Ube Industries, Inc.

Toyota Jidosha Kabushiki Kaisha

Fukoku Co., Ltd.

Masahiro Naiki

Atsushi Morikami

Fumio Adachi

Manabu Takahashi

Masayuki Kinouchi

Ryoichi Takasawa

Tetsuji Hirano

Shuichi Maeda

Takao Nomura

Takeyoshi Nishio

Seiji Ishikawa

Yasuhiro Kawachi

Masahiko Watanabe

Taku Nakamura

Koji Hayashi

Yuji Matsui

Yasuyuki Okamoto

Takenobu Matsumura

Yoshiki Tanaka

Katsutoshi Hirashima

Kosuke Fujiyama

Takeshi Yamada

A coating agent for a wiper blade rubber having superior friction performance and wiping performance, both initially and during use for an extended period, and having superior durability by inhibiting wear and the like, and a wiper blade rubber using the same. The coating agent for the wiper blade rubber includes a solid lubricant and a binder containing a polycarbonate-based polyurethane resin. The wiper blade rubber has the coating agent on both lateral surfaces of a lip portion of the wiper blade rubber.

Coating agent for wiper blade rubber and wiper blade rubber using same

The present invention is to provide an aqueous polyurethane resin dispersion in which a polyurethane resin s dispersed in an aqueous medium, wherein the polyurethane resin is obtained by reacting (A) a polyurethane prepolymer which is obtained by reacting (a) a polyisocyanate compound, (b) a polyol compound containing a polycarbonate polyol having a number average molecular weight of 800 to 3500, and (c) an acidic group-containing polyol compound, and (B) a chain extender, being dispersed in an aqueous medium, (B) the chain extender contains a polyamine compound having three or more in total of an amino group(s) and/or an imino group(s) per molecule, and the polyurethane resin has, each based on a solid content, a content of urethane bonds of 5 to 10% by weight, a content of urea bonds of 2 to 7% by weight, a content of carbonate bonds of 15 to 40% by weight, has neither ether bond nor ester bond, has a density of cross-linking points of 1.0&#xd7;10to 1.0&#xd7;10mol/g, an acid value of 12 to 20 mg KOH/g, and a weight average molecular weight of 100,000 or more.

Aqueous polyurethane resin dispersion and coating composition comprising the same

An aqueous polyurethane resin dispersion containing a polyurethane resin obtained by reacting (A) a polyurethane prepolymer obtained by reacting (a) a polyisocyanate compound, (b) at least one polyol compound containing a polycarbonate polyol having a number average molecular weight of 400 to 3000, (c) an acidic group-containing polyol compound, (d) a blocking agent for an isocyanate group, which dissociates at 80 to 180&#xb0; C., and (B) a chain elongating agent having reactivity with the isocyanate group, being dispersed in an aqueous medium, a sum of a content of urethane and urea bondings is 15 to 30% by weight in terms of solid components, a content of carbonate bondings is 8% to &#x3c;15% by weight in terms of solid components, and a content of isocyanate group to which the above-mentioned blocking agent has bound is 0.2 to 3% by weight in terms of solid components as calculated on isocyanate group.

Aqueous polyurethane resin dispersion and process for preparing the same

An aqueous polyurethane resin dispersion containing a polyurethane resin obtained by reacting (A) a polyurethane prepolymer obtained by reacting (a) a polyisocyanate compound, (b) at least one polyol compound containing a polycarbonate polyol having a number average molecular weight of 400 to 3000, (c) an acidic group-containing polyol compound, and (d) a blocking agent for an isocyanate group, which dissociates at 80 to 180&#xb0; C., and (B) a chain elongating agent having reactivity with the isocyanate group, being dispersed in an aqueous medium, a sum of a content of urethane bondings and a content of urea bondings is 7 to 18% by weight of solid components, a content of carbonate bondings is 15 to 40% by weight of solid components, and a content of an isocyanate group to which the above-mentioned blocking agent has bonded is 0.2 to 3% by weight of solid components and calculated on the isocyanate group.

An object of this invention is to obtain an aqueous polyurethane resin dispersion having excellent drying property, which can provide a coating film having high hardness. The aqueous polyurethane resin dispersion comprises a polyurethane resin obtained by reacting (a) a polyol compound, (b) a polyisocyanate compound, (c) an acidic group-containing polyol compound and (d) a chain-elongating agent, which is being dispersed in an aqueous medium, wherein the above-mentioned (a) polyol compound contains at least (a1) a polycarbonate polyol having an alicyclic structure at the main chain and (a2) a polymer polyol having a number average molecular weight of 500 to 5000 and having no alicyclic structure.

