Halliburton Company

Cesi Chemical, Inc.

Plainsman Technology, Inc.

Marlin D Holtmyer

Charles V Hunt

Phillip C Harris

Lakia M Champagne

Ronald E Himes

Weldon M Harms

Andrei Zelenev

David J Hanlon

John M Tinsley

Charles J Githens

David Philpot

Mary A Laramay

Todd Sanner

Earl Parnell

Mike Conway

Gydeon Gilzow

Thomas Sifferman

Richard W Pauls

Jeffrey A Dahl

Lawrence E Harris

Alireza B Rahimi

L W Bishop

Murray G Clark

A method of preparing and using a drag-reducing composition in a well treatment operation includes the step of preparing the drag-reducing composition by mixing a polymer emulsion that includes a first surfactant and a first solvent, with a second surfactant and a second solvent. The method continues with the step of combining the drag-reducing composition with an aqueous treatment fluid. The method further includes the step of injecting the drag-reducing composition and aqueous treatment fluid into a subterranean formation, a pipeline or a gathering line.

Drag-reducing copolymer compositions

A drag-reducing additive includes 40-85% by weight of a polymer emulsion that includes a polymer, a first surfactant, and a first solvent; 10-35% by weight of a second surfactant with an HLB greater than 8; and 5-30% by weight of a second solvent. In a preferred embodiment, the second solvent includes a terpene. In another preferred embodiment, the polymer is a copolymer that includes acrylamide and acrylic acid.

There is provided an additive for and a method of using the additive to treat a clay-containing earthen formation, such as a subterranean formation, to substantially reduce formation damage caused by contact of the formation with an aqueous liquid foreign to the formation. The additive, which is employed in a water solution, is comprised of a chloride-free, quaternary ammonium compound which can be used without adverse affect upon animal, soil and water resources due to the chloride-free and substantial organic nature thereof. It thus biodegrades to environmentally acceptable end products.

Method for clay stabilization

The present invention provides a method of gravel packing a subterranean formation using a gel of a graft copolymer of a hydroxyalkyl cellulose prepared by a redox reaction with vinyl phosphonic acid. The gel is formed by hydrating the graft copolymer in an aqueous liquid. The gel in crosslinked by the addition of a crosslink initiator comprising a Lewis base or Bronsted-Lowry base, which is substantially free of polyvalent metal ions, to the gel in an amount sufficient to effect crosslinking of the graft copolymer. The viscosity of the crosslinked gel is reduced by contacting the gel with an acidic fluid whereby the pH of the gel is caused to decrease. The reduction in gel viscosity facilitates formation of the gravel pack.

Method of gravel packing a well

The present invention provides a method of cleaning a pipeline using a gel pig of a graft copolymer of a hydroxyalkyl cellulose prepared by a redox reaction with vinyl phosphonic acid. The gel pig is formed by hydrating the graft copolymer in an aqueous liquid. The gel pig is crosslinked by the addition of a Lewis base or Bronsted-Lowry base, to the gel in an amount sufficient to initiate crosslinking of the graft copolymer. Contaminants entrained in the crosslinked gel pig during the cleaning process may be separated by the addition of a pH reducing agent to the pig whereby the viscosity of the gel is caused to decrease. The gel may be used for further cleaning after contaminant separation by addition of an additional quantity of the Lewis base or Bronsted-Lowry base.

Pipeline cleaning process

The present invention provides a method of treating of subterranean formation using a gel of a graft copolymer of a hydroxyalkyl cellulose, guar or hydroxypropyl guar prepared by a redox reaction with vinyl phosphonic acid. The gel is formed by hydrating the graft copolymer in an aqueous liquid containing at least a trace amount of at least one divalent cation. The gel is crosslinked by the addition of a Lewis base or Bronsted-Lowry base, which is substantially free of polyvalent metal ions, to the gel in an amount sufficient to effect crosslinking of the graft copolymer.

