Syntroleum Corporation

Emerging Fuels Technology, Inc.

Mark A Agee

Kenneth L Agee

Larry J Weick

Kym Brian Arcuri

Rafael Luis Espinoza

Elliot L Trepper

A gas to liquids process with a reduced COfootprint to convert both natural gas and a renewable feedstock material into fuels or chemicals. In one embodiment of the invention, a natural gas feed is converted into synthesis gas containing hydrogen and carbon monoxide. A minor portion of the hydrogen is thereafter extracted from the synthesis gas. The synthesis gas is converted to hydrocarbons in a Fischer Tropsch reaction. The Fischer Tropsch hydrocarbon product and a renewable feedstock are hydroprocessed with the extracted hydrogen in order to produce fuels and/or chemicals. Waste products from the renewable feed are recycled to produce additional synthesis gas for the Fischer Tropsch reaction.

Integrated fuel processing with biomass oil

A gas to liquids process with a reduced COfootprint to convert natural gas and a renewable feed stock material into fuels or chemicals. In one non-limiting embodiment of the invention, a natural gas feed is converted into synthesis gas containing hydrogen and carbon monoxide. A minor portion of the hydrogen is thereafter extracted from the synthesis gas. The synthesis gas is converted to hydrocarbons in a Fischer Tropsch reaction. The Fischer Tropsch hydrocarbon product and a renewable feedstock are hydro processed with the extracted hydrogen in order to produce fuels and/or chemicals. Waste products from the renewable feed are recycled to produce additional synthesis gas for the Fischer Tropsch reaction.

Renewable fuels co-processing

A Fischer-Tropsch catalyst for the conversion of synthesis gas into Fischer-Tropsch products includes a stationary Fischer-Tropsch catalyst having a voidage ratio greater than approximately 0.45 or 0.6 and may further have a catalyst concentration for a given reactor volume of at least 10 percent. A Fischer-Tropsch catalyst has a structured shape promoting non-Taylor flow and/or producing a productivity in the range of 200-4000 vol CO/vol. Catalyst/hour or greater over at least a 600 hour run of a Fischer-Tropsch reactor with the catalyst therein. A system for converting synthesis gas into longer-chain hydrocarbon products through the Fisher-Tropsch reaction has a reactor for receiving synthesis gas directly or as a saturated hydrocarbon liquid or a combination, and a stationary, structured Fischer-Tropsch catalyst disposed within the reactor for converting at least a portion of the synthesis gas into longer-chain hydrocarbons through Fischer-Tropsch reaction. A Fischer-Tropsch reactor system having a structured Fischer-Tropsch catalyst may have an all-liquid saturated reactant feed, an all gas reactant feed, or a plethora of combinations therebetween. The systems may or may not include heat removal devices. Methods of manufacturing catalysts and converting synthesis gas are also presented.

Structured Fischer-Tropsch catalyst system and method

System and method for converting light hydrocarbons into heavier hydrocarbons with a plurality of synthesis gas subsystems

A system for converting light hydrocarbons to heavier hydrocarbons having a synthesis gas production unit and a hydrocarbon synthesis unit. For one application the synthesis gas production unit includes a turbine unit with a compression section, an autothermal reformer fluidly coupled to the compression section for producing synthesis gas and combusting at least a portion the gas therein, and an expansion section of the turbine unit fluidly coupled to the autothermal reformer for developing energy from the output of the autothermal reformer. A water separation unit is preferably fluidly coupled to the synthesis gas production unit for removing water from the synthesis gas. The water is directed to an oxygen/hydrogen separator to produce oxygen and hydrogen. Another water separation unit may also be coupled to the output from the hydrocarbon synthesis unit for removing water from the heavier hydrocarbons and directing the water to the oxygen/hydrogen separator.

System for converting light hydrocarbons to heavier hydrocarbons with separation of water into oxygen and hydrogen

Structured fischer-tropsch catalyst system and method

A synthesis gas production system (302) incudes a gas turbine (310) having a compressor (312) with an autothermal reformer (308) between the compressor (312) and the turbine (314). The system (302) may include a separator (326) for removing a portion of the mass exiting the compressor (312) prior to its delivery to the autothermal reformer (308). Gaseous light hydrocarbons are delivered to the autothermal reformer (308) through conduit (330) and may be selectively controlled with a valve (331). Synthesis gas production system (302) may be used with a methanol process, ammonia process, a Fischer-Tropsch process (304), or other process involving synthesis gas.

Synthesis gas production system and method

System and method for converting light hydrocarbons to heavier

A system for recovering liquid hydrocarbons from hydrates on an ocean floor includes a vessel, a positioning subsystem coupled to the vessel for holding the vessel in a desired location over a hydrate formation, a hydrate recovery subsystem coupled to the vessel for delivering hydrates from an ocean floor to the vessel and separating gas from hydrates removed from an ocean floor, a gas conversion subsystem coupled to the hydrate recovery subsystem for converting gas to liquids, and a storage and removal subsystem. Excess energy from the gas conversion subsystem is used elsewhere in the system. A method of recovering hydrates from an ocean floor is also provided.

Growing community of inventors

Jenks, OK, United States of America

Mark A Agee