Dow Silicones Corporation

Dow Global Technolgoies LLC

Dow Corning Corporation

Cambridge Enterprise Limited

Dow France S.a.s.

Martin Grasmann

Bizhong Zhu

Brian Harkness

William Johnson

Bindu Krishnan

Jeanette Young

Eric Jude Joffre

William Hoy Heath

Elizabeth Santos

David M Hagan

Justin Scherzer

Stephen Michael Hlinka, Ii

Emmanuel Duquesne

William Alden Crossland

Terry Clapp

Jonathan Hannington

Anthony Bernard Davey

Huan Xu

Russell Keith King

Harry J Coles

Qiuyun Xu

Fumito Nishida

Omar Farooq

Vinita Pandit

Michael Salvatore Ferritto

Xavier Thomas

Terry Victor Clapp

Eric E Joffre

Mykhaylo Pivnenko

Oliver Hadeler

Bertrand Louis Julien Lenoble

David Pierre

Michael S Ferrito

Steven Robson

Mikhael Pivnenko

Russel Keith King

Jonathan Paul Hannington

Michael Salvatore Ferrito

Steve Hlinka Ii

Steve Hlinka

Stephen Michael Ii Hlinka

Harry James Coles

A composition comprises at least one silicone-polyether copolymer having the average formula X[ZY], where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyether moiety, each Z is an independently selected organosilicon moiety, subscript c is from 1 to 150, subscript g is >1, subscript j is independently 0 or 1, and subscript o is independently 0 or 1, with the provisos that 1≤j+o≤2 in each moiety indicated by subscript c and that there is at least one moiety indicated by subscript c in which subscript o is 1. A method of preparing the composition is also disclosed, along with a sealant formed therewith.

Silicone-polyether copolymer, sealants comprising same, and related methods

A silicone-polyacrylate copolymer has the formula X[ZY], where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyacrylate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0≤j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polyacrylate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polyacrylate copolymer and a condensation-reaction catalyst.

Silicone-poly acrylate copolymer, sealants comprising same, and related methods

A silicone-polyester copolymer has the formula X[ZY], where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyester moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0≤j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polyester copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polyester copolymer and a condensation-reaction catalyst.

Silicone-polyester copolymer, sealants comprising same, and related methods

A silicone-organic copolymer has the formula X[ZY], where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyacrylate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is &#x3e;1, 0&#x3c;j&#x3c;2, and 0&#x3c;o&#x3c;2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-organic copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-organic copolymer and a condensation-reaction catalyst.

Silicone-organic copolymer, sealants comprising same, and related methods

A silicone-polycarbonate copolymer has the formula X[ZY], where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polycarbonate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is &#x3e;1, 0&#x2264;j&#x3c;2, and 0&#x3c;o&#x3c;2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polycarbonate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polycarbonate copolymer and a condensation-reaction catalyst.

Silicone-polycarbonate copolymer, sealants comprising same, and related methods

A crosslinkable composition is useful for preparing a skin contact adhesive or a coating on a substrate. The crosslinkable composition includes (A) a polyurethane-polyorganosiloxane copolymer and (B) a curing catalyst. The skin contact adhesive prepared by crosslinking the crosslinkable composition is useful in applications such as adhesives for medical tapes, adhesives for wound dressings, adhesives for prosthetics, ostomy appliance adhesives, adhesives for medical monitoring appliances, adhesives for scar therapy treatments, adhesives for cosmetic patches, and transdermal drug delivery systems.

Skin contact adhesive and methods for its preparation and use

A polyurethane-polyorganosiloxane copolymer and methods for its preparation are disclosed. The copolymer has polyfunctional end groups, which render it crosslinkable by multiple crosslinking reactions.

Polyurethane-polyorganosiloxane copolymer and method for its preparation

A silicone urethane urea copolymer and methods for preparation and use of the copolymer are disclosed. The copolymer is crosslinkable. The copolymer is useful in various applications, including personal care compositions, such as hair care compositions and skin care compositions and in health care compositions such as skin contact adhesive compositions and transdermal drug delivery systems.

Silicone urethane urea copolymer and preparation and use thereof

A silicone-polyether copolymer has the formula X[ZY], where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyether moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is &#x3e;1, and each subscript j and o are independently &#x3e;0 and &#x3c;2, with the proviso that j+o=2 in each moiety indicated by subscript c. A method of preparing the silicone-polyether copolymer is also disclosed, and comprises reacting a polyether compound, a chain extending organosilicon compound, and an endcapping organosilicon compound in the presence of a hydrosilylation catalyst. A sealant is also disclosed, the sealant comprising the silicone-polyether copolymer and a condensation-reaction catalyst.

