Kansai Paint Company, Ltd.

Sanyo Chemical Industries, Ltd.

Sankyo Organic Chemicals Co., Ltd.

Masafumi Kume

Yasuhiro Fujii

Komaharu Matsui

Tadayoshi Hiraki

Haruo Nagaoka

Shinji Sugiura

Osamu Iwase

Eisaku Nakatani

Ichiro Tabushi

Takashi Udagawa

Hidehiko Haneishi

Akira Tominaga

Yoichi Masubuchi

Yoshio Yasuoka

Hirosi Oosumimoto

Tadashi Watanabe

Akimasa Nakahata

Masaru Mitsuji

Tadayoshi Tatsuno

Kenji Yamamoto

Yasuyuki Hirata

Kiyoshi Kato

Takahisa Kasukawa

Kazuyuki Morimoto

Hiroshi Oosumimoto

Hideo Kogure

Koji Kamikado

Heihachi Murase

Toshio Ohkoshi

Teiji Katayama

Yuzo Miyamoto

Kyoichi Horibe

Masanobu Kudoh

Hirokazu Hayashi

Masahiko Sagane

Hiroshi Nishimoto

Susumu Midogohchi

Toshio Ogasawara

Masayuki Misawa

Haruhiko Kataoka

Masato Yamamoto

Yoshimitsu Tsukahara

Kenichi Yoneyama

Akira Motohashi

Tetsuya Takasu

Kazuo Masuda

Katsuya Sera

The present invention provides a cationic electrodepositable coating composition comprising:

Cationic electrodepositable coating composition and coating method using

This invention provides a cationic electrodepositable coating composition comprising: (A) 30 to 1% by weight of a high-molecular-weight polyurethane resin prepared by reacting (a) an organic polyisocyanate, (b) a high-molecular-weight polyol, and (c) a diol having at least one tertiary amino group, the high-molecular-weight polyurethane resin (A) having a SP value of 9.5 to 12.0 and a number average molecular weight of at least 15,000; and (B) 70 to 99% by weight of an epoxy-type cationic electrodepositable resin.

Electrodepositable coating composition

An electrodeposition paint composition which contains a titanium oxide pigment coated with 1 to 10% by weight of an zinc compound in terms of metal zinc based on the titanium oxide. It is possible by use of the composition to form a coating film excellent in corrosion resistance without using an anticorrosive pigment having a problem on measures against environmental pollution.

Electrodeposition paint composition

Cationically electrodepositable (gelled) fine particles using, as the base, an epoxy resin-amine adduct having hydrolysable alkoxysilane groups, and a cationic electrodeposition paint composition comprising said fine particles. Said fine particles give a paint film having excellent corrosion resistance and are useful as a rheology-controlling agent for cationic electrodeposition paint. Said electrodeposition paint composition has an excellent edge-covering property, and a paint film formed therewith on an article to be coated can give improved corrosion resistance to the edges of said article and has good surface smoothness.

Cationically electrodepositable fine particles derived from

Film-formable, chelate-forming resin, process for preparation thereof,

A blocked isocyanate group-containing electrocoating composition comprising at least one dialkyltin aromatic carboxylate and at least one bismuth or zirconium compound as a combined curing catalyst. This electrocoating composition gives an electrocoating film superior in corrosion resistance and low-temperature curability and has good bath stability over an extended period.

Electrocoating composition containing blocked isocyanate, dialkyltin

An electrodeposition paint composition which contains at least one lanthanum compound. When this composition is used, electrolytically deposited coating films exhibiting excellent corrosion resistance can be provided, without using rust inhibiting pigments such as of lead compounds or chromium compounds which are liable to cause environmental pollution.

Electrodeposition paint compositions

A cationically electrodepositable finely divided gelled polymer obtained by emulsion-polymerizing, in the presence of a water-soluble or water-dispersible cationic resin, a monomer component (A) comprising (a) a polymerizable unsaturated vinylsilane monomer having a vinylic double bond and a hydrolyzable akloxysilane group, (b) a polymerizable monomer having at least two radically polymerizable unsaturated groups in the molecule, (c) a polymerizable unsaturated monomer having a vinylic double bond and a hydroxyl group, and (d) other polymerizable unsaturated monomer, and a cationically electrodepositable finely divided gelled polymer obtained by emulsion-polymerizing, in the presence of the above finely divided gelled polymer, a monomer component (B) comprising (e) a blocked mono- or polyisocyanate in which the at least one isocyanate group in the molecule is blocked with a radically polymerizable monohydroxy compound, (f) a polymerizable unsaturated monomer having a vinylic double bond and a hydroxyl group, and (g) other polymerizable unsaturated monomer, said cationically electrodepositable finely divided gelled polymer having a core-sheath structure consisting of a core of the polymerization product of the monomer component (A) and a sheath of the polymerization product of the monomer component (B).

Cationically electrodepositable finely divided gelled polymers having a

A process for coating a metallic substrate, characterized by applying on a metallic substrate a electrocoating paint, applying thereon a barrier coat comprising a film-forming thermoplastic resin other than a modified polyolefin resin and capable of forming a barrier coat film having a static glass transition temperature of 0.degree. to -75.degree. C., optionally applying on said barrier coat an intermediate coating paint and then applying thereon a top coating paint.

Process for coating metallic substrate

A process for coating a metallic substrate, characterized by applying on a metallic substrate an electrocoating paint, applying thereon a barrier coat comprising a film-forming thermoplastic resin other than a modified polyolefin resin and capable of forming a barrier coat film having a static glass transition temperature of 0.degree. to -75.degree. C., optionally applying on said barrier coat an intermediate coating paint and then applying thereon a top coating paint.

Coating method

A cationic electrodeposition coating composition for forming a multilayer film, said composition comprising

Cationic electrodeposition coating composition for multilayer film

An electrodeposition coating composition containing blocked isocyanate groups comprising at least one dialkyltin aromatic carboxylic acid salt represented by the following formula ##STR1## wherein R represents an alkyl group having 1 to 12 carbon atoms, and R.sup.1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.

Electrodeposition coating composition

A process for forming a composite coated film, which comprises coating a cationically electrodepositing paint composed mainly of a cationic resin having a functional group capable of reacting with isocyanate groups on the surface of a substrate, then coating an organic solvent-base paint containing a polyisocyanate compound and capable of forming a coated film having a static glass transition temperature of 0.degree. to -75.degree. C. on the surface of the electrodeposited paint film, and then coating a top coat paint.

Process for forming composite coated film

A method of electrodeposition coating, which comprises performing a first electrodeposition coating on an article as a cathode using (I) a cationic electrodeposition paint comprising (A) a resin and (B) at least one pigment, said pigment (B) containing at least 5% by weight of a pigment having an oil absorption of at least 100 and being incorporated so that the total oil absorption of the pigment (B) is in the range of 1,000 to 10,000 per 100 g of the resin (A), then while the resulting coated film is in the uncured state, performing a second electrodeposition coating on it using (II) an emulsion-type cationic electrodeposition coating paint comprising a resin (C) and a pigment (D) and having a minimum electrodeposition current density of not more than 0.7 mA/cm.sup.2 and a degree of emulsification of at least 80% by weight, said pigment (D) having a lower total oil absorption than the total oil absorption of the pigment (B) in the cationic electrodeposition paint (I), and thereafter curing the applied films under heat to form a composite cured coated film.

Electrodeposition coating method

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Hiratsuka, Japan

Masafumi Kume