Ppg Industries Ohio, Inc.

Mark W McMillen

Gregory J McCollum

Edward Francis Rakiewicz

Richard F Karabin

Nathan J Silvernail

Michelle S Miles

Shan Cheng

Peter Lawrence Votruba-Drzal

Justin Jonathan Martin

Neil D McMurdie

Kevin Thomas Sylvester

Randall J Brent

John F McIntyre

Michel Sudour

Richard M Vargas

Terri Lynn Ziegler

Brian C Okerberg

Matthew E Wehrle

Nicephoros A Fotinos

David A Raney

Steven J Lemon

Mark W Simpson

James A DeChant

James D Chant

Neil D Mcmurdie

The present invention is directed towards an aqueous alkaline cleaner composition comprising: an iron cation, a molybdenum cation, a cobalt cation, or combinations thereof; and an alkaline component; wherein the pH of the aqueous alkaline composition is at least 10, and the aqueous alkaline composition includes no more than 50 ppm of phosphate. Also disclosed are treatment systems comprising an aqueous alkaline composition for treating at least a portion of a substrate, and a pretreatment composition for treating at least a portion of a substrate. Also disclosed are substrates treated according to the disclosed treatment systems.

Alkaline molybdenum cation and phosphonate-containing cleaning composition

Disclosed are methods for treating metal substrates that include contacting the substrate with a pretreatment composition comprising a rare earth metal and a zirconyl compound. The present invention also relates to coated substrates produced thereby and further to substrates additionally coated with an electrophoretically applied coating composition.

Zirconium pretreatment compositions containing a rare earth metal, associated methods for treating metal substrates, and related coated metal substrates

Disclosed are pretreatment compositions and associated methods for treating metal substrates with pretreatment compositions, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The pretreatment composition includes: (a) a group IIIB and/or IVB metal; (b) free fluorine; (c) a source of aluminum ions; and (d) water. The methods include contacting the metal substrates with the pretreatment composition.

Pretreatment compositions and methods for coating a metal substrate

Disclosed are methods for treating metal substrates, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The methods include depositing an electropositive metal onto at least a portion of the substrate, and then contacting the substrate with a pretreatment composition that is substantially free of crystalline phosphates and chromates. The present invention also relates to coated substrates produced thereby.

Methods for coating a metal substrate and related coated metal substrates

Disclosed are methods for treating metal substrates, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The methods include contacting the metal substrates with a conditioning composition including a free fluoride source and then depositing a pretreatment composition including a Group IIIB and/or IVB metal on a portion of the substrate contacted with the conditioning composition. Also disclosed are electrophoretically coated substrates treated by the methods.

Method for preparing and treating a steel substrate

An activating rinse for treating a substrate is disclosed. The activating rinse comprises a first component comprising a dispersion of divalent or trivalent metal phosphate particles having an average particle size that is not greater than 10 &#x3bc;m, and a second component comprising first and second copolymers. The first copolymer is formed by the polymerization of ethylene oxide, propylene oxide, or combinations thereof, wherein one end of the first copolymer is terminated by an amine group, a hydroxyl group, or an alkyl group. The second copolymer is formed by the polymerization of styrene and a second monomer containing at least one carboxylate group, anhydride group, or combinations thereof. The second monomer is present in an amount of less than 50 percent by weight of the total weight of the second component. Also disclosed are methods for treating a substrate with the activating rinse and substrates treated with the activating rinse.

Activating rinse and method for treating a substrate

Disclosed are replenisher compositions and methods of replenishing pretreatment compositions. The methods include adding a replenisher composition to a pretreatment composition wherein the replenisher composition includes: (a) a dissolved complex metal fluoride ion wherein the metal ion comprises a Group IIIA metal, Group IVA metal, Group IVB metal, or combinations thereof; (b) a component comprising an oxide, hydroxide, or carbonate of Group IIIA, Group IVA, Group IVB metals, or combinations thereof; and optionally (c) a dissolved metal ion comprising a Group IB metal, Group IIB metal, Group VIIB metal, Group VIII metal, Lanthanide Series metal, or combinations thereof.

Replenishing compositions and methods of replenishing pretreatment compositions

Disclosed are methods for treating metal substrates, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The methods include contacting the substrate with a pretreatment composition that includes: (a) a group IIIB and/or IVB metal; (b) free fluorine; (c) a metal fluoride salt formed from a metal which forms a fluoride salt having a pKof at least 11; and (d) water.

A method includes (a) contacting at least a portion of a substrate material with a solution comprising a source of copper, wherein the solution is essentially free of a source of a group IIIB metal and a source of a group IVB metal; and (b) after step (a), contacting at least a portion of the substrate with an electrodepositable coating composition comprising (i) a film-forming resin and (ii) a source of yttrium.

Copper prerinse for electrodepositable coating composition comprising yttrium

Disclosed are methods for passivating metal substrates, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The methods comprise the steps of depositing an electropositive metal onto at least a portion of the substrate, followed immediately by electrophoretically depositing on the substrate a curable, electrodepositable coating composition. The present invention also relates to coated substrates produced by the above methods.

Methods for passivating a metal substrate and related coated metal substrates

Disclosed are methods for coating a metal substrate with a yttrium-containing coating, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. Also disclosed are coated substrates produced thereby.

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Cabot, PA, United States of America

Mark W McMillen