Exxon Research and Engineering Company

Martin O Gernand

Francis X Mayer

Robert L Seiver

Vincent Siminski

Neville L Cull

Dale D Maness

Robert H Waghorne

Bernie John Pafford

William W Lincoln

A hydrotreating process with a composition which exhibits high induced magnetism in a small applied magnetic field when formed into a magnetically stabilized fluidized bed and which comprises particles containing a nonferromagnetic component, or components, composited with a plurality of elongated ferromagnetic components, randomly oriented and present in each of said particles in relatively low concentration, based on the total volume of the particles; a process for formation of said compositions and a process wherein such composite particles are formed into a magnetically stabilized fluidized bed and contacted with a fluid, preferably gas.

Composition and hydrotreating process for the operation of a

A composition which exhibits high induced magnetism in a small applied magnetic field when formed into a magnetically stabilized fluidized bed and which comprises particles containing a nonferromagnetic component, or components, composited with a plurality of elongated ferromagnetic components, randomly oriented and present in each of said particles in relatively low concentration, based on the total volume of the particles; a process for formation of said compositions and a process wherein such composite particles are formed into a magnetically stabilized fluidized bed and contacted with a fluid, preferably gas.

Composition for use in a magnetically fluidized bed

An adsorption process for the recovery of hydrogen from a feed gas or vapor which contains hydrogen in admixture with one or more hydrocarbon components, alone or in admixture with non-hydrocarbon components. Particulate adsorbent solids are provided with a magnetizable component, or components, and circulated between an adsorption zone in which hydrogen is concentrated in the off gas by contact of the adsorbent solids with the feed, and hydrogen recovered, and a desorption zone in which the exhausted solids are regenerated. Within the adsorption zone the feed is countercurrently contacted with the solids at relatively low temperature to selectively adsorb hydrocarbons, and perhaps other non-hydrogen components. The solids are formed into a moving, fluidized bed, and magnetically stabilized to suppress gross solids circulation while hydrocarbons are adsorbed from the feed. Occluded hydrogen is subsequently displaced from the particulate adsorbent solids with hydrocarbons, and the hydrocarbon enriched particulate adsorbent solids are then transported to the desorption zone. In the desorption zone the solids are fluidized, and the temperature of the bed is elevated sufficiently to desorb at least a portion of the hydrocarbons. The residual hydrocarbons are subsequently displaced, suitably with steam or water by contact with steam in a magnetically stabilized bed of the solids. The wet solids are then dried by contact with hydrogen to displace the water, and cooled to complete the regeneration.

Magnetically stabilized bed, temperature, partial pressure swing,

Apparatus for effecting fluid-solids contacting wherein a bed of stationary or downward moving ferromagnetic particles are contacted with a fluid which passes through the bed in a cross-flow manner, said bed being structured or stabilized, by a magnetic field. Also disclosed are processes for using the magnetically stabilized cross-flow contactor including processes for removing particulates from gaseous streams, flue gas desulfurization processes and the like.

Magnetically stabilized fluid cross-flow contactor and process for using

Apparatus for effecting fluid-solids contacting wherein a bed stationary downward moving ferromagnetic particles are contacted within a contacting chamber with a fluid which passes through the bed in a cross-flow manner, said bed being structured or stabilized, by a magnetic field the improvement which comprises providing at least one support means positioned near or adjacent to the opening means, said support means extending into the contacting chamber. Also disclosed are processes for using the improved magnetically stabilized cross-flow contactor including processes for removing particulates from gaseous streams, flue gas desulfurization processes and the like.

Magnetically stabilized fluid cross-flow contactor having support means

A process for flue gas desulfurization or nitrogen oxide removal in a fluid using a magnetically stabilized fluid cross-flow contactor of the panel or radial reactor type wherein ferromagnetic bed solids are structured or stabilized by the action of a magnetic field.

Process for flue gas desulfurization or nitrogen oxide removal using a

A process for the removal of particulates entrained in a fluid using a magnetically stabilized fluid cross-flow contactor of the panel or radial reactor type wherein ferro-magnetic bed solids are structured or stabilized by the action of a magnetic field.

Process for the removal of particulates entrained in a fluid using a

Process for preparing shaped base materials for use in solid catalysts for commercial processes. The solid contact material is prepared by pre-soaking a porous solid particulate carrier material in an organic liquid, immersing the carrier without drying in a dilute acid solution for a given time interval, washing, drying and calcining the impregnated carrier. After calcination, the carrier is impregnated with an active material.

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Baton Rouge, LA, United States of America

Martin O Gernand