Greatbatch Ltd.

Wilson Greatbatch Technologies, Inc.

Mark J Roy

Gary Freitag

Robert S Rubino

Xiangyang Steve Dai

Joseph M Lehnes

Esther S Takeuchi

Hong Gan

William C Thiebolt

Marcus J Palazzo

Ho-Chul Yun

Dominick J Frustaci

Paul T Hallifax

Sally Ann Smesko

Bruce Platt

Eric Ziarniak

William M Paulot

Kenneth L Grubb

David Dianetti

Michael Guidi

Lou Serpe

Susan L Clare

A current collector for an electrochemical cell is described. Unlike conventional current collector designs, the current collector does not have an unperforated perimeter frame completely bordering or surrounding a perforated interior region. Instead, only that portion of the current collector adjacent to the connector tab is unperforated. Otherwise, perforations extend directly to the perimeter edge.

Foil-type current collector having an unperforated strip at the connector tab

A lithium electrochemical cell with increased energy density is described. The electrochemical cell comprises an improved sandwich cathode design with a second cathode active material of a relatively high energy density but of a relatively low rate capability sandwiched between two current collectors and with a first cathode active material having a relatively low energy density but of a relatively high rate capability in contact with the opposite sides of the two current collectors. In addition, a cathode fabrication process is described that increases manufacturing efficiency. The cathode fabrication process comprises a process in which first and second cathode active materials are directly applied to opposite surfaces of a perforated current collector and laminated together. The present cathode design is useful for powering an implantable medical device requiring a high rate discharge application.

Sandwich cathode lithium battery with high energy density

An electrochemical cell, preferably a secondary, rechargeable cell, including a casing comprised of a main body portion having opposed lower and upper open ends closed by respective lower and upper lids is described. The main body portion is composed of titanium Grades 5 or 23 having a relatively high electrical resistivity material while the lower and upper lids are composed of titanium Grades 1 or 2. The lids are preferably joined to the main body portion using laser welding. The combination of these differing titanium alloys provides a cell casing that effectively retards eddy current induced heating during cell recharging.

Method of providing an electrochemical cell casing having an open-ended main body portion of grade 5 or 23 titanium closed by upper and lower lids of grade 1 or 2 titanium

Disclosed herein are electrochemical cells that generally relate to the conversion of chemical energy to electrical energy. More particularly, the present disclosure is directed to primary lithium electrochemical cells possessing insulator pocket structures, which substantially envelope cathode components to prevent lithium cluster formation therein.

Cathode insulator design

Electrochemical cell casing having an open-ended main body portion of grade 5 or 23 titanium closed by upper and lower lids of grade 1 or 2 titanium

A process for creating a laser braze weld joint between a current collector and a terminal pin in the construction of electrochemical cells is described. The laser braze welding process utilizes a laser weld instrument to create a braze-like joint between two work pieces. The weld joint is created by controlling the amount of laser heat and energy imparted to the work pieces through proper control and positioning of the laser beam with respect to the work pieces. Preferably, the method is used to bond the terminal pin to the cathode current collector. This method of attachment is suitable for either primary or secondary cells, particularly those powering implantable biomedical devices.

Connector from the tab of an electrode current collector to the terminal pin of a feedthrough in an electrochemical cell

The present invention is directed to an electrochemical cell having plate electrodes housed inside a mating 'clamshell' casing. When mated together, the casing components are form-fitting with respect to the internal battery structure so as to reduce the overall size of the electrochemical package. A header assembly containing both a glass-to-metal seal opening for a terminal lead and an electrolyte fill opening is used in conjunction with the clamshell casing. The electrolyte fill opening is constructed with an elongated opening with at least two different radii. A first and second sealing element is welded within the electrolyte fill opening at different depths within the header to block the flow of electrolyte and form a hermetic seal.

Dual weld plug for an electrochemical cell

An ultrasonic welding process for joining a current collector to an anode or cathode material of electrochemical cells is described. The ultrasonic welding process utilizes an ultrasonic welding frequency which may be combined with an applied force to bond dissimilar metals comprising the electrode material and the current collector. Preferably, the method is used to bond the anode material to the anode current collector. This method of attachment is suitable for either primary or secondary cells, particularly those powering implantable biomedical devices.

Ultrasonic welding of lithium onto a current collector

A lithium/fluorinated carbon electrochemical cell having the CFmaterial supported on a titanium current collector screen sputter coated with a noble metal is described. The gold, iridium, palladium, platinum, rhodium and ruthenium-coated titanium current collector provides the cell with higher rate capability, even after exposure to high temperatures, in comparison to cells of a similar chemistry having the CFcontacted to a titanium current collector painted with a carbon coating.

[object Object]

A method for making an electrochemical device enclosure is described. The methods comprises the steps of forming first and second casing members; inserting electrochemically active materials within the first casing member; mating the first casing member to the second casing member, thereby forming an interface therebetween; providing a laser welding apparatus comprising a laser; intermittently turning a laser beam on and off while traversing the laser in a first welding pass 360 degrees along the perimeters of the first and second casing members, thereby forming a first intermittent set of welded and unwelded sections at the interface between the casing members; and intermittently turning the laser beam on and off while traversing the laser in a second welding pass 360 degrees along the perimeters of the first and second casing members, thereby forming a second intermittent set of welded sections at the interface between the first and second casing members. The first and second intermitted welded sections combine to provide a complete hermetic seal around and along the circumference of the casing members interface.

Laser weld process for seam welded electrochemical devices

A new cathode design has a first cathode active material of a relatively low energy density but of a relatively high rate capability contacted to the outer sides of first and second cathode current collectors and a second cathode active material having a relatively high energy density but of a relatively low rate capability in contact with the inner sides of the current collectors. The first and second current collectors have a thickness in the range of from about 0.001 inches to about 0.002 inches. A conventional Li/SVO cell powering an implantable medical device has the cathode with a current collector of about 0.003 inches. Even though the present current collectors are about one-half as thick as that of a conventional cell, their combined thickness means that the cell has no reduction in current carrying capacity.

Sandwich electrode design having relatively thin current collectors

A new cathode design has a first cathode active material of a relatively low energy density but of a relatively high rate capability contacted to the outer sides of first and second cathode current collectors and a second cathode active material having a relatively high energy density but of a relatively low rate capability in contact with the inner sides of the current collectors. The second cathode active material has a greater peripheral extend than the current collectors and the opposed layers of the first cathode active material between which it is sandwiched. This construction helps prevent delamination by promoting improved contact of the respective active materials to the current collectors. The present cathode design is useful for powering an implantable medical device requiring a high rate discharge application.

Dual chemistry electrode design

An alkali metal/solid cathode electrochemical cell, such as of a Li/SVO couple, having the cathode material supported on a titanium current collector screen coated with a carbonaceous material is described. The thusly-coated titanium current collector provides the cell with higher rate capability in comparison to cells of a similar chemistry having the cathode active material contacted to an uncoated titanium current collector.

Growing community of inventors

Buffalo, NY, United States of America

Mark J Roy