Sumitomo Chemical Company, Limited

Masahide Mohri

Yoshio Uchida

Yoshinari Sawabe

Hisashi Watanabe

Shinichiro Tanaka

Tetsu Umeda

Norio Matsuda

Hironobu Koike

Hiroshi Ogawa

Kenji Nakane

Kunio Saegusa

Akira Hasegawa

Yasunori Nishida

Shinji Fujiwara

Hiroshi Tabuchi

Takeshi Miyai

Alpha alumina powder having a regulated particle size, a uniform particle shape and a narrow particle size distribution and further a low halogen content is produced by calcining at least one starting material selected from transition alumina and alumina compounds in a halogen-containing atmosphere which comprises a hydrogen halide gas, a halogen gas or a mixture of a halogen gas and steam and contains at least 0.1% by volume of at least one halogen-containing gas selected from the group consisting of hydrogen halide gas and halogen gas, and removing halogen from a calcined material. The produced alpha-alumina powder is excellent in a packing property and homogeneously packed.

Method for producing &agr;-alumina powder

A process for producing &agr;-alumina containing &agr;-alumina single crystal particles characterized in that at least one of a transition alumina and transition alumina precursor is calcined in an atmosphere containing at least 1% by volume of hydrogen chloride at a temperature of not less than 600&deg; C., preferably from 600 to 1,400&deg; C., and more preferably from 800 to 1,200&deg; C. Aluminum hydroxide, alum, aluminum sulfate, etc. are used as the alumina raw material capable of being converted to transition alumina on heating. &agr;-Alumina comprising octahedral or higher polyhedral &agr;-alumina single crystal particles have a high alumina purity above a given level, are fine and homogeneous, have a narrow particle size distribution, are not agglomerated particles, and can be obtained from raw materials of various kinds, purities, shapes, sizes, and compositions.

Process for producing &agr;-alumina

A metal oxide powder except &agr;-alumina, is disclosed comprising polyhedral particles having at least 6 planes each, a number average particle size of from 0.1 to 300 &mgr;m, and a D,/D,ratio of 10 or less where D,and D,are particle sizes at 10% and 90% accumulation, respectively from the smallest particle size side in a cumulative particle size curve of the particles. This metal oxide powder contains less agglomerated particles, and has a narrow particle size distribution and a uniform particle shape.

Metal oxide powder and method for the production of the same

.alpha.-Alumina comprising .alpha.-alumina single crystal particles which are homogeneous containing no crystal seed inside the particles; have an octa- or higher polyhedral shape; have a D/H ratio of from 0.5 to 3.0, wherein D represents a maximum particle diameter parallel to a hexagonal lattice plane of a hexagonal close-packed lattice of the particles, and H represents a diameter perpendicular to the hexagonal lattice plane; have a number average particle diameter of more than 5 .mu.m and not more than 30 .mu.m; have a sodium content of less than 5 ppm in terms of Na.sub.2 O; and have an alumina purity of not less than 99.90% by weight. .alpha.-Alumina in a powder form composed of .alpha.-alumina single crystal particles having a high punity, a fine and uniform composition, a narrow particle size distribution, and an octa- or higher polyhedral shape which are not aggromerates. The .alpha.-alumina of the invention is useful as an abrasive, a raw material for sintered products, a raw material for a encapsulations, a raw material for ceramic filters, etc. and, owing to its high purity, particularly useful as a raw material for single crystals, e.g., yttrium aluminum garnet (YAG), sapphire, ruby, etc. and as a raw material for high purity sintered products.

.alpha.-alumina

A powdery .alpha.-alumina having an alumina purity of at least 99.8 wt. %, a sodium content of 40 ppm or less and an iron content of 20 ppm or less, which is obtained by grinding aluminum hydroxide which is produced by the Bayer process or a transition alumina which is obtained by precalcining aluminum hydroxide produced by the Bayer process, and calcining the aluminum hydroxide or transition alumina in an atmosphere containing 1 vol. % or more of a hydrogen chloride gas, or an atmosphere containing 1 vol. % or more of a chlorine gas and 0.1 vol. % or more of steam, at a temperature of 600 to 1400.degree. C.

Alpha-alumina and method for producing same

A process for producing .alpha.-alumina powder comprising the step of calcining at least one of transition alumina and a transition alumina precursor capable of becoming transition alumina on heating, in a gas atmosphere containing (1) a hydrogen halide, (2) a component prepared from a halogen and steam or (3) a halogen, in the presence of at least one of a seed crystal and a shape-controlling agent. The .alpha.-alumina powder is particularly useful as a raw material for abrasives, fillers, sinters or spacers which comprises .alpha.-alumina particles having a substantially octahedral or eicosahedral shape, a specific structure, and a narrow primary particle size distribution.

.alpha.-alumina powder and process for producing the same

Alpha alumina powder is produced by granulating at least one alumina starting material selected from group consisting of transition alumina and alumina compound to obtain particles and calcining the particles in a halogen-containing atmosphere which comprises a hydrogen halide gas, a halogen gas or a mixture of a halogen gas and steam and contains at least 0.1 % by volume of at least one halogen-containing gas selected from the group consisting of hydrogen halide gas and halogen gas. By granulating the alumina starting material powder in the form of particles to increase a bulk density and calcining them in the presence of halogen, .alpha.-alumina powder having a regulated particle size and shape and a narrow particle size distribution and containing fewer agglomerated particles is produced at a high calcining efficiency.

Method for producing alpha-alumina powder

An inorganic porous sintered body comprising inorganic particles of polyhedral crystals, said inorganic porous sintered body having pores formed by the inorganic particles, wherein said pores have a pore size distribution that a ratio of D10 to D90 is not more than 3 and D50 is 0.01-5 .mu.m when D10, D50 and D90 are pore sizes at 10%, 50% and 90% cumulation from the largest pore size of a cumulative pore volume distribution, respectively, and a porosity is 10-50%.

Inorganic porous sintered body and filter

Complex metal oxide powder and method for the production of the same

An alumina composition, an alumina molded article, prepared from the alumina composition, an alumina ceramic prepared by sintering the alumina molded article, and a process for producing the ceramic; the alumina composition comprising .alpha.-alumina particles having a ratio of the shortest diameter to the longest diameter of from 0.3 to 1; and a size distribution of not more than 5, as expressed in terms of a D.sub.90 /D.sub.10 ratio, wherein D.sub.10 and D.sub.90 represent a cumulative 10% diameter and a cumulative 90% diameter, respectively, of a cumulative distribution depicted from the small diameter side, or comprising .alpha.-alumina particles having a polyhedral shape; a D/H ratio of from 0.5 to 3.0, wherein D represents a maximum particle diameter parallel to a hexagonal lattice plane of a hexagonal close-packed lattice of .alpha.-alumina, and H represents a particle diameter perpendicular to the lattice plane; and a size distribution of not more than 5, as expressed in terms of a D.sub.90 /D.sub.10 ratio, wherein D.sub.10 and D.sub.90 are as defined above.

Alumina composition, alumina molded article, alumina ceramics, and

An aluminum nitride powder comprising polycrystalline particles which have clearly observed grain boundaries, an agglomerated particle size of 0.1 to 100 .mu.m when measured by a particle size distribution analyzer, a tapped bulk density of 0.55 to 2.0 g/cm.sup.3, and a ratio of a number average particle size calculated from a SEM photograph image to a particle size calculated from a BET specific surface area of 1.1 to 3.

Aluminum nitride powder

A process for producing .alpha.-alumina powder comprising .alpha.-alumina single crystal particles, the process comprising the step of calcining at least one of transition alumina and a transition alumina precursor capable of becoming transition alumina on heating, in a gas atmosphere containing (1) at least about 5% by volume, based on the total gas atmosphere, of a halogen selected from fluorine, chlorine, bromine, and iodine, (2) at least about 1% by volume, based on the total gas atmosphere, of a hydrogen halide selected from hydrogen fluoride, hydrogen bromide, and hydrogen iodide, or (3) a component prepared from at least about 1% by volume, based on the total gas atmosphere, of a halogen gas selected from fluorine gas, bromine gas, and iodine gas, and at least about 0.1% by volume, based on the total gas atmosphere, of steam.

Process for producing alpha-alumina powder

A method of preparing dense sintered bodies of beta alumina suitable for solid electrolytes, which comprises preparing a shaped body from a mixture containing an aluminum powder, a sodium compound, a structure stabilizer and a zirconia powder or from a mixture containing an aluminum powder, an alumina powder, a sodium compound, a structure stabilizer and a zirconia powder, and reaction-sintering the shaped body.

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Ibaraki, Japan

Masahide Mohri