Disclosed is an aqueous polyurethane resin dispersion which comprises a polyurethane resin which is obtained by reacting (A) a polyurethane prepolymer obtained by reacting (a) a polycarbonate polyol having an alicyclic structure in the main chain, (b) an acidic group-containing polyol compound and (d) a polyisocyanate, and (B) a chain-elongating agent, being dispersed in an aqueous medium, a carboxylic acid group content of the above-mentioned (A) polyurethane prepolymer based on a solid component of (A) the polyurethane prepolymer is 2.0 to 13.0% by weight, and a number of a hydroxyl equivalent of a mixture of the above-mentioned (a) polycarbonate polyol having an alicyclic structure in the main chain, the above-mentioned (b) acidic group-containing polyol compound, and, if necessary, (c) a polyol other than (a) and (b) is 70 to 270.

Aqueous polyurethane resin dispersion, preparation method of the same, and coating composition containing the same

The phosphorus-containing polycarbonate polyol disclosed herein has a structural unit (I) represented by a formula: &#x2014;OCOO&#x2014; and a structural unit (II) represented by a residue A, wherein A denotes a n-valent residue in which n of alcoholic hydroxyl groups are removed from a phosphorus compound having at least n of alcoholic hydroxyl groups, in which n is an integer of 2 or larger, and wherein a terminal group of the polyol is a alcoholic hydroxyl group. The novel phosphorus-containing polycarbonate polyol, as a reactive flame-retardant agent, can provide flame-retardant properties easily to polyurethane or the like.

Phosphorus-containing polycarbonate polyol, method for production thereof, and phosphorus-containing polycarbonate polyurethane

A curable polyimide resin composition containing a polyimide resin obtainable from by a reaction of a reaction mixture containing a diisocyanate compound, a carbonate group-containing diol compound and an imide compound having two terminal hydroxyhydrocarbyl groups gives a cured insulation film having improved characteristics.

Polyimide resin and curable resin composition

A process for packaging an electronic device employs an insulating protective resin layer produced from one or more of the resin compositions: (1) 100 parts of an organic solvent-soluble resin having a polysiloxane skeleton and a polar group, 0.5 to 30 parts of an epoxy compound having an epoxy equivalent of more than 800, and an organic solvent, (2) 100 parts of an organic solvent-soluble resin having a polysiloxane skeleton and a polar group, 0.1 to 10 parts of an epoxy compound having an epoxy equivalent of 100 to 800, 2 to 30 weight parts of a polyvalent isocyanate compound, and an organic solvent; and (3) 100 parts of an organic solvent-soluble resin having a polysiloxane skeleton and a polar group, 0.1 to 20 parts of an epoxy compound having an epoxy equivalent of more than 800, 2 to 30 parts of a polyvalent isocyanate compound, and an organic solvent.

Process for packaging electronic devices

A modified polyimide resin favorably employable for manufacturing an insulation film of an electric-electronic device is composed of recurring units (I) derived from a biphenyltetracarboxylic acid compound, a diamine compound, and a monoamine compound having at least one hydroxyl group and recurring units (II) derived from diisocyanate and polybutadiene having hydroxyl group at each terminal, which optionally contains further recurring units (III) derived from diisocyanate and a compound having hydroxyl group at each terminal and further having a reactive substituent.

Modified polyimide resin and curable resin composition

A flexible wiring board for tape carrier package having improved flame resistance is disclosed. The flexible wiring board has an insulating film having a bending slit, a wiring pattern formed thereon and crossing the bending slit, an adhesive layer adhering the wiring pattern to the insulating film, a flex resin layer protecting the wiring pattern at the bending slit, and an overcoat layer protecting the wiring pattern, in which the overcoat layer is obtained from a curable resin composition, when cured into a form of film, the film has an initial modulus of 10 to 1,500 MPa at 25&#xb0; C., an electrical insulation of sufficient level, a soldering resistance of 10 seconds at 260&#xb0; C., and an oxygen index exceeding 22.0.

Flexible wiring board for tape carrier package having improved flame resistance

A polypropylene resin composition comprising an isotactic polypropylene component, a rubber component, and an inorganic filler component, wherein (a) the melt flow rate, according to ASTM D1238, is 20 g/10 min or more, (b) the flexural modulus, according to ASTM D790, is 2300 MPa or more, (c) the Izod impact strength, according to ASTM D256, is 180 J/m or more at 23.degree. C. and 45 J/m or more at -30.degree. C., (d) the heat deformation temperature, according to ASTM D648, is 130.degree. C. or more, and (e) there is a diffraction peak unique to polypropylene of space group P21/c in the diffraction pattern measured by the wide angle X-ray diffraction method in an injection molded article of the composition formed under a quenching condition.

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Ube, Japan

Masahiro Naiki