Instituto Mexicano Del Petroleo

María Antonia Cortés Jacome

Marcelo Lozada Y Cassou

José Antonio Toledo Antonio

Esteban López Salinas

Carlos Angeles Chávez

Gerardo Ferrat Torres

Fernando Alvarez Ramírez

Yosadara Ruiz Morales

Rodolfo Juventino Mora Vallejo

Luis Francisco Flores Ortiz

José Escobar Aguilar

Víctor Pérez Moreno

Jose Escobar Aguilar

Maria De Lourdes Araceli Mosqueira Mondragon

Maria De Lourdes Mosqueira Mondragon

Miguel Pérez Luna

María De Lourdes Mosqueira Mondragón

The invention relates to a method of preparing a catalytic composition comprising at least one non-noble metal from group VIII and at least one metal from group VIB of the periodic table. The invention also relates to the catalytic composition thus produced, which has a high specific activity in reactions involving the hydroprocessing of light and intermediate fractions, preferably in reactions involving the hydrotreatment of hydrocarbon streams, including hydrodesulphurization (HDS), hydrodenitrogenation (HDN) and hydro-dearomatization (HDA).

Process for preparing a catalytic composition for the hydroconversion of petroleum fractions

The present invention relates to the novel catalytic composition having a high specific activity in reactions involving hydroprocessing of light and intermediate petroleum fractions, and preferably in hydrodesulphurization and hydrodenitrogenation reactions. The inventive catalyst contains at least one element of a non-noble metal from group VIII, at least one element from group VIB and, optionally, a group one element of the VA group, which are deposited on a novel catalytic support comprising of an inorganic metal oxide from group IVB, consisting of an (1D) one-dimensional nanostructured material having nanofibers and/or nanotube morphology with high specific surface area of between 10 and 500 m/g.

Catalytic composition for hydroprocessing of light and intermediate oil fractions

Nanomaterials of the JT phase of the titanium oxide TiO, where 0&#x2266;x&#x2266;1 having as a building block a crystalline structure with an orthorhombic symmetry and described by at least one of the space groups 59 Pmmn, 63 Amma, 71 Immm or 63 Bmmb. These nanomaterials are in the form of nanofibers, nanowires, nanorods, nanoscrolls and/or nanotubes. The nanomaterials are obtained from a hydrogen titanate and/or a mixed sodium and hydrogen titanate precursor compound that is isostructural to the JT crystalline structure. The titanates are the hydrogenated, the protonated, the hydrated and/or the alkalinized phases of the JT crystalline phase that are obtained from titanium compounds such as titanium oxide with an anatase crystalline structure, amorphous titanium oxide, and titanium oxide with a rutile crystalline structure, and/or directly from the rutile mineral and/or from ilmenite. The titanates are submitted to dynamic thermal treatment in an inert, oxidizing or reducing atmosphere to produce the JT phase of the TiO, where 0&#x2266;x&#x2266;1 with an orthorhombic structure.

Nanostructured titanium oxide material and its synthesis procedure

An adsorbent composition comprising a nanostructured titanium oxide material of the formula TiO, where 0&#x2266;&#xd7;&#x2266;1 with nanotubular and/or nanofibrilar morphology, high oxygen deficiency, having an orthorhombic JT crystalline phase described by at least one of the space groups 59 Pmmn, 63 Amma, 71Immm or 63 Bmmb, and comprising between 0 and 20 weight percent of a transition metal oxide is used for the selective adsorption of nitrogen compounds and/or sulfur compounds from light and intermediate petroleum fractions.

Selective adsorbent material and its use

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Col. San Bartolo Atepehuacan México, Mexico

María Antonia Cortés Jacome