Fiberchem, Inc.

Marcus S Butler

Stanley M Klainer

Kisholoy Goswami

Dileep K Dandge

Johnny R Thomas

A species-specific metal clad segment on a waveguide, including a planar waveguide, allows controlled light leakage of light propagating through the waveguide by total internal reflection, to measure refractive index and identify chemical species. A waveguide sensor is designed for a particular chemical species by selecting a metal clad with an affinity for the species and by matching the refractive indices of the waveguide body, clad, metal clad segment and chemical species. Dual or multiple measurement methods use a pair or multiple metal clad segments of different specificity. The metal clad segment may include another material to provide a suitable refractive index while having the desired affinity for the chemical species or to provide a catalyst to react the species to form a reaction product which is more readily detected.

Planar and other waveguide refractive index sensors using metal cladding

Single or multi-cell reservoir sensors with single illumination sources and one or more detectors per cell unit have an arrangement whereby a gaseous, vapor or liquid sample enters the cell body and interacts with a sensing solution to detect and quantify a given species. Entrance of the sample into the sensor is through an opening in the cell body which may be covered with a membrane to contain the sensing reagent and to presort the species entering the cell. Reservoir cells can be used with organic, inorganic or biochemical sensing materials. A variety of sensors as alcohol, drugs of abuse, organic halides, cyanide and inorganic ions are provided.

Reservoir chemical sensors

A refractive index FOCS has a fiber optic core with a partly light transmissive thin metal film clad of an effective thickness and light transmissivity so that transmission through the core is strongly affected by the refractive index of a surrounding liquid or vapor medium. The metal clad and surrounding medium produce a localized refractive index at the core interface which modulates light transmission through the core as a function of the medium refractive index. The clad is made of platinum, or also of gold, rhodium, palladium, nickel, iron, cobalt, ruthenium, iridium, osmium, zinc, copper, silver, chronium, molybdenum, tungsten, vanadium, niobium, tantalum, titanium, zirconium or hafnium. The clad is also made of oxides of these metals, or metal compounds or alloys. With a fluorescent tip, the changes in the fluorescent signal are a measure of the medium refractive index. With a reflective tip, the changes in the reflected signal are measured. In a linear configuration, source and detector are placed at opposite ends of the fiber and changes in the transmitted signal are measured as a function of refractive index. Multiple measurements with multiple clads of different specificity can be made. The multiple clads can be on a single fiber or on separate fibers.

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Henderson, NV, United States of America

Marcus S Butler