The Goodyear & Tire Rubber Company

Ashland Oil, Inc.

Marvin T Randleman

Michael E Kimball

Thomas G Rabito

Richard L Cline

Stephen M Oswalt

Improved two component adhesives allowing the components to be mixed at essentially a 1:1 ratio, giving excellent sag resistance, low viscosity, excellent handling ability and satisfactory gel time, said adhesives being composed of a prepolymer composition and a curative composition that can be mixed preferably at 1:2 to 2:1 ratio and a curative composition composed of a mixture of a reaction product of a multiple hydroxyl polyol of relatively low equivalent weight with a small amount of an organic polyiisocyanate and a polyamine.

Sag resistant at essentially 1:1 ratio two component adhesive

A curative for a two component isocyanate or polyurethane adhesive composed of a prepolymer component having about 3 to 15 percent free isocyanate, said curative comprising at least one polyol of about 400 to 6000 molecular weight and a polyamine with at least part of said polyol and said diamine being reacted with an organic polyisocyanate to form micelles that exhibit upon NMR examination strong urea peaks and weak urethane peaks. The curative is useful to make an adhesive that is particularly useful for adhering to metals and polyesters.

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New London, OH, United States of America

Marvin T Randleman