3M Innovative Properties Company

Mary M Caruso Dailey

Hassan Sahouani

Michael A Kropp

Christopher Bland Walker, Jr

Alexander J Kugel

Corinne Elizabeth Lipscomb

Anthony F Schultz

Ying Lin

Babu Nana Gaddam

Larry R Krepski

Duane Douglas Fansler

Patricia M Savu

Ronald Wayne Ausen

Wayne Scott Mahoney

William H Moser

Jonathan E Janoski

Joseph D Rule

John Charles Clark

Jason D Clapper

William J Kopecky

Abdullahi A Mohamud

Kim Marie Vogel

Yongshang Lu

Shri Niwas

Eric Wayne Nelson

Clayton Allen George

Ann R Fornof

Steven J McMan

Jingjing Ma

Serkan Yurt

Michael W Kobe

John C Hulteen

Karissa L Eckert

Matthew J Kryger

Vivek Krishnan

Erik M Townsend

Ying Xia

Carla S Thomas

Sithya S Khieu

Sonja S Mackey

Cyrus A Anderson

Luke E Heinzen

Zachary J Thompson

Tien Yi T H Whiting

Lili Qie

Benjamin G Sonnek

Matthew R C Atkinson

Jing Fang

Jonathan W Kemling

Anne N De Rovere

Vasav Sahni

Ibrahim A El Hedok

Mark A Smith

Dmitri D Iarikov

Shannon R A Harnden

Krishnamurthy Sridhar

Steven J Mcman

Matthew RC Atkinson

Tien Yi TH Whiting

The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent derived from a barbiturate, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization.

Photolabile barbiturate compounds

Articles that include at least one application layer; at least one bead bond layer (); a layer of optical elements () that are partially embedded in the at least one bead bond layer (); and at least one reflective layer () that is located functionally between the layer of optical elements () and the bead bond layer (), wherein the at least one bead bond layer (), the at least one application layer, or both comprise a cured product of an adhesive compositions that include polymerized units of one or more (meth)acrylate ester monomers derived from an alcohol containing 1 to 14 carbon atoms; at least one of urethane acrylate polymer or at least one acrylic copolymer; and at least one initiator.

Articles having adhesive layers including urethane acrylate polymer or acrylate copolymer

Described herein is an article comprising (i) bead film comprising a binder resin layer and a plurality of microspheres partially embedded in the binder resin layer such that a portion of the microspheres outwardly protrude a first distance from the surface of the binder resin layer; (ii) a stabilizing layer disposed on the outwardly protruding microspheres opposite the binder resin layer, wherein the stabilizing layer intimately conforms to the protruding microspheres, and wherein the stabilizing layer has a Tg less than 100 C and a storage modulus at 150&#xb0; C. of at least 1.5 MPa; and (iii) a release agent, wherein (a) the binder resin layer comprises the release agent, (b) the stabilizing layer comprises the release agent, and/or (c) an intermediate layer comprises the release agent, wherein the intermediate layer is disposed between the monolayer of microspheres and the stabilizing layer, with the proviso that when the binder resin layer has a fluorine content along the polymeric backbone greater than 65 wt %, the stabilizing layer comprises a release agent selected from a silicone and a fluoropolymer. Also disclosed herein are methods of making thermoformable bead films.

Thermoformable beaded articles with removable stabilizing layer and methods thereof

Compositions are provided that include a matrix and a polymeric composite particles disposed in the matrix. The polymeric composite particles include a porous polymeric core and a fragrance positioned within the porous polymeric core. Polymeric composite particles are also provided including a porous polymeric core, a fragrance positioned within the porous polymeric core, and a coating layer around the porous polymeric core. Further, a method of determining a minimum temperature of a composition is provided including providing a composition including polymeric composite particles disposed in a matrix, heating the composition, releasing at least a portion of the fragrance as a vapor from the porous polymeric core of the polymeric composite particles at or above the minimum temperature, and detecting at least a portion of the fragrance vapor in a location outside of the matrix.

Polymeric composite particles

Articles are provided, including a substrate having a first major surface, the substrate including a nonwoven material, a woven material, or a foam. The article further includes microcapsules having an outer surface and a plasticizer encapsulated in the microcapsules, where the plurality of microcapsules is attached to the first major surface of the substrate with a polymeric material. A method of making an article is also provided, including providing a substrate having a first major surface and providing microcapsules having an outer surface and a plasticizer encapsulated in the microcapsules. The method further includes attaching the microcapsules to the first major surface of the substrate with a polymeric material, thereby forming a polymeric matrix attached to the first major surface of the substrate.

