Johnson Matthey Inc.

Mark McKenna

Peter Edward James Abbott

Peter William Farnell

Alejandro Martin Antonini

A process for the conversion of a hydrocarbon to COand electrical power is described which includes subjecting a gas mixture of a hydrocarbon feed stream and steam to an integrated reforming process including stages of steam reforming in a gas-heated reformer and secondary reforming to generate a reformed gas mixture, increasing the hydrogen content of the reformed gas mixture by subjecting it to one or more water-gas-shift stages, cooling the resulting hydrogen-enriched reformed gas and separating condensed water therefrom, passing the resulting de-watered hydrogen-enriched reformed gas to one or more stages of carbon dioxide separation to recover carbon dioxide, combusting the remaining hydrogen-containing fuel stream with an oxygen containing gas in a gas turbine to generate electrical power and passing the exhaust gas mixture from the gas turbine to a heat recovery steam generation system that feeds one or more steam turbines to generate additional electrical power.

Conversion of hydrocarbons to carbon dioxide and electrical power

A process for reducing COemissions from combined cycle power generation processes utilizing a gaseous hydrocarbon feed, which includes splitting the hydrocarbon feed into two portions; a first portion &#x2266;45% by volume of the feed and a second portion &#x2267;55% by volume of the feed, feeding the first portion to an autothermal reforming process to generate a hydrogen-containing gas and a carbon dioxide stream, combining the hydrogen-containing stream with the second portion, combusting the resulting hydrogen-containing fuel stream with oxygen containing gas in a gas turbine to generate electrical power and passing the exhaust gas mixture from the gas turbine to a heat recovery steam generation system that feeds one or more steam turbines to generate additional electrical power. The captured carbon dioxide stream may be fed to storage or enhanced oil recovery processes. The process may be retrofitted into existing combined cycle processes.

A process is described for the conversion of synthesis gas into hydrocarbons including the steps of;

Two stage process for the conversion of synthesis gas using a cobalt catalyst in the first stage and a supported ruthenium catalyst in the second stage

A catalyst unit suitable for loading into a tube in a reactor includes a plurality of catalyst particles incorporated within a removable solid matrix, said unit in the form of an elongate body in which the particles are packed together such that the volume shrinkage upon removal of the removable matrix is &#x2266;20%. The catalyst particles preferably comprise one or more metals selected from the group consisting of Fe and Co in oxidic or reduced form. The units are particularly suitable for loading catalyst into tubes in a Fischer-Tropsch reactor.

Shaped catalyst units

A process for re-processing of a Fischer-Tropsch catalyst is described comprising the steps of; (i) de-waxing the Fischer-Tropsch catalyst, (ii) subjecting the de-waxed catalyst to hydrometallurgical leaching or extraction to separate catalyst metal or metals from catalyst support material, and (iii) recovering the separated catalyst metal or metals, wherein the de-waxing step is performed using a pressurised near-critical or supercritical fluid under conditions that minimise catalyst metal spinel formation.

Catalyst reprocessing

A process for the production of hydrocarbons is described including; a) subjecting a mixture of a hydrocarbon feedstock and steam to catalytic steam reforming to form a partially reformed gas, b) subjecting the partially reformed gas to partial combustion with an oxygen-containing gas and bringing the resultant partially combusted gas towards equilibrium over a steam reforming catalyst to form a reformed gas mixture, c) cooling the reformed gas mixture to below the dew point of the steam therein to condense water and separating condensed water to give a de-watered synthesis gas, d) synthesising hydrocarbons from side de-watered synthesis gas by the Fischer-Tropsch reaction and e) separating the hydrocarbons from co-produced water, characterised in that at least part of said co-produced water is fed to a saturator wherein it is contacted with hydrocarbon feedstock to provide at least part of the mixture of hydrocarbon feedstock and steam subjected to steam reforming.

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Stockton on Tees, United Kingdom

Mark McKenna