Honeywell International Inc.

University of Notre Dame Du Lac

Mark L La Forest

Slawomir T Fryska

Allen Simpson

Neil Murdie

Alexander Mukasyan

Roger L Klinedinst

David M Wright

Barry P Soos

Mark Criss James

Christopher S Wahlers

Thomas Heinrich Siegmund

Raymond J Cipra

David Flask

Peter Franz Braunisch

Alan E Fatz

Charles D D'Amico

Nabil Abu Gharbieh

Russell W Johnson

Charles A Parker

Frank Dillon

Akshay Waghray

Douglas J Steinke

Jeffrey Troester

Ryan Bourlier

David R Cole

Richard C Donaldson

Mark E Behnke

Roger W Holloway

Gregory Vanderheyden

Peter F Braunisch

Tobey Cordell

Russel W Johnson

Allen H Simpson

A carbon-carbon composite preform including a plurality of layers including carbon fibers or carbon-precursor fibers, the layers include a first exterior layer defining a first major surface, a second exterior layer defining a second major surface, and at least one interior layer disposed between the first exterior layer and the second exterior layer, the at least one interior layer having a peripheral region that forms a portion of an outer surface of the preform. The preform includes needled fibers, where at least some needled fibers extend through two or more layers. The preform has an exterior region and a core region, where the exterior region includes at least the peripheral region of at least one interior layer. The needled fibers define a first needled fiber number density (NFND) in the exterior region and a second greater NFND in at least a portion of the core region.

Differential needling of a carbon fiber preform

A method of forming a densified preform or composite part is disclosed that includes partially densifying a porous preform, forming channels in the partially densified preform that open to an exterior surface of the partially densified preform, infiltrating a densifying agent, such as pitch, into at least some of the channels of the partially densified preform, at least partially stabilizing the densifying agent, including heating at a first temperature, such that cracks form within the densifying agent, and exposing the preform to an oxidizing agent, and heating the at least partially stabilized preform at a second temperature to carbonize at least the stabilized densifying agent. A partially densified preform including a densifying agent disposed at least in such channels also is disclosed.

Facilitating pitch stabilization in densified carbon fiber preforms

A carbon fiber preform that includes a plurality of fibrous layers stacked together and a plurality of sacrificial fibers that bind the plurality of fibrous layers together, where at least one fibrous layer of the plurality of fibrous layers includes a plurality of carbon fibers or carbon fiber precursor fibers.

Sacrificial fibers to create channels in a composite material

In some examples, a method including depositing a resin and a plurality of carbon fibers via a print head of a three-dimensional printing system to form a carbon fiber preform including a plurality of individual carbon fiber layers, wherein each individual layer of the plurality of individual carbon fiber layers includes the resin and carbon fibers, and wherein the carbon fiber preform exhibits at least one of a non-uniform composition of the resin within the preform, different types of the carbon fibers within the preform, or non-uniform fiber orientation within the preform.

Carbon fiber preforms

A brake disc rotor or stator is manufactured with slots in the interior face of the disc. A paste comprised of a fine powder of a carbide-forming metal along with fine carbon powder, suspended in an organic binder, is applied to the force-bearing areas in the rotor slot faces or the stator slot faces. The disc is then placed into a furnace in a nitrogen atmosphere and heated to the ignition temperature. When the furnace reaches the ignition temperature, a combustion reaction begins that creates a molten liquid ceramic material on the slot face. Upon cooling, the resulting brake disc has a tough, hard, abrasion-resistant ceramic surface on the portion of the brake disc slot that bears pressure.

Reactive sintering to eliminate metal inserts in carbon-carbon brake discs

In some examples, a method includes depositing a mixture including a resin and an additive powder via a print head of a three-dimensional printing system to form a carbon fiber preform including a plurality of individual carbon fiber layers, wherein each individual layer of the plurality of individual carbon fiber layers includes a plurality of carbon fibers and the mixture of the resin and the additive powder.

Method of making carbon fiber preforms

In some examples, the disclosure describes a method including depositing a first layer including a resin and at least one of a carbon fiber or a carbon fiber precursor material on a work surface of a three-dimensional printing system, carbonizing at least the resin of the first layer using a carbonizer attached to the three-dimensional printer to form a first layer of carbon-carbon composite including carbon fibers and carbonized matrix material, depositing an additional layer including a resin and at least one of a carbon fiber or a carbon fiber precursor material of material on the first layer of carbon-carbon composite, and carbonizing at least the resin of the additional layer using the carbonizer to form an additional layer of carbon-carbon composite on the first layer of carbon-carbon composite.

In situ carbonization of a resin to form a carbon-carbon composite

A technique of forming a carbon-carbon composite that includes infiltrating a preform comprising carbon fibers or carbon-precursor fibers with a pitch and pyrolyzing the pitch using a controlled pressure and temperature ramp rate to control a growth of optical textures as the pitch is pyrolyzed to a coke matrix. Pyrolyzing the pitch may include initiating pyrolysis of at least some of the pitch at a first pressure less than about 2000 psi and a first temperature ramp rate between about 5&#xb0; C./hr and about 50&#xb0; C./hr to a first target temperature, and pyrolyzing at least some of the pitch at a second pressure greater than 2000 psi and a second temperature ramp rate between about 5&#xb0; C./hr and about 50&#xb0; C./hr to a second target temperature, where the second target temperature is greater than the first target temperature.

