L'oreal

Marie Mignon

Alain Lagrange

Henri Samain

Leïla Hercouet

Marie Giafferi

Chrystel Pourille

Boris Lalleman

Fabien Aubert

Arno Wahler

Marie Crette

The present invention relates to an anhydrous solid composition for dyeing keratin fibres, in particular human keratin fibres such as the hair, comprising a particular chemical oxidizing agent and a polymer comprising at least one heterocyclic vinyl monomer. The present invention also relates to a packaging article containing said composition. The present invention also relates to processes for dyeing keratin fibres using said composition or said packaging article. Finally, the present invention relates to the use of said composition or of said packaging article for dyeing keratin fibres, and in particular human keratin fibres such as the hair.

Anhydrous solid composition for dyeing keratin fibres comprising a polymer comprising at least one heterocyclic vinyl monomer

The present invention relates to an anhydrous solid composition for dyeing keratin fibres, in particular human keratin fibres such as the hair, comprising one or more metabisulfites. The present invention also relates to a packaging article containing said composition. The present invention also relates to processes for dyeing keratin fibres using said composition or said packaging article. Finally, the present invention also relates to the use of said composition or of said packaging article for dyeing keratin fibres, and in particular human keratin fibres such as the hair.

Anhydrous solid composition for dyeing keratin fibres comprising a metabisulfite

The invention relates to a process for dyeing keratin fibers by treating said fibers with i) at least one aromatic compound comprising a hydrocarbon-based polycycle comprising at least 10 carbon atoms, at least one of the rings of which is aromatic, ii) at least one indol(in)e compound; optionally iii) at least one metal salt, iv) at least hydrogen peroxide or at least one hydrogen peroxide-generating system and v) at least one basifying agent; to a dye composition comprising ingredients i) and ii), and optionally iii) to v) as defined previously and to a kit comprising ingredients i) to v) as defined previously. This hair dyeing process makes it possible to obtain better colorings which are more uniform, chromatic and long-lasting and which do not impair the cosmetic properties of the keratin fibers, and prevents changing of the color associated with the presence of indol(in)e derivatives.

Hair dyeing process using a composition comprising at least one indol(in)e compound and a polycyclic aromatic compound containing at least ten carbon atoms

The invention relates to a process for dyeing keratin fibers, comprising the use of one or more metal catalysts and of a composition (A) comprising: &#x2014;one or more oxidizing agents, and &#x2014;at least one monoaminobenzene of formula (I), or an addition salt or solvate thereof in which the radicals R1 to R5 represent, independently of each other: a hydrogen atom; a halogen atom, a C1-C6 alkyl radical, a C1-C6 alkoxy radical, a carboxylic radical (&#x2014;COOH), a sulfonic radical (&#x2014;S03 H); two of the adjacent radicals R1 to R5 possibly forming, with the carbon atoms that bear them, a saturated or unsaturated 5- to 7-membered ring, optionally comprising from 1 to 2 heteroatoms, preferably oxygen, the said ring being optionally fused with a saturated or unsaturated 5- to 6-membered ring; on condition that at least one of the radicals R1 to R5 represents an optionally substituted alkoxy radical and preferably at least one of the other radicals R1 to R5 is a hydrogen atom. 

Oxidation dyeing process using a composition comprising a monoaminobenzene and a metal catalyst

The present invention relates to a composition for dyeing keratin fibres, comprising: at least one fatty substance, at least one surfactant; at least one oxidation base, at least one coupler of formula (B3) below and also salts thereof, optical and geometrical isomers and tautomers thereof, and hydrates thereof: (B3) in which; R, R, Rrepresent a hydrogen; a C-Calkyl or alkenyl, &#x2014;SR or &#x2014;OR; a (C-C)alkylcarbonyl; hydrocarbonyl; sulphonic or carboxylic acid; R, Rrepresent a hydrogen, a C-Calkyl or alkenyl; &#x2014;OR'; two groups chosen from R, R, R, R, Rand borne by adjacent carbon atoms may form, together with said carbon atoms, a ring or a heterocycle which is optionally substituted, and which is optionally interrupted with one or more carbonyl groups; at least one of the radicals R, R, Rrepresenting a hydrogen; at least one of the radicals Ror Rdenoting a group &#x2014;OR&#x2032; with R&#x2032; representing a C-Calkyl or alkenyl, it being possible for this radical to form, with the carbon atom bearing it, one of the neighbouring carbon atoms and its substituent, a heterocycle; at least one alkalinizing agent; the fatty substance content representing in total at least 25% by weight relative to the total weight of the composition. The present invention also relates to a process using this composition in the presence of at least one chemical oxidizing agent, and to multicompartment devices suitable for the implementation of the invention. 

Dye composition using a phenol-derived coupler in a medium rich in fatty substances, processes and devices

The present invention relates to a process for dyeing human keratin fibres, in which use is made of one or more metal catalysts and a composition (A) comprising: (a) at least 10% by weight of one or more fatty substances, (b) one or more oxidation bases of formula (I) or (II), the addition salts thereof, solvates thereof and mixtures thereof: Formula (I), Formula (II) (c) one or more chemical oxidizing agents other than atmospheric oxygen. The invention also relates to a multi-compartment device and to a composition comprising all of the above-mentioned ingredients. 

Process for dyeing in the presence of oxidation bases comprising at least one sulfonic, sulfonamide, sulfone, amid or acid group and a metal catalyst, device and ready-to-use composition

The present invention relates to a process for the oxidation dyeing of keratin fibers implementing: a) a step of pretreating said fibers by application to said fibers of a cosmetic composition (B) comprising: i) at least one fatty substance in an amount of greater than or equal to 10% by weight relative to the total weight of the composition (B); and ii) at least one metal catalyst; b) optionally a washing, rinsing, drying and/or rubbing-dry step; c) followed by a step of dyeing by application to said fibers of a cosmetic composition (A) comprising: i) at least one oxidation base, preferably chosen from para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases preferably comprising at least two nitrogen atoms, and addition salts thereof; ii) optionally at least one coupler; and iii) at least one chemical oxidizing agent. The dyeing process makes it possible to significantly improve the dyeing properties of the coloration, in particular in terms of selectivity, of chromaticity, and of color intensity and uptake. The use of a composition which is rich in fatty substances, i.e. greater than 10%, and contains at least one catalyst pretreatment, before oxidation dyeing, allows a clear improvement in the dyeing properties, in particular in terms of dye uptake onto keratin fibers, of strength and of chromaticity and of selectivity of the color.

Oxidation dyeing process implementing a pretreatment based on a composition rich in fatty substances and on metal catalysts

The subject of the present invention is a process for the oxidation dyeing of keratin fibers, in particular human keratin fibers such as the hair, implementing: a) a step of treating said fibers by application to said fibers of a cosmetic composition (A) comprising: i) at least one fatty substance in an amount of greater than 10% by weight relative to the total weight of the composition (A), at least one metal catalyst; ii) at least one coupler; iii) optionally at least one oxidation base, preferably chosen from para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, addition salts thereof and solvates thereof; b) optionally a washing, rinsing, drying and/or rubbing-dry step; c) a step of treatment by application to said fibers of an oxidizing cosmetic composition (B) comprising at least one chemical oxidizing agent; and it being understood that steps a), b) and c) can be carried out successively a), then b), then c), or else a) then c), followed by b). The dyeing process makes it possible to significantly improve the dyeing properties of the coloration, in particular in terms of selectivity, of chromaticity, and of color intensity and uptake. The use of a composition which is rich in fatty substances, i.e. greater than 10%, and contains at least one catalyst, as a pretreatment, before oxidation dyeing, allows a clear improvement in the dyeing properties, in particular in terms of dye uptake onto keratin fibers, of strength and of chromaticity and of selectivity of the color.

Oxidation dyeing process using a composition rich in fatty substances which comprises metal catalysts and couplers

The present invention relates to a composition for dyeing keratin fibers, comprising at least one fatty substance; at least one surfactant; at least one dye for keratin fibers, having a log P greater than or equal to 1.3; at least one alkaline agent; at least one chemical oxidizing agent; at least 0.5% by weight relative to the weight of the composition of at least one liquid non-ionic compound having a Hansen parameter &#x3b4; H below 16 MPa &#xbd;; the fatty substance content representing in total at least 25% by weight relative to the total weight of the composition. The present invention also relates to a method using this composition, and to multi-compartment devices that are suitable for using this invention.

Dye composition using a specific non-ionic hydrotropic compound in a medium rich in fatty substances, methods and device

The present invention relates to a composition for dyeing keratin fibers, comprising:&#x2014;one or more fatty substances,&#x2014;one or more surfactants;&#x2014;one or more oxidation bases,&#x2014;one or more phenol-derived couplers corresponding to the formula (B2) below: * R, R, R, represent a hydrogen; an optionally substituted C-Calkyl or alkenyl radical; &#x2014;SR or &#x2014;OR; a saturated C-Ccyclic group; a (C-C)alkylcarbonyl group; hydrocarbonyl; a sulphonic or carboxylic acid group; * at least one of the radicals R, R, Rrepresenting a hydrogen atom; * R, Rrepresent a hydrogen; an optionally substituted C-Calkyl or alkenyl; &#x2014;SR; a (C-C)alkyl-carbonyl; hydrocarbonyl; a sulphonic or carboxylic acid group; * two groups chosen from R, R, R, R, Rand borne by adjacent carbon atoms may form, together with said carbon atoms, a ring or a heterocycle with a single heteroatom, this ring or heterocycle comprising no double bond other than that of the ring to which it is fused; * at least one of the radicals R, R, R, R, Rbeing other than hydrogen;&#x2014;one or more alkalinizing agents; the fatty substance content representing in total at least 25% by weight relative to the total weight of the composition. The present invention also relates to a process using this composition in the presence of at least one chemical oxidizing agent, and to multicompartment devices suitable for the implementation of the invention. 

Dye composition using a particular phenolic coupler in a medium rich in fatty substances, processes and devices

The present invention relates to a process for dyeing keratin fibers, in particular human keratin fibers such as the hair, comprising the use of one or more metal catalysts chosen from transition metal salts and rare-earth metal salts, and mixtures thereof and a composition (I) comprising at least 10% by weight of one or more fatty substances different from fatty acids, one or more oxidation dyes and one or more oxidizing agents.

Oxidation dyeing process using a composition rich in fatty substances and metal catalysts, and device suitable therefor

The present invention relates to a cosmetic composition for dyeing keratin fibers, in particular human keratin fibers such as the hair, comprising: a) one or more fatty substances; b) one or more surfactants; c) one or more oxidation bases; d) one or more couplers based on 2-hydroxynaphthalene derivatives or particular phenol derivatives, acylaminophenol derivatives or quinoline derivatives; f) one or more basifying agents; e) optionally one or more chemical oxidizing agents; and the fatty substance content representing in total at least 25% by weight relative to the total weight of the formulation. The present invention also relates to a process using this composition, and to a multi-compartment device that is suitable for performing the said process.

Dye composition using a 2-hydroxynaphthalene, (acylamino)phenol or quinoline coupler in a fatty-substance-rich medium, dyeing process and device therefor

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Paris, France

Marie Mignon