Articles including microcapsules for on-demand adhesion and methods of making same

Curable compositions are provided including a curable system that requires a thermally generated amine to cause curing of the system, and a self-assembled particle distributed in the curable system. The curable system contains at least one reactive moiety and the self-assembled particle comprises a reactive amine ionically bound to a chromonic network. A multilayer article is also provided, including a substrate, a chromonic amine layer disposed on the substrate, and a curable layer disposed on the chromonic amine layer. Methods of making a cured composition and of adhering two substrates together are further provided.

Curable compositions including a chromonic network, articles, and methods

A film is described comprises a (meth)acrylic polymer and a polyvinyl acetal (e.g. butyral) resin. The film has a tensile elastic modulus of at least 1 MPa at 25&#xb0; C. and 1 hertz and a glass transition temperature (i.e. Tg) less than 30 C. The film typically comprises photoinitiator as a result of the method by which the film was made. In one embodiment, the film is heat bondable and further comprising a backing.

Acrylic polyvinyl acetal films, composition, and heat bondable articles

There is provided an article having at least a first surface having: a binder resin layer comprising an actinic radiation reactive polyurethane dispersion, where the binder resin layer has a first major surface opposite a second major surface; and a plurality of microspheres partially embedded and adhered to the first major surface of the binder resin layer. There is also provided a thermoset article derived from such thermoformable articles.

Chemical resistant microsphere articles

Composite particles are provided that can be used to cure epoxy resins. More particularly, the composite particles have a porous polymeric core particle, a curing agent and/or a curing catalyst for an epoxy resin positioned within the porous polymeric core particle, and a fluoropolymer-containing coating layer around the porous polymeric core particle. Additionally, curable compositions are provided that are mixtures containing an epoxy resin and the composite particles. The epoxy resin typically does not react until the curable composition is heated causing the release of the curing agent and/or curing catalyst from the composite particle. Further, cured compositions formed from the curable composition are provided.

Composite particles for curing epoxy resin compositions and curable and cured epoxy resin compositions prepared using the particles

Polymeric composite particles are provided that can be used for the storage and delivery of various biologically active agent. The polymeric composite particles contain a porous polymeric core and a coating layer around the porous polymeric core. The porous polymeric composite particles typically further include a biologically active agent positioned within the porous polymeric core but not covalently bonded to the porous polymeric core. The biologically active agent can be released from the polymeric composite particle by diffusing out of the porous polymeric core through the coating layer.

Release of biologically active agents from polymeric composite particles

A quantum dot film article includes a first barrier layer; a second barrier layer; and a quantum dot layer between the first barrier layer and the second barrier layer. The quantum dot layer has quantum dots dispersed in a matrix including a cured adhesive composition, wherein the adhesive composition includes: an epoxide; an amino-functional compound of Formula I: wherein A is a monocyclic or a polycyclic alkylene group, or a monocyclic or a polycyclic heteroalkylene group, and m and n are integers each independently selected from 0 to 5; and a radiation curable methacrylate compound.

Quantum dot article with improved edge ingress

Described herein is a curable composition comprising: a crosslinkable epoxy resin; a curing agent; and a compound, wherein the compound comprises a pyrazine moiety but not a primary amine.

Epoxy resins comprising a pyrazine-containing compound

There is provided an adhesive composition comprising at least 50 wt % of an aqueous dispersion of an amorphous polyurethane having a Tg below 25&#xb0; C.; and a water dispersible cross-linker, where the adhesive composition has a peel retention of greater than or equal to 5% according to the Water/IPA Exposure Test.

Polyurethane laminating adhesive composition

The present disclosure provides an crosslinkable composition comprising a (meth)acrylate copolymer component having pendant photobase functional groups and a crosslinking agent that has amine-reactive functional groups. On exposure to light, the pendant photobase group photolyzes to provide a pendant amine group, that crosslinks the copolymer.

Crosslinkable composition comprising photobase generators

Growing community of inventors

Maplewood, MN, United States of America

Mary M Caruso Dailey