Nippon Steel Corporation

Nippon Steel Sumitomo Metal Corporation

Masafumi Usui

Noriyuki Negi

Masaharu Ibaragi

Masako Nakai

Kohei Ueda

Atsuo Koga

Sukeyoshi Yamamoto

Masumi Koori

To provide a metal-fiber reinforced resin material (FRP) composite having a good appearance even when used as an automobile outer panel and not deformed even after a coating and baking process. The metal-FRP composite of the invention has a laminated structure of three or more layers, having at least a metal layer, a fiber-reinforced resin material layer holding a reinforced fiber material in a layer constituted by a matrix resin, and a resin layer located between the metal layer and the fiber-reinforced resin material layer. The resin layer is a layer constituted by a room temperature curing adhesive or by a predetermined resin and the room temperature curing adhesive. An elastic modulus E of the resin layer is more than 0.1 MPa and 1000 MPa or less, and a thickness of the resin layer is 0.005 times or more and less than 7.500 times a thickness of the metal layer.

Metal-fiber reinforced resin material composite

A metal-fiber reinforced resin material composite body is provided with: a metal member; a fiber-reinforced resin material which is superposed on at least one surface of the metal member so as to be complexed with the metal member; and a bonding resin layer which is interposed between the metal member and the fiber-reinforced resin material. The fiber-reinforced resin material includes a matrix resin that contains 50 parts by mass or more of a phenoxy resin in 100 parts by mass of the resin component and a reinforcing fiber material that is contained in the matrix resin; the concentration of the phenoxy resin in the resin component of the bonding resin layer is lower than the concentration of the phenoxy resin in the resin component of the matrix resin; and the shear strength between the metal member and the fiber-reinforced resin material is 0.8 MPa or more.

Metal-fiber reinforced resin material composite body and method for producing metal-fiber reinforced resin material composite body

The invention has as its object the provision of a metal-fiber reinforced plastic composite able to more reliably prevent occurrence of an electrolytic corrosion action when forming a composite of a metal member and a fiber reinforced plastic layer comprising reinforcing fiber (carbon fiber) and a matrix resin. A metal-fiber reinforced plastic compositeaccording to the present invention comprises a metal member, an insulating layerarranged on at least part of a surface of the metal memberand comprising a first matrix resincontaining nonconductive fiber, and a CFRP layerarranged on at least part of a surface of the insulating layerand comprising a second matrix resincontaining carbon fiber, wherein, when viewing the surface of the metal memberfrom vertically above, the CFRP layeris positioned at the inside of a region where the insulating layeris present and an outer edge of the CFRP layerand an outer edge of the insulating layerare 0.2 mm or more apart. Due to this, it is possible to prevent electrolytic corrosion of the metal member.

Metal-fiber reinforced plastic composite

A composite of metal and carbon-fiber-reinforced plastic according to the present invention comprising a predetermined metal member, a resin layer positioned at a surface of at least part of the metal member and containing an inorganic filler having a thermal conductivity of 20 W/(m·K) or more, and carbon fiber reinforced plastic positioned on the resin layer and containing a predetermined matrix resin and carbon reinforcing fiber present in the matrix resin, the carbon reinforcing fiber being at least one of pitch-based carbon reinforcing fiber having a thermal conductivity of 180 to 900 W/(m·K) in range or PAN-based carbon reinforcing fiber having a thermal conductivity of 100 to 200 W/(m·K) in range, a content of the inorganic filler in the resin layer being 10 to 45 vol % in range with respect to a total volume of the resin layer, a number density of the inorganic filler present in a region of a width X μm from an interface of the resin layer and the carbon fiber reinforced plastic in a direction of the resin layer being 300/mmor more, where X μm is an average particle size of the inorganic filler.

Composite of metal and carbon-fiber-reinforced plastic and method for manufacturing composite of metal and carbon-fiber-reinforced plastic

[Problem] A metal-fiber reinforced resin material composite is provided which improves the shear strength between a metallic member and a fiber reinforced material by more strongly bonding the metallic member and the fiber reinforced resin member, and which is very light and has excellent workability while increasing strength. [Solution] This metal-fiber reinforced resin material composite is provided with a metallic member and with a fiber reinforced resin material that is stacked on at least one surface of the metallic member and combined with the metallic member, wherein the fiber reinforced resin material comprises a matrix resin containing a thermoplastic resin, a reinforcing fiber material included in the matrix resin, and a resin layer interposed between the reinforcing fiber material and the metallic member and comprising a resin of the same type as the matrix resin. The shear strength of the metallic member and the fiber reinforced resin material is greater than or equal to 0.8 MPa.

Metal-fiber-reinforced resin material composite and production method thereof

[Problem] To provide a metal/fiber-reinforced resin material composite in which a metal member and a fiber-reinforced resin material are firmly bonded, a light weight and excellent workability are obtained while the strength is enhanced, and the amount of the fiber-reinforced resin material used can be reduced. [Solution] A metal/fiber-reinforced resin material composite comprising a metal member, and a first fiber-reinforced resin material having a matrix resin and a reinforcement fiber material, the metal member and the first fiber-reinforced resin material being formed into a composite with an adhesive resin layer interposed therebetween, wherein the adhesive resin layer is obtained by solidifying or curing an adhesive resin composition containing at least 50 mass parts of a phenoxy resin (A), and the maximum load of the metal/fiber-reinforced resin material composite is greater than the total load of the maximum load of the metal member alone and the maximum load of the fiber-reinforced resin material alone (i.e., so as to display a 'super-law-of-mixture (or law of over-mixture)' that surpasses the law of mixture with respect to the tensile load).

Metal/fiber-reinforced resin material composite

Provided is a composite particle which can improve the capacity per volume and charge-discharge cycle characteristics. The composite particle includes a plurality of specific particles and a binding material. The specific particle contains an alloy phase. The alloy phase undergoes thermoelastic diffusionless transformation when releasing metal ions or occluding metal ions. The binding material contains at least one of non-graphite carbon and a carbon precursor. The plurality of specific particles bind with each other via the binding material.

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Tokyo, Japan

Masafumi Usui