US Government As Represented by the Secretary of the Army

The Clorox Company

The Drackett Company

Maria A Geigel

Chester W Marynowski

Peter M Newgard

An isocyanate compound of the general formula R(NCO).sub.n, wherein R is her an aliphatic or an aromatic radical or a combination of both, and n is 1 or a larger integer is prepared by the process comprising dissolving in a high temperature boiling point solvent contained in an agitated, jacketed reactor vessel, an amine of the formula R(NH.sub.2).sub.n, completing a hydrochlorination and precipitation step to form a colloidal suspension of microcrystalline salt particles of amine hydrochloride salt R(NH.sub.2).sub.n.nHCl, introducing oxalyl chloride with agitation and by subsurface injection into the amine hydrochloride salt solution to form an intermediate of amine oxamyl chloride in situ which is thermally decomposed to yield an isocyanate of the general formula R(NCO).sub.n, and separating and purifying the isocyanate by distillation. The unreacted oxalyl chloride and high temperature reaction solvent are recovered by distillation and by absorption from the HCl by-product and are recycled. The by-product HCl is also partially recycled and used for hydrochlorination.

Isocyanates from oxalyl chloride and amines

A sealabe dispenser adapted for mounting in a liquid containing reservoir, said reservoir having closable and openable inlet and outlet ports, the level of the liquid in said reservoir being capable of being lowered and raised by the appropriate manipulation of said inlet and outlet ports, said dispenser comprising at least one storage chamber containing material to be dispensed into said liquid reservoir, said material to be dispensed from said storage chamber by means of said liquid flowing into and out of said storage chamber, said storage chamber being provided with liquid passage means for permitting said liquid to enter and leave said chamber in response to the level of the liquid in said reservoir and venting means to vent the interior of said storage chamber to the atmosphere, moveable sealing means cooperating with said liquid passage means and said venting means to seal and unseal said liquid passage means and said venting means.

Sealable dispenser and hanger

Diperoxyacids are unstable compounds, and processes for their production have normally provided relatively low product throughputs per reactor vessel volume. The present invention is a method for making diperoxyacids in which formation of the diperoxyacids is controlled and a high solids throughput may be achieved. The inventive method includes a controlling step wherein a reaction solids phase is maintained at not greater than about 36 wt. % of a reaction system, more preferably maintained at about 12 wt. % to about 36 wt. %.

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Menlo Park, CA, United States of America

Maria A Geigel