Method of crosslinking cellulose and guar derivatives for treating

Novel treating fluid compositions containing crosslinkable non-ionic cellulose derivatives and methods of use in petroleum recovery operations are disclosed. The treating fluid polymers are prepared by reacting vinyl monomers having a crosslinkable substituent with a cellulose derivative using a redox system comprising the reaction product of hydrogen peroxide with ferrous salt. The polymers readily crosslink with polyvalent metal ions, such as zirconium and titanium, to form temperature-stable gels useful in petroleum recovery operations.

Crosslinkable cellulose derivatives

Novel treating fluid compositions containing crosslinkable non-ionic cellulose derivatives and methods of use in petroleum recovery operations are disclosed. The treating fluid polymers are prepared by reacting vinyl monomers having a crosslinkable substituent with a cellulose derivative using a redox system comprising the reaction product of hydrogen peroxide with ferrous salt. The polymers readily crosslink with polyvalent metal ions, such as zirconium and titianium, to form temperature-stable gels useful in petroleum recovery operations.

The present invention relates to novel crosslinkable interpolymers and methods of use in treating subterranean formations. The novel interpolymers comprise a water soluble monomer, a hydrophobe monomer, and vicinal diol monomer polymerized to form high molecular weight polymers which viscosify aqueous liquids. The solution viscosity may be enhanced by the addition of a surfactant having an HLB value of about 10 or less. The interpolymers are readily crosslinkable with polyvalent metal ions, such as titanium and zirconium to form thermally stable viscoelastic gels. The gels provide viscosity and solids transport characteristics that are useful in stimulating, gravel packing and polymer flooding operations.

Crosslinkable interpolymers

Novel treating fluid compositions containing crosslinkable non-ionic cellulose derivatives and methods of use in petroleum recovery operations are disclosed. The treating fluid polymers are prepared by reacting vinyl or allyl monomers having a crosslinkable substitutent with a cellulose derivative using a ceric ion redox system. Treatment of a non-ionic cellulose derivative with a ceric ion redox system also yields a crosslinkable polymer. The polymers readily crosslink with polyvalent metal ions, such as zirconium and titanium, to form temperature-stable gels useful in petroleum recovery operations.

A method of treating a subterranean formation is provided using a treating fluid comprising from about 0% up to about 80% by volume liquid carbon dioxide. The remainder of the treating fluid comprises a viscous substantially anhydrous liquid which may be crosslinked by a metal ion source. The treating fluid is formed by the addition of polymers or copolymers of dimethylacrylamide to the substantially anhydrous fluid.

Non-aqueous viscosified carbon dioxide and method of use

A method and composition for stimulating high temperature subterranean formations. The composition comprises a novel crosslinkable polymer containing anionic and cationic functional groups (a polyampholyte). The polyampholyte comprises a mixture of at least one from each of the following groups:

Polyampholytes-high temperature polymers and method of use

The present invention relates to a method and composition for viscosifying hydrocarbon liquids utilizing a viscosifying agent. The viscosifying agent comprises: (i) a copolymer of N,N-dimethylacrylamide and dimethylaminopropyl methacrylamide, (ii) a monocarboxylic acid and (iii) a selected amine having an ethanolamine structure admixed in a hydrocarbon liquid. The viscosifying agent constituents are admixed with the liquid hydrocarbon in an amount sufficient to effect viscosification of the hydrocarbon.

Method and composition for viscosifying hydrocarbons

The present invention provides vicinal diol containing monomers and polymers and methods of preparing and using such monomers and polymers. When crosslinked in aqueous fluids, the polymers form high viscosity gels which are stable at high temperatures.

Vicinal diol containing monomers and polymers and methods of treating a

The present invention provides a water soluble vinyl monomer containing a vicinal diol group of the general formula: ##STR1## wherein R.sub.1 is hydrogen or methyl; R.sub.3 and R.sub.4 are independently methyl or ethyl; Y is oxygen or NH; X.sup.- is a halogen, sulfate, CH.sub.3 SO.sub.4.sup.- or C.sub.2 H.sub.3 SO.sub.4.sup.- or CH.sub.3 COO.sup.- and n is 2 or 3. Polymers containing the monomer when crosslinked in aqueous fluids form high viscosity gels which are stable at high temperatures and can be used in carrying out completion, stimulation, enhanced production and other treatments in subterranean formations.

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Duncan, OK, United States of America

Marlin D Holtmyer