Battelle Memorial Institute

Battelle Development Corporation

Mark A Paisley

Robert Dwayne Litt

Herman F Feldmann

A method for cracking and shifting a synthesis gas by the steps of providing a catalyst consisting essentially of alumina in a reaction zone; contacting the catalyst with a substantially oxygen free mixture of gases comprising water vapor and hydrocarbons having one or more carbon atoms, at a temperature between about 530.degree. C. (1000.degree. F.) to about 980.degree. C. (1800.degree. F.); and whereby the hydrocarbons are cracked to form hydrogen, carbon monoxide and/or carbon dioxide and the hydrogen content of the mixture increases with a corresponding decrease in carbon monoxide, and carbon formation is substantially eliminated.

Method for hot gas conditioning

A method is described for the recovery of high yields of monomers from waste and scrape polymeric materials with minimal amounts of char and tar. The process involves heating the polymer at a heating rate of at least 500.degree. C./sec in a flow-through reactor. Heating is accomplished by contacting the polymer with a heat transfer material such as hot incandescent sand. A flow-through reactor is used to provide the high heating rates and short reactor residence times for the monomer product. The flow through reactor may be a circulating fluidized bed reactor, an entrainment reactor, a cyclonic reactor or a gravity reactor.

Monomer recovery from polymeric materials

A method is described for the recovery of high yields of monomers from waste and scrape polymeric materials with minimal amounts of char and tar. The process involves pyrolysis in a circulating fluid bed (CFB). The polymer is heated to a temperature of about 650.degree.C. to about 1000.degree.C. at a rate of more than 500.degree.C./sec in less than two seconds. Heat is supplied to the CFB by a stream of hot sand heated in a separate combustor. The sand is also used as the circulating fluid bed material of the CFB. The process is essentially devoid of solid carbon char and non-monomeric liquid products.

Monomeric recovery from polymeric materials

The present invention discloses a novel method of operating a gasifier for production of fuel gas from carbonaceous fuels. The process disclosed enables operating in an entrained mode using inlet gas velocities of less than 7 feet per second, feedstock throughputs exceeding 4000 lbs/ft.sup.2 -hr, and pressures below 100 psia.

Growing community of inventors

Upper Arlington, OH, United States of America

Mark A Paisley