Umg Abs, Ltd.

Masahito Nakamoto

Hideichiro Kawaguchi

Koichi Tezuka

Iwao Fujimoto

Yoshitaka Naito

Shigeki Hamamoto

Hiroshi Tanigawa

Joichi Watanabe

Hirotoshi Saito

A reinforced thermoplastic resin composition which has good moldability and can increase a rigidity, impact resistance, mechanical strength, heat resistance and flame retardancy of an obtained molded article, and a molded article having a high rigidity, impact resistance, mechanical strength, heat resistance, flame retardancy, and weld strength. The reinforced thermoplastic resin composition including 80% to 100% by mass of a polycarbonate resin (A); a resin main component (C) containing 0% to 20% by mass of a specific graft copolymer (G); a polyethylene terephthalate resin (B) obtained by solid phase polymerization of recycled and/or repelletized material; an inorganic filler (D); and a glycidyl ether unit-containing polymer (E) having a mass average molecular weight of 3,800 to 60,000 at a specific ratio.

Reinforced thermoplastic resin composition and molded article thereof

A reinforced thermoplastic resin composition of the present invention comprises a resin component (C) which consists of 80 to 100% by mass of a polycarbonate resin (A) and 0 to 20% by mass of a specific graft copolymer (G) (wherein the total amount of the polycarbonate resin (A) and the graft copolymer (G) is 100% by mass), a recycled and/or repelletized polyethylene terephthalate resin (B), an inorganic filler (D), and a glycidyl ether unit-containing polymer (E) having a weight average molecular weight of 3,800 to 60,000 in a specified ratio.

A reinforced thermoplastic resin composition is provided containing a resin main component (C) including 50% to 100% by mass of a polycarbonate resin (A) and 0% to 50% by mass of a graft copolymer (B) obtained by polymerizing a monomer mixture containing an aromatic alkenyl compound monomer (a) and a vinyl cyanide compound monomer (b) in the presence of a rubbery polymer (B1), an inorganic filler (D), a glycidyl ether unit-containing polymer (E) having a glycidyl ether unit and a mass-average molecular mass of 3,800 to 60,000, and polyamide 6/66 (F) having a moisture content of 0.1% or less in a specific ratio.

Reinforced thermoplastic resin composition and molded article

A reinforced thermoplastic resin composition comprising specific amounts of: a main resin component (C) comprising 50 to 100% by weight of a polycarbonate resin (A) and 0 to 50% by weight of a graft copolymer (B) obtained by polymerizing an aromatic alkenyl compound monomer (a) and a vinyl cyanide compound monomer (b) in the presence of a rubber polymer (B1); a grass fiber (D); a glycidyl ether unit-containing polymer (E) containing glycidyl ether units and having a weight average molecular weight of 3,800 to 60,000; a phosphoric acid ester-based flame retardant (F); and an organomodified siloxane (G).

A reinforced thermoplastic resin composition containing, in specific proportions, a resin main component (C) composed of a polycarbonate resin (A) and an optional graft copolymer (B), an inorganic filler (D), a glycidyl ether unit-containing polymer (E) having a weight-average molecular weight of 3,800 to 60,000 (excluding (B)), and a phosphorus-containing modified polyester-based resin (H) prepared by modifying a phosphorus-containing polyester-based resin (F), which includes a dicarboxylic acid component containing a cyclic phosphorous compound of formula (1) and has a phosphorus content of at least 4% by masswith a polycarbodiimide compound (G), wherein (B) is a polymer obtained by polymerizing a monomer mixture containing an aromatic alkenyl compound monomer (a) and a vinyl cyanide compound monomer (b) in the presence of a rubber-like polymer (B1).

Reinforced thermoplastic resin composition and molding

A reinforced thermoplastic resin composition containing: a resin main component (C) consisting of 50 to 100% by mass of a polycarbonate resin (A) and 0 to 50% by mass of a graft copolymer (B) obtainable by polymerization of a monomer mixture containing an aromatic alkenyl compound monomer (a) and a vinyl cyanide compound monomer (b) in the presence of a rubber polymer (B1); an inorganic filler (D); a glycidyl ether unit-containing polymer (E) that has a glycidyl ether unit and has the mass average molecular weight of 3,800 to 60,000; and a specific amount of a polyamide (F) that has a moisture percentage of 0.1% by mass or less.

The present invention relates to a reinforced resin composition for plating bases having excellent moldability, mechanical strengths, and plating ability, as well as being capable of improving the surface appearance of the molded article after plating. The reinforced resin composition for plating bases of the present invention includes: graft copolymer (A) in which a graft chain (A2) is grafted to a rubber polymer (A1) a matrix polymer (B) which includes one or more types of polymers selected from the group consisting of a vinyl-based copolymer (B-1), a polycarbonate resin (B-2), and a polyester resin (B-3); an inorganic filler (D); and a glycidyl ether unit-containing polymer (E). The content of the rubber polymer (A1) is from 5 to 25% by mass, relative to 100% by mass of the total amount of the component of (A) and the component of the matrix polymer (B).

Reinforced resin composition for plating base, molded article, and electroplated component

A reinforced thermoplastic resin composition containing: 50 to 90% by weight of a polycarbonate resin; 10 to 50% by weight of a graft copolymer in which a polymer including an aromatic alkenyl compound monomer unit and a vinyl cyanide compound monomer unit is grafted to a rubber polymer; 61 to 129 parts by weight of a grass fiber which has been surface-treated with a water-soluble polyurethane, relative to the total of 100 parts by weight of the polycarbonate resin and the graft copolymer; 0.5 to 20 parts by weight of a glycidyl ether unit-containing polymer; and 10 to 40 parts by weight of a phosphoric acid ester-based flame-retardant agent.

The present invention relates to a reinforced thermoplastic resin composition having excellent moldability, processability, and mechanical strengths, as well as being capable of improving the drop impact resistance (surface impact strength determined by a falling ball test). The reinforced thermoplastic resin composition of the present invention includes 10 to 60% by mass of a graft copolymer (A) having a graft chain (A2) grafted to a rubber polymer (A1); 40 to 90% by mass of a matrix polymer (B) which includes one or more types of polymers selected from the group consisting of a vinyl-based copolymer (B-1), a polycarbonate resin (B-2), and a polyester resin (B-3); 0.1 to 50 parts by mass of an inorganic filler (D); and 0.5 to 20 parts by mass of a glycidyl ether unit-containing polymer (E) having a mass average molecular weight of 3,000 to 200,000.

Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CBof vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CBof vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB&#x2212;CB| is 0% to 3.0% by mass.

Flame-retardant thermoplastic resin composition and molded article thereof

The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.

Growing community of inventors

Ube, Japan

Masahito Nakamoto