Exxonmobil Chemical Patents Inc.

Exxonmobil Research and Engineering Company

Masaaki Sugita

Christopher Gordon Smalley

Mark Paul Hagemeister

Lu Han

Rathna P Davuluri

James Richardson Lattner

Robert G Tinger

Timothy Paul Bender

Brian A Cunningham

Bing Du

Jon Edmond Randolph Stanat

Alvin U Chen

Joseph S Famolaro

Timothy Forbes

Tarrant Jay Falcke

Nicholas E Smith

Kentaro Kobayashi

A method of predicting the tendency of a heavy oil feed to generate coke deposits in the FCC riser under a given set of operating parameters in the unit; thus, by utilizing operating parameters appropriate to the feed, the formation of coke deposits in the riser may be minimized. The margin between the theoretical dew point of the hydrocarbon feed established from unit operating parameters and the theoretical mix zone temperature in the feed injection zone of the unit is developed by applying a regression-derived linear model from multiple rigorous model runs. The mix zone of the unit is then operated at a temperature which reduces the level of riser coking predicted from this ascertainable margin or, at least, maintains it within levels which are predictable and acceptable.

Reduction of coking in FCCU feed zone

A method of improving the uniformity of the contacting of a heavy oil feed with FCC cracking catalyst in the feed zone of an FCC cracking riser in which the heavy oil feed is injected into the catalyst in the riser by means of feed injectors located around the riser, the method comprising minimizing the differences in the temperature profile in the oil/catalyst mixture across the feed zone by varying the oil feed rate to the injectors.

Method for optimizing catalyst/oil mixing in an FCC reactor feed zone

The invention relates to a process of alkylating aromatic hydrocarbons, and more particularly a process of making paraxylene by alkylation of benzene and/or toluene with methanol and/or dimethyl ether, and to an apparatus for carrying out said process, the improvement comprising staged injection of one of the reactants, with the stages separated by structured packing so as to minimize at least one of gas phase back-mixing, by-pass phenomena, and gas bubble size.

Fluid bed reactor with staged baffles

In a process for the production of para-xylene, an aromatic feedstock comprising toluene and/or benzene is reacted with methanol under alkylation conditions in a reactor in the presence of a fluidized bed of solid catalyst particles to produce a vapor phase effluent comprising para-xylene, water, unreacted toluene and/or benzene and solid catalyst fines. The vapor phase effluent is contacted with a liquid hydrocarbon quench stream under conditions to condense a minor portion of the vapor phase effluent and produce a condensate which contains at least some of the catalyst fines and which is substantially free of an aqueous phase. The condensate containing said catalyst fines is then separated from the remainder of the vapor phase effluent.

Production of para-xylene by the methylation of benzene and/or toluene

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McLean, VA, United States of America

Masaaki Sugita