Enichem S.p.a

Montedipe S.p.a.

Enichem Anic S.r.l.

Other

Versalis S.p.a.

Polimeri Europa S.p.a.

Enitecnologie S.p.a.

Maria Angela Mantegazza

Angela Carati

Guido Petrini

Giuseppe Bellussi

Mario Padovan

Paolo Roffia

Franco Rivetti

Alberto Cesana

Luigi Balducci

Giudo Petrini

Carlo Perego

Daniele Bianchi

Roberto Buzzoni

Gianni Girotti

Paolo Pollesel

Raffaele Ungarelli

Roberto Millini

Stefano Peratello

Sergio Tonti

Giordano De Alberti

Giuseppe Leofanti

Roberto Bagatin

Fabrizio Bordes

Massimo Romagnoli

Giorgio R Tauszik

Donatella Berti

Sergio Sgorlon

The invention relates to a new process which allows the preparation of TS-1 zeolites in a pure phase and with a crystallinity higher than 95%, operating at reduced reaction volumes, and obtaining high productivities and extremely high crystallization yields. The particular crystalline form of the TS-1 zeolite thus prepared, is also described.

Process for the preparation of TS-1 zeolites

The invention relates to a process for the production of ethylbenzene which comprises: a reaction step in which benzene is reacted with ethanol, or a mixture of ethanol and ethylene, at a pressure higher than atmospheric pressure, preferably in gaseous phase or in mixed gas-liquid phase, in the presence of a catalytic system containing a zeolite belonging to the BEA family, and a separation step of the product obtained. According to a preferred aspect, ethanol deriving from biomasses is used, in particular ethanol obtained from the fermentation of sugars deriving from biomasses.

Process for preparing ethylbenzene

Process for the production of propylene starting from mixtures of hydrocarbons, prevalently olefins, the above hydrocarbons having a boiling point ranging from &#x2212;15&#xb0; C. to +80&#xb0; C., preferably from &#x2212;12&#xb0; C. to +60&#xb0; C., which comprises putting the above mixture of hydrocarbons in contact, under cracking conditions, with a large-pore zeolite having a molar ratio Silica/Alumina lower than 200, preferably ranging from 50 to 150.

Process for the production of propylene from olefinic streams

A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.

Process for preparing bound zeolites

A process is described for regenerating exhausted zeolitic catalysts containing titanium and deriving from oxidation processes of organic substrates with hydrogen peroxide. Said process consists in carrying out a treatment in an aqueous medium with hydrogen peroxide in the presence of inorganic fluorinated compounds, subsequent to thermal treatment of the exhausted catalyst.

Process for the regeneration of zeolitic catalysts containing titanium

A method is described for improving the catalytic performances of titanium silicalite having formula (I) by the activation of the catalyst (I) in an aqueous medium with hydrogen peroxide, in the presence of precursors of fluoride ions or anionic species containing fluorine. The activated catalyst (I) is particularly useful in oxidation processes with hydrogen peroxide of organic substrates and, in particular, in hydroxylation reactions of aromatic compounds, amoximation reactions of carbonyl compounds, epoxidation reactions of olefinic compounds and oxidation reactions of nitrogenated compounds.

Activation method of titanium silicalite

Process for the production of oximes which comprises ammoximation of a carbonylic compound selected from acetophenone and cyclododecanone with H.sub.2 O.sub.2 and NH.sub.3 in the presence of a catalyst based on silicon, titanium and oxygen and a cocatalyst consisting of amorphous silica.

Catalytic process for the production of oximes

Direct catalytic process for the production of hydroxylamine by means of the oxidation of ammonia with H.sub.2 O.sub.2, wherein the catalyst is composed of silicon, titanium and oxygen and has a crystalline (as in the case of titanium-silicalites, for example) or amorphous structure.

Direct catalytic process for the production of hydroxylamine

Two-step process in the liquid phase for producing oximes at 60.degree.-100.degree. C. and 1.5-5 bars, which comprises:

Two-step process for liquid-phase production of oximes

The invention relates to a process for the synthesis of an N,N-dialkyl-hydroxylamine by reaction of the corresponding dialkylamine with H.sub.2 O.sub.2, said reaction being carried out in the presence of a catalyst based on titanium-silicalite.

Process for the synthesis of a N,N-dialkyl-hydroxylamine

The invention concerns a catalytic process for the manufacture of oximes by reaction, in the liquid phase, of the corresponding carbonylic compounds with NH.sub.3 and H.sub.2 O.sub.2, in which process the catalyst is substantially consisting of a crystalline material with a zeolitic structure containing silicon and titanium, subjected, before use, to an activating treatment with H.sub.2 O.sub.2.

Catalytic process for the manufacture of oximes

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Cambiago, Italy

Maria Angela Mantegazza