Mitsui Petrochemical Industries, Ltd.

General Electric Company

Mitsui Chemicals, Inc.

Shimadzu Corporation

Masahide Tanaka

Tetsuo Hayashi

Tomoaki Shimoda

Kinya Mizui

Kazunori Takahata

Takashi Hayashi

Tokinori Agou

Tadaaki Fujimoto

Takeshi Sakashita

Yoshihisa Kiso

Takato Kimura

Hideki Hirano

Hajime Oyoshi

Kenji Shimamoto

Masaru Sudo

Masahiro Kuwabara

Norio Kashiwa

Masaaki Kawasaki

Keiji Okada

Eiichi Ozeki

Masayasu Ishibashi

Kenichi Morizono

Shuji Minami

Ryousuke Kaneshige

Hidenori Kaya

Hiroki Kuyama

Takeshi Ishitoku

Saburo Fuji

Kazutoyo Uno

Kazuyuki Watanabe

Hitomi Matsuzaki

Ryosuke Kaneshige

Masaru Sudou

Kunihiko Takeuchi

Naoya Sakamoto

Takami Nishikawa

Jiro Ishihara

Takamasa Tsumoto

Masahiro Kuwahara

Kosei Nakamura

The specification describes a method for manufacturing dialkyl carbonate by reacting carbon monoxide, oxygen and alcohol in the presence of a catalyst. The catalyst is produced by reacting together ingredients including a cupric halide and an alkoxide compound of a group III through VII metal.

Method for manufacturing dialkyl carbonate

A composition prepared by adding as the sliding properties improving agent a small amount of ethylene-&agr;-olefin random copolymer having polar groups to engineering plastics including polyacetal, ABS, and polyamide is suitable for the manufacture of gears, rotary shafts and bearings by way of exploiting its molding processibility including excellent mold release properties, and at the same time is capable of enhancing its friction/wear resistance. As the sliding properties improving agent, an oxidation-modified material produced from ethylene-&agr;-olefin random copolymer or a graft-modified material prepared by graft-copolymerizing an ethylenic unsaturated monomer having carboxylic acid group, hydroxyl group or the like with ethylene-&agr;-olefin random copolymer is particularly preferable.

Molding resin composition

The present invention is directed towards a lubricating oil comprising a random copolymer of an &agr;-olefin/aromatic vinyl compound, wherein the copolymer has a viscosity falling within a specific range and comprises ethylene, an aromatic vinyl compound, and optionally an &agr;-olefin. The lubricating oil possesses excellent viscosity properties, thermal stability, oxidation stability, abrasion resistance, and compatibility with lubricating oil additives. The random copolymer having a different viscosity range is useful as a viscosity index improver and a compatibilizing agent for a lubricating oil. The invention also provides a lubricating oil composition comprising a base oil and the viscosity index improver or the compatibilizing agent. The invention further provides a fuel oil composition comprising a fuel oil fluidity improver based on the above random copolymer having a different viscosity range and a middle fraction fuel oil having a boiling point of 150 to 400&deg; C. The fuel oil composition prevents an increase in viscosity of the middle fraction fuel oil, lowers the clogging point and the flow point in a low-temperature filter, and inhibits the abrasion of a fuel jet nozzle.

Lubricating oil or lubricating oil composition and fuel oil composition

The present invention provides a method, which makes it possible to manufacture aromatic carbonates from dialkyl carbonates and aromatic hydroxy compounds inexpensively and with good efficiency. The method uses a titanium catalyst in a particular amount relative to aromatic polyhydric hydroxy compound impurities in a crude aromatic hydroxy compound solution.

Method for manufacturing aromatic carbonates

A crosslinked polycarbonate is obtained by polycondensation of diol (A), trivalent or more polyhydric alcohol (B) whose arbitrary two hydroxy groups are not in the positional relationship of 1,2-disubstitution or 1,3-disubstitution, and carbonyl component (C) such as carbonic acid diesters. In the polycondensation step, no side reaction does not occur. This crosslinked polycarbonate is used as a modifier for polylactic acids. The brittleness of the polylactic acid is improved while maintaining mechanical strength, thermostability, and transparency.

Crosslinked polycarbonate and polylactic acid composition containing the

A monocarbonate represented by the formula (R.sup.1).sub.n Ph--O(R.sup.2 O).sub.m --CO--O--CH.sub.2 --C(R.sup.3)(R.sup.4)(R.sup.5), a lubricating oil containing this monocarbonate, and a process for preparing a composition of this monocarbonate, a monocarbonate to which are bonded, via carbonic acid, two (R.sup.5)(R.sup.4)(R.sup.3)C--CH.sub.2 -- groups and a monocarbonate to which are bonded, via carbonic acid, two (R.sup.1).sub.n Ph--(OR.sup.2).sub.m -- groups. The monocarbonate exhibits excellent lubricating property, cleaning property and electrically insulating property, exhibits excellent compatibility with hydrogenated fluorocarbons such as R-134a, and can be favorably used as a lubricating oil for refrigerators such as electric refrigerators and air conditioners for room.

Monocarbonates, use thereof and process for the preparation of

Lubricating oil containing aromatic ether compounds

The polycarbonates of the present invention include those of sucrose series having a specific cyclic structure, those of oligosaccharide and monosaccharide series other than the sucrose series, those derived from specific saccharides having no cyclic structure, those having a skeletal structure of pentaerythritol, neopentyl glycol or trimethylolmethane, and specific dicarbonates. The lubricating oil and electrical insulating oil of the invention contain the above-mentioned polycarbonates. The polycarbonates of the invention are excellent in compatibility with Freon R-134a (HFC) as well as in lubricating properties, detergency and electrical insulating properties, and are capable of providing lubricating oil for refrigerator, automotive engine oil, automotive gear oil, lubricating oil for rolling and lubricating oil for fiber, especially lubricating oil for which electrical insulating properties are required, and electrical insulating oil.

Polycarbonates, uses thereof, processes for preparing and purifying same

The polycarbonates of the present invention include those of sucrose series having a specific cyclic structure, those of oligosaccharide and monosaccharide series other than the sucrose series, those derived from specific saccharides having no cyclic structure, those having a skeletal structure of pentaerythritol, neopentyl glycol or trimethylolmethane, and specific dicarbonates. The lubricating oil and electrical insulating oil of the invention contain the above-mentioned polycarbonates. The polycarbonates of tile invention are excellent in compatibility with Freon R-134a (HFC) as well as in lubricating properties, detergency and electrical insulating properties, and are capable of providing lubricating oil for refrigerator, automotive engine oil, automotive gear oil, lubricating oil for rolling and lubricating oil for fiber, especially lubricating oil for which electrical insulating properties are required, and electrical insulating oil.

The present invention provides lubricant oil compositions comprising a polyalkylene glycol carbonate. The lubricant oil compositions are useful for industrial gear oil, automotive gear oil, and lubricant oil for refrigerators, rolling installations and fibers, which are excellent in lubricating properties and detergency. The present invention also relates to lubricant oil compositions which comprise a polyalkylene glycol polycarbonate having mutual solubility with an ozone layer-nondestructive Freon such as Freon R-134a, and which are accordingly especially suited for refrigerators using hydrogenated fluorocarbon as a refrigerant. A polyalkylene glycol carbonate according to the invention comprises a polyoxypropylene group in the molecular chain and an alkyl group and an alkyloxyalkylene group at the molecular terminals. This invention provides a process for preparing said polyalkylene glycol polycarbonate wherein a polypropylene glycol and a carbonate are allowed to react, said reaction including condensation polymerization. The invention also provides a process without condensation polymerization for preparing a polyalkylene glycol polyol wherein a polyol and a carbonate is allowed to react in the presence of a basic catalyst while a produced alcohol is being distilled off, the catalyst is removed then, and the unreacted carbonate is eliminated.

Polyalkylene glycol polycarbonate based lubricant oil composition

The polycarbonate of the invention is a polycarbonate derived from adducts such as propylene oxide adducts of polyglycerols. The lubricating oil of the invention comprises this polycarbonate, and if necessary, a specific polycarbonate having a --C.sub.2 H.sub.4 O-- group and/or a --CH.sub.2 CH(CH.sub.3)O-- group in its main chain. The lubricating oil of the invention can be used as a lubricating oil for refrigerators such as automotive air-conditioner and electric refrigerator. In particular, the lubricating oil of the invention is suitable as a lubricating oil for refrigerator wherein high-viscosity lubricating oil is used, for example, lubricating oil for automotive rotary air-conditioner, and also suitable as lubricating oil for a refrigerator wherein ozone layer-nondestructive hydrogenated fluorocarbon such as R-134a is used as a refrigerant.

Polycarbonate and use thereof

A polycarbonate lubricating oil composition which is resistant to decomposition of the polycarbonate and the generation of carbon dioxide gas. The lubricating oil composition contains a polycarbonate lubricant, at least one compound selected from the group of epoxy compound, phenol compound, sulfur compound and amine compound, and optionally a triester phosphite or a triester phosphate compound as inhibitors to the generation of carbon dioxide gas. The lubricating oil composition are stable, have excellent lubricating properties, cleaning properties, and electrical insulating properties, and their viscosity at low temperature can readily be lowered.

Lubricating oil composition

The present invention provides lubricant oil compositions comprising polyalkylene glycol polycarbonates. The lubricant oil compositions are useful as industrial gear oils, automotive gear oils, lubricant oils for refrigerators and rolling installations. The lubricant oils exhibit excellent lubricating properties and detergency and also have mutual solubility with an ozone layer nondestructive Freon such as R-134a. The lubricants of the present invention are especially suited for refrigerator systems using a hydrogenated fluorocarbon as a refrigerant.

Lubricant oil, polyalkylene glycol polycarbonates and process for

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Ichihara, Japan

Masahide Tanaka