Other

Nippon Ketjen Co., Ltd.

Masafumi Shimowake

Katsuhisa Fujita

Tetsuro Kamo

Akira Hino

Satoshi Abe

Yoshimasa Inoue

Eiichi Yano

Nobuhito Matsumoto

The present invention pertains to a catalyst comprising 7&#x2013;20 wt. % of a Group VIB metal component, calculated as trioxide on the weight of the catalyst, and 0.5 to 6 wt. % of a Group VIII metal component, calculated as oxide on the weight of the catalyst, on a porous inorganic carrier. The catalyst has a specific surface area of 100&#x2013;180 m/g, a total pore volume of at least 0.55 ml/g, at least 50% of the total pore volume in pores with a diameter of at least 20 nm (200 &#x212b;), 10&#x2013;30% of the total pore volume in pores with a diameter of at least 200 nm (2000 &#x212b;), and 0&#x2013;1% of the total pore volume in pores with a diameter above 1000 nm (10000 &#x212b;). The catalyst is particularly suitable for the hydroprocessing of heavy hydrocarbon feeds of which at least 50 wt. % boils above 538&#xb0; C. (1000&#xb0; F.). It is especially advantageous for the hydroprocessing of feedstocks of which at least 80 wt. % boils above 538&#xb0; C. (1000&#xb0; F.).

High-macropore hydroprocessing catalyst and its use

The invention pertains to a process for preparing spherical oxide particles comprising the steps of shaping a starting material comprising an oxide hydrate into particles of substantially constant length by leading the material to a set of two rolls rotating towards each other followed by leading the material to a roll equipped with grooves to form rod-type shapes, cutting the rod-type shapes into particles of substantially constant length, converting the thus formed particles into spheres, and heating the particles to convert the oxide hydrate into an oxide. The process results in particles in which there is substantially no difference in density between the core portion and the shell portion of the particles, which results in a high abrasion resistance. The particles prepared by the claimed process are particularly suitable for the preparation of hydroprocessing catalysts, more in particular for the preparation of hydroprocessing catalysts suitable for the hydroprocessing of heavy hydrocarbon feeds.

Process for producing spherical oxide particles

The invention relates to a spherical catalyst composition comprising a Group VI metal component and optionally a Group VIII metal component on a carrier, which catalyst has a particle size of 0.5-7 mm, a total pore volume of 0.5-1.3 ml/g, an average pore diameter of 15-30 nm, and a % PV(>100 nm) of 2-30%, there being substantially no difference in density between the core region of the carrier particles and their surface regions. The catalyst is particularly suitable for use in non-fixed bed processes for the hydroprocessing of heavy hydrocarbon feeds. It has high hydrodesulfurization and hydrodemetallization activity in combination with a high abrasion resistance.

Hydroprocessing catalyst and process

A catalyst composition suitable for effecting simultaneous hydrodesulphurisation and hydrodemetallisation of sulphur and metals containing feedstocks which shows a high hydrodesulphurisation activity, a high hydrodemetallisation activity, and a long life is disclosed. The catalyst includes: a) a support, at least 90 wt. % of which includes alumina, which alumina has an R value of from 0.08 to 0.30, the R value being defined as the ratio between the integrated intensity of the X-ray diffraction peak at 2 .theta.=32.degree. and the integrated intensity of the X-ray diffraction peak at 2 .theta.=46.degree., b) from 2 to 8 wt. % of a Group VIB metal component, calculated as metal, c) from 0.5 to 2.5 wt. % of a Group VIII metal component, calculated as metal; and d) a pore size distribution as determined by nitrogen adsorption satisfying the following requirements: (i) a pore volume of from 0.5 to 1.0 ml/g, (ii) an average pore diameter of from 18 to 30 nm, and (iii) of the pore volume of pores with a diameter below 60 nm at least 40% is present in pores within a range of the average pore diameter .+-.5 nm. A process for use of this catalyst and for its preparation is also disclosed.

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Niihama, Japan

Masafumi Shimowake