An isocyanate-functional silicone-polyether copolymer having a particular structure is disclosed. A method of preparing the isocyanate-functional silicone-polyether copolymer is also disclosed, the method comprising reacting a polyether compound and an organosilicon compound to give the isocyanate-functional silicone-polyether copolymer. A silicone-polyether-urethane copolymer formed therewith, as well as a method of preparing the silicone-polyether-urethane copolymer, are also disclosed. Sealants comprising the isocyanate-functional silicone-polyether copolymer and/or the silicone-polyether-urethane copolymer are further disclosed.

Isocyanate-functional silicone-polyether copolymer, silicone-polyether-urethane copolymer formed therewith, sealants comprising same, and related methods

A silicone-polyether copolymer has the formula X&#x2014;Y, where X is a silicone moiety having a particular structure and Y is a polyether moiety. An isocyanate-functional silicone-polyether copolymer formed therewith is also disclosed. Further, a silicone-polyether-urethane copolymer formed with the isocyanate-functional silicone-polyether copolymer is disclosed. Related methods of preparation as well as sealants and cured products thereof are further disclosed.

Silicone-polyether copolymer, isocyanate-functional silicone-polyether copolymer formed therewith, silicone-polyether-urethane copolymer, sealants comprising same, and related methods

A silicone-polyether copolymer has the formula X&#x2014;Y, where each X is an independently selected silicone moiety having a particular structure, Y is a linear or branched polyether moiety, and subscript g is on average more than 1. A method of preparing the silicone-polyether copolymer comprising reacting a polyether compound and an organosilicon compound in the presence of a hydrosilylation-reaction catalyst. A sealant is also disclosed, the sealant comprising the silicone-polyether copolymer and a condensation-reaction catalyst.

Silicone-polyether copolymer, method of preparing same, and sealant comprising same

The present, invention relates to liquid crystal compositions having a smectic A structure for use in an optical device in which the composition is sandwiched between a pair of electrodes (-). In essence the composition includes a siloxane oligomer (component (a)) which may be seen to construct a layered SmA system of particular spacing and 'strength'. Within this structure a low molar mass nematic mesogen (component (c)) is provided that may be considered to be that of a 'plasticiser' which moderates the layer &#x201c;strength&#x201d;, while simultaneously providing tuneability to the properties of the composition, e.g. its refractive index or dielectric anisotropy. The addition of a side chain liquid crystal polysiloxane (component (d)) allows such systems to be further moderated since they can be considered as binding together the la&#x3e;&#xbe;rs, both within a given layer and between layers. An ionic dopant (component (b)) is also included in the composition that migrates through the composition when low frequency electric fields are applied to the composition by the electrodes, thereby disrupting the order to the composition. Order in the composition can be restored by applying a higher frequency field that does not allow the dopant time to migrate significantly. Chromophores may also be included in the formulation.

Liquid crystal formulations and structures for smectic A optical devices

A liquid crystal formulation is described. The liquid crystal formulation comprises a first oligosiloxane-modified nano-phase segregating liquid crystalline material; and at least one additional material selected from a second oligosiloxane-modified nano-phase segregating liquid crystalline material, non-liquid crystalline oligosiloxane-modified materials, organic liquid crystalline materials, or non-liquid crystalline materials, wherein the liquid crystal formulation has an I&#x2192;SmA*&#x2192;SmC* phase transition, with a SmC* temperature range from about 15&#xb0; C. to about 35&#xb0; C., a tilt angle of about 22.5&#xb0;&#xb1;6&#xb0; or about 45&#xb0;&#xb1;6&#xb0;, a spontaneous polarization of less than about 50 nC/cm2., and a rotational viscosity of less than about 600 cP. Devices containing liquid crystal formulations are also described. The device has a stable bookshelf geometry, bistable switching, and isothermal electric field alignment, a response time of less than 500 &#x3bc;s when switched between two stable states, and an electric drive field of less than about 30 V/&#x3bc;m.

Oligosiloxane modified liquid crystal formulations and devices using same

A liquid crystal formulation is described. The liquid crystal formulation comprises a first oligosiloxane-modified nano-phase segregating liquid crystalline material; and at least one additional material selected from a second oligosiloxane-modified nano-phase segregating liquid crystalline material, non-liquid crystalline oligosiloxane-modified materials, organic liquid crystalline materials, or organic non-liquid crystalline materials, wherein the liquid crystal formulation is nano-phase segregated in the SmC* phase, has an I&#x2192;SmC* phase transition, with a SmC* temperature range from about 15&#xb0; C. to about 35&#xb0; C., has a tilt angle of about 22.5&#xb0;&#xb1;6&#xb0; or about 45&#xb0;&#xb1;6&#xb0;, and has a spontaneous polarization of less than about 50 nC/cm2, and a rotational viscosity of less than about 600 cP. Devices containing liquid crystal formulations are also described. The device has a stable bookshelf geometry, bistable switching, and isothermal electric field alignment, a response time of less than 500 &#x3bc;s when switched between two stable states, and an electric drive field of less than about 30 V/&#x3bc;m.

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Midland, MI, United States of America

Martin Grasmann