonaqueous electrolyte secondary battery using the same that has high safety are provided. The non-aqueous electrolyte of the invention for use in secondary batteries includes ethylene carbonate, propylene carbonate, diethyl carbonate, and an additive, as a non-aqueous solvent. The additive is at least one of a fluorinated aromatic compound having a molecular weight of 90 to 200 and a fatty acid alkyl ester having a molecular weight of 80 to 240. A weight ratio Wethylene carbonate, a weight ratio Wof propylene carbonate, a weight ratio W DEC of diethyl carbonate, and a weight ratio Wof the additive are 5 to 30 wt %, 15 to 60 wt %, 10 to 50 wt %, and 5 to 35 wt %, respectively, to the total of the non-aqueous electrolyte.

Non-aqueous electrolyte and non-aqueous electrolyte secondary battery using the same

A non-aqueous electrolyte secondary battery includes: a positive electrode capable of absorbing and desorbing lithium; a negative electrode capable of absorbing and desorbing lithium; a separator interposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte. The positive electrode includes a composite oxide represented by formula (1): LiNiMLOas an active material. The formula (1) satisfies 0.3&#x2266;x&#x2266;0.9 and 0&#x2266;y&#x2266;0.1. The element M is at least one selected from the group consisting of Co and Mn, and the element L is at least one selected from the group consisting of Mg, Al, Ti, Sr, Zn, B, Ca, Cr, Si, Ga, Sn, P, V, Sb, Nb, Ta, Mo, W, Zr, Y and Fe. The non-aqueous electrolyte includes a main solvent, a solute and vinyl ethylene carbonate.

A nonaqueous electrolyte secondary battery, comprising a positive electrode having a positive-electrode active material layer reversibly inserting and extracting lithium ions on a positive-electrode current collector, a negative electrode having a negative-electrode active material layer reversibly inserting and extracting lithium ions on a negative-electrode current collector, and a nonaqueous electrolyte solution, wherein at least one of the positive and negative electrodes has a film on the surface and at least one of the positive electrode, the negative electrode and the nonaqueous electrolyte solution contains a nitrogen-containing cyclic compound. Such a nonaqueous electrolyte secondary battery is superior in high-temperature storage stability allowing preservation of favorable discharge rate even after high-temperature storage.

Growing community of inventors

Hyogo, Japan

Masaki Deguchi