High density carbon-carbon friction materials

A technique of heating a mixture of fibers that includes sacrificial fibers and carbon fiber precursor fibers to a temperature between about 170&#xb0; C. and about 400&#xb0; C., such that the sacrificial fibers are substantially removed and a plurality of channels remain in a preform precursor, and carbonizing the carbon fiber precursor fibers to form a porous carbon fiber preform. Also disclosed is a technique of heating a mixture of fibers that includes sacrificial fibers and carbon fibers to a temperature between about 170&#xb0; C. and about 400&#xb0; C., such that the sacrificial fibers are substantially removed and a plurality of channels remain, and infiltrating a densifying agent into at least the plurality of channels. Also disclosed is an article including a mixture of fibers that includes sacrificial fibers and carbon fiber precursor fibers or carbon fibers.

In the manufacture of carbon-carbon composite brake discs, migration of anti-oxidant substances into the friction surfaces is prevented by limiting or eliminating surface porosity in the carbon-carbon composite brake materials. The method includes infusing a suitable resin into pores in surface layers of the carbon-carbon composite disc and then charring the resin-infused disc to convert the resin in the pores to pyrolytic carbon. The resin may be infused into the carbon disc by submerging the disc in a molten resin. Prior to submerging the disc in the molten resin, the disc may subjected to a vacuum to remove air from the pores. While the disc is submerged in the molten resin, the pressure in the pressurizable vessel may increased to force the molten resin into the open porosity of the disc.

Preventing carbon AO migration by limiting surface porosity

A technique of forming a carbon-carbon composite material includes infusing a liquid carbonizable precursor into a porous preform, and the infused precursor is subsequently pyrolyzed to convert the precursor to isotropic carbon. The preform then can be densified with a densifying agent, followed by infusion of the liquid carbonizable precursor into the densified preform. In some examples, after pyrolyzing the liquid carbonizable precursor, isotropic carbon extends substantially throughout a volume of the carbon-carbon composite material.

Carbon-carbon composites including isotropic carbon encapsulating layer and methods of forming the same

Method of making a carbon-carbon composite brake disc or pad by: needling a plurality of layers of fibrous fabric segments to one another to form a brake disc or pad preform; carbonizing the fibrous preform to provide a carbon fiber brake disc or pad preform having a fiber volume fraction in the range 17% to 30% in the brake disc or pad preform; densifying the resulting carbonized needled fibrous fabric preform with pitch (isotropic or anisotropic) or with pitch and CVD/CVI; carbonizing the resulting pitch-infiltrated carbon fiber disk to carbonize the pitch therein; heat-treating the resulting pitch-densified carbon brake disc or pad; and subjecting the carbon brake disc or pad to a final cycle of CVD/CVI processing in order to produce a carbon-carbon composite brake disc or pad having a density of at least 1.70 g/cc and having a uniform through-thickness density. Benefits over conventional processing are obtained by increasing the needling rate used to manufacture the preform and reducing the amount of fiber used in the preform. In addition, the use of pitch in combination with CVI/CVD to densify the carbon fiber preform enables higher final densities to be achieved. This carbon-carbon composite manufacturing method also benefits from lowered manufacturing cycle time.

Low cost, high density aircraft friction materials utilizing low fiber volume nonwoven preforms with pitch densification

In some examples, a technique for forming a partially densified preform including ceramic particles may include mixing a densifying agent with metal oxide particles or metal oxide precursor to form a blended densifying agent, infiltrating the blended densifying agent in to a porous preform, pyrolyzing the infiltrated preform to convert the densifying agent to carbon and form a partially densified preform, and heat treating the partially densified preform to react at least some of the carbon with the metal oxide particles to form ceramic particles. Composite materials formed from porous preforms in which a blended densifying agent is disposed in pores of the preform are also described.

Composite materials including ceramic particles and methods of forming the same

A pitch densification apparatus may be used to form a carbon-carbon composite material. The apparatus may be used to compress a carbon fiber material, and, thereafter, pitch densify the carbon fiber material. The compression and pitch densification of the carbon fiber material may be carried out within the same mold cavity of the pitch densification apparatus. In one example, an apparatus may comprise a mold defining a mold cavity that is configured to receive a material to be densified. The mold cavity is configured to be adjusted from a first volume to a second volume less than the first volume to compress the material in the mold cavity. The example apparatus may further comprise a gas source configured to apply a gas pressure in the mold cavity to force pitch into the material in the mold cavity to densify the material, and a vacuum source configured to create a vacuum pressure in the mold cavity at least prior to the application of the gas pressure.

Apparatus for carbon fiber processing and pitch densification

A liquid carbonizable precursor is infused into a porous preform, and the infused precursor is subsequently pyrolyzed to convert the precursor to a carbon. The carbon enhances rigidity of the preform. In some examples, the preform can be densified to define a carbon-carbon composite brake disc for use in the aerospace industry.

Growing community of inventors

Granger, IN, United States of America

Mark